Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil

Umirzak Dzhusipbekov; Dametken Fischer; Gulzipa Nurgalieva; Kubat Kemelov; Damira Sambaeva; Zarlık Maymekov

doi:10.51354/mjen.1211527

EN

Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil

Abstract

In this study, thermodynamic modelling of the process of thermal destruction of oil-contaminated soil of Ozenmunaigas JSC, which includes compounds such as carbon, silicon, aluminum, iron, calcium, magnesium, sodium, potassium, chromium, phosphorus, manganese, copper, titanium, molybdenum, nickel, vanadium, and water, was carried out. The physicochemical and thermodynamic parameters of the complex system were calculated at P=0.1 MPa, T=598-3000 K. The concentration distribution of components, particles, and condensed phases in the gas phase has been established. In the process of thermal destruction of oil-contaminated soil, the formation of condensed phases was as follows: SiO2(c), Al2O3(c), AlO3H3(c), Cu(c), Cu2O(c), FeO(c), Fe2O3(c), Fe3O4(c), Fe2SiO4(c), NiO(c), MnO(c), Mn3O4(c), MnO2H2(c), Cr2O3(c), MoO2(c), V2O3(c), V2O4(c), TiO2(c), MgSiO3(c), Mg2SiO4(c), MgTi2O5(c), Ca3P2O8(c), Mg2SiO4(c), MgTi2O5(c), Ca3P2O8(c), CaCO3(c), CaSiO3(c), CaTiO3(c), Na2Si2O5(c), K2Si4O9(c). At the same time, the amount of condensed calcium silicate CaSiO3(c) was significant and amounted to 3.2 mol/kg, which is due to the initial standard content of oxides of the type (g/kg): SiO2-473,7, CaO-181,5 in oil-contaminated soil. The formation of various types of condensed phases (from 10-30 to 10-4 mol/kg) during thermal degradation can help reduce the synergism and toxicity of metal particles in oil-contaminated soils. In the process of thermal destruction of oil-contaminated soil, its carbon-containing components (mg/kg: С12-6,27; С13-10,98; С14-15,69; С15-18,82; С16-23,52; С17-31,37; С18-27,80; С19-17,25; С20-29,80) were mainly converted into oxide, carbon dioxide, and water, and thereby neutralized the organic mass of the soil.

Keywords

oil, soil, carbon, metal, chemical composition, component, particle, thermodynamics, modeling, condensed phase, neutralization

References

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Umirzak Dzhusipbekov This is me
0000-0002-2354-9878
Kazakhstan

Dametken Fischer
0000-0001-8326-1545
Kazakhstan

Gulzipa Nurgalieva This is me
0000-0003-2659-3361
Kazakhstan

Kubat Kemelov ^*
0000-0001-7375-6325
Kyrgyzstan

Damira Sambaeva
0000-0002-9834-341X
Kyrgyzstan

Zarlık Maymekov
0000-0002-9117-262X
Kyrgyzstan

Early Pub Date

June 23, 2023

Publication Date

July 1, 2023

Submission Date

December 6, 2022

Acceptance Date

May 24, 2023

Published in Issue

Year 2023 Volume: 11 Number: 1

DOI

https://doi.org/10.51354/mjen.1211527

IZ

https://izlik.org/JA74HD42ZR

APA

Dzhusipbekov, U., Fischer, D., Nurgalieva, G., Kemelov, K., Sambaeva, D., & Maymekov, Z. (2023). Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil. MANAS Journal of Engineering, 11(1), 53-63. https://doi.org/10.51354/mjen.1211527

AMA

1.Dzhusipbekov U, Fischer D, Nurgalieva G, Kemelov K, Sambaeva D, Maymekov Z. Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil. MJEN. 2023;11(1):53-63. doi:10.51354/mjen.1211527

Chicago

Dzhusipbekov, Umirzak, Dametken Fischer, Gulzipa Nurgalieva, Kubat Kemelov, Damira Sambaeva, and Zarlık Maymekov. 2023. “Prediction of the Formation of Low-Molecular Components, Particles, and Condensed Phases During Thermal Destruction of Oil-Contaminated Soil”. MANAS Journal of Engineering 11 (1): 53-63. https://doi.org/10.51354/mjen.1211527.

EndNote

Dzhusipbekov U, Fischer D, Nurgalieva G, Kemelov K, Sambaeva D, Maymekov Z (July 1, 2023) Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil. MANAS Journal of Engineering 11 1 53–63.

IEEE

[1]U. Dzhusipbekov, D. Fischer, G. Nurgalieva, K. Kemelov, D. Sambaeva, and Z. Maymekov, “Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil”, MJEN, vol. 11, no. 1, pp. 53–63, July 2023, doi: 10.51354/mjen.1211527.

ISNAD

Dzhusipbekov, Umirzak - Fischer, Dametken - Nurgalieva, Gulzipa - Kemelov, Kubat - Sambaeva, Damira - Maymekov, Zarlık. “Prediction of the Formation of Low-Molecular Components, Particles, and Condensed Phases During Thermal Destruction of Oil-Contaminated Soil”. MANAS Journal of Engineering 11/1 (July 1, 2023): 53-63. https://doi.org/10.51354/mjen.1211527.

JAMA

1.Dzhusipbekov U, Fischer D, Nurgalieva G, Kemelov K, Sambaeva D, Maymekov Z. Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil. MJEN. 2023;11:53–63.

MLA

Dzhusipbekov, Umirzak, et al. “Prediction of the Formation of Low-Molecular Components, Particles, and Condensed Phases During Thermal Destruction of Oil-Contaminated Soil”. MANAS Journal of Engineering, vol. 11, no. 1, July 2023, pp. 53-63, doi:10.51354/mjen.1211527.

Vancouver

1.Umirzak Dzhusipbekov, Dametken Fischer, Gulzipa Nurgalieva, Kubat Kemelov, Damira Sambaeva, Zarlık Maymekov. Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil. MJEN. 2023 Jul. 1;11(1):53-6. doi:10.51354/mjen.1211527

Manas Journal of Engineering

16155

Abstract

Keywords

Prediction of the formation of low-molecular components, particles, and condensed phases during thermal destruction of oil-contaminated soil

Abstract

Keywords

References

Details

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Subjects

Journal Section

Authors

Early Pub Date

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Submission Date

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Published in Issue

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IZ

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