Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Nevroz Aslan Ertaş; Arif Kıvrak

EN

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Abstract

In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids form the new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl-1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reaction between 2 and arylboronic acids give a new rearrangement reaction involving free radicals. Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones. This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.

Keywords

ferrocene,naphthoquinone,rearrangement reactions

Supporting Institution

TUBITAK

Project Number

114Z042

Thanks

We want to express our thanks to the Scientific and Technical Research Council of Turkey (TUBİTAK-114Z042) for financial supports of Microwave Reactor and Van Yüzüncü Yil University (FBA-2019-7910) for financial supports of chemicals. N. A. also thanks to YÖK 100/2000 for scholarships.

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Nevroz Aslan Ertaş
0000-0003-3590-5961
Türkiye

Arif Kıvrak ^*
0000-0003-4770-2686
Türkiye

Publication Date

June 30, 2020

Submission Date

May 29, 2020

Acceptance Date

June 19, 2020

Published in Issue

Year 2020 Volume: 8 Number: 1

IZ

https://izlik.org/JA35CN29WJ

APA

Aslan Ertaş, N., & Kıvrak, A. (2020). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MANAS Journal of Engineering, 8(1), 22-27. https://izlik.org/JA35CN29WJ

AMA

1.Aslan Ertaş N, Kıvrak A. Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MJEN. 2020;8(1):22-27. https://izlik.org/JA35CN29WJ

Chicago

Aslan Ertaş, Nevroz, and Arif Kıvrak. 2020. “Ferrocene As a Leaving Group; Unexpected Rearrangement Reactions for the Synthesis of 2,3-Diarylnapthoquinones”. MANAS Journal of Engineering 8 (1): 22-27. https://izlik.org/JA35CN29WJ.

EndNote

Aslan Ertaş N, Kıvrak A (June 1, 2020) Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MANAS Journal of Engineering 8 1 22–27.

IEEE

[1]N. Aslan Ertaş and A. Kıvrak, “Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones”, MJEN, vol. 8, no. 1, pp. 22–27, June 2020, [Online]. Available: https://izlik.org/JA35CN29WJ

ISNAD

Aslan Ertaş, Nevroz - Kıvrak, Arif. “Ferrocene As a Leaving Group; Unexpected Rearrangement Reactions for the Synthesis of 2,3-Diarylnapthoquinones”. MANAS Journal of Engineering 8/1 (June 1, 2020): 22-27. https://izlik.org/JA35CN29WJ.

JAMA

1.Aslan Ertaş N, Kıvrak A. Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MJEN. 2020;8:22–27.

MLA

Aslan Ertaş, Nevroz, and Arif Kıvrak. “Ferrocene As a Leaving Group; Unexpected Rearrangement Reactions for the Synthesis of 2,3-Diarylnapthoquinones”. MANAS Journal of Engineering, vol. 8, no. 1, June 2020, pp. 22-27, https://izlik.org/JA35CN29WJ.

Vancouver

1.Nevroz Aslan Ertaş, Arif Kıvrak. Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MJEN [Internet]. 2020 Jun. 1;8(1):22-7. Available from: https://izlik.org/JA35CN29WJ

Manas Journal of Engineering

16155

Abstract

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

IZ

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