Study of the activity of a novel green catalyst used in the production of hydrogen from methanolysis of sodium borohydride

Year 2021, , 115 - 121, 06.12.2021

Tülin Avcı Hansu

https://doi.org/10.51354/mjen.934839

Cited By: 5

Abstract

Biomass is an important energy source because it is easily accessible, contributes to the protection of the environment, and can be easily used in industry. Biomass resources can be classified as plants, vegetable and animal wastes, urban and industrial wastes. Highly active catalysts can be prepared by physical and chemical activation methods. Here, Microcystis aeruginosa was used as a biomass source and a metal-free catalyst was synthesized. The production conditions were determined by burning the microsistis modified with 3M H3PO4 at different temperatures (100, 200, 300 and 400 oC) and at different times (30, 45, 60 and 90 minutes). Parameters such as NaBH4 amount, catalyst amount and temperature of the synthesized MA- H3PO4 catalyst that affect methanolization were investigated. In the kinetic calculations, the reaction order was found as n 0.18, activation energy 19.014 kj / mol and initial rate 4998.7 ml H2min^-1gcat^-1. The reusability of the MA-H3PO4 catalyst was tested 5 times and its stability determined.

Keywords

Metal-free catalyst, Microcystis aeruginosa, Methanolysis, NaBH4

References

• Milano J., Ong H.C., Masjuki H.H., Chong W.T., Lam M.K., Loh P.K., Vellayan V., “Microalgae biofuels as an alternative to fossil fuel for power generation”, Renewable and Sustainable Energy Reviews, 58, (2016), 180-197.
• Suganya T., Varman M., Masjuki H.H., Renganathan, S., “Macroalgae and microalgae as a potential source for commercial applications along with biofuels production: a biorefinery approach”, Renewable and Sustainable Energy Reviews, 55, (2016), 909-941.
• Hosseini S. E., Wahid, M.A., “Hydrogen production from renewable and sustainable energy resources: promising green energy carrier for clean development”, Renewable and Sustainable Energy Reviews, 57, (2016), 850-866.
• Kaya M., “Evaluating organic waste sources (spent coffee ground) as metal-free catalyst for hydrogen generation by the methanolysis of sodium borohydride”, International Journal of Hydrogen Energy, 45(23), (2020), 12743-12754.
• Kaya M., “Production of metal-free catalyst from defatted spent coffee ground for hydrogen generation by sodium borohyride methanolysis”, International journal of hydrogen energy, 45(23), (2020), 12731-12742.
• Mustafa K.A.Y.A., Bekirogullari, M., “Investigation of hydrogen production from sodium borohydride methanolysis in the presence of Al2O3/spirulina platensis supported Co catalyst”, Avrupa Bilim ve Teknoloji Dergisi, (16), (2019), 69-76.
• Bilici M.S.U. “Energy Carrier Hydrogen”, Hydrogen Carrier Sodium Borohydride, Mining Bulletin, (67), (2004).
• Hansu T.A., Sahin O., Caglar A., Kivrak H.,” A remarkable Mo doped Ru catalyst for hydrogen generation from sodium borohydride: the effect of Mo addition and estimation of kinetic parameters”, Reaction Kinetics, Mechanisms and Catalysis, 131(2), (2020), 661-676.
• Avci Hansu T., Sahin O., Çağlar A., Demir Kivrak, H.,” Untangling the cobalt promotion role for ruthenium in sodium borohydride dehydrogenation with multiwalled carbon nanotube‐supported binary ruthenium cobalt catalyst”, International Journal of Energy Research, 45(4), (2021), 6054-6066.
• Hansu F., “The effect of dielectric barrier discharge cold plasmas on the electrochemical activity of Co–Cr–B based catalysts”, Journal of the Energy Institute, 88(3), (2015), 266-274.
• Kivrak H. D., Caglar A., Hansu T. A., Şahin, Ö.” Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading”, MANAS Journal of Engineering, 8(1), (2020), 1-10.
• Akdemir M., Avci Hansu T., Caglar A., Kaya M., Demir Kivrak, H.,” Ruthenium modified defatted spent coffee catalysts for supercapacitor and methanolysis application”, Energy Storage, e243, (2021).
• Hansu T. A., Caglar A., Sahin O., Kivrak, H., “Hydrolysis and electrooxidation of sodium borohydride on novel CNT supported CoBi fuel cell catalyst”, Materials Chemistry and Physics, 239, (2020), 122031.
• Braesch G., Bonnefont A., Martin V., Savinova E. R., Chatenet M., “Borohydride oxidation reaction mechanisms and poisoning effects on Au, Pt and Pd bulk electrodes: From model (low) to direct borohydride fuel cell operating (high) concentrations”, Electrochimica Acta, 273, (2018), 483-494.
• Braesch G., Wang Z., Sankarasubramanian S., Oshchepkov A. G., Bonnefont A., Savinova E. R., ... & Chatenet, M., “A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes”, Journal of Materials Chemistry A, 8(39), (2020),20543-20552.
• Caglar A., Ulas B., Cogenli M.S., Yurtcan A.B., Kivrak, H., “Synthesis and characterization of Co, Zn, Mn, V modified Pd formic acid fuel cell anode catalysts”, Journal of Electroanalytical Chemistry, 850, (2019), 113402.
• Ulas B., Caglar A., Kivrak H.,” Determination of optimum Pd: Ni ratio for Pd x Ni 100‐x/CNT s formic acid electrooxidation catalysts synthesized via sodium borohydride reduction method”, International Journal of Energy Research, 43(8), (2019), 3436-3445.
• Ulas B., Alpaslan D., Yilmaz Y., Dudu T. E., Er O. F., Kivrak, H., “Disentangling the enhanced catalytic activity on Ga modified Ru surfaces for sodium borohydride electrooxidation.”,Surfaces and Interfaces, 23, (2021), 100999.
• Biniwale R. B., Rayalu S., Devotta S., Ichikawa, M.,” Chemical hydrides: a solution to high capacity hydrogen storage and supply”, International Journal of Hydrogen Energy, 33(1), (2008), 360-365.
• Duman F., Atelge M.R., Kaya M., Atabani A. E., Kumar G., Sahin U., Unalan S., “A novel Microcystis aeruginosa supported manganese catalyst for hydrogen generation through methanolysis of sodium borohydride”, International Journal of Hydrogen Energy, 45(23), (2020), 12755-12765.
• Inal I.I.G., Akdemir M., Kaya M., “Microcystis aeruginosa supported-Mn catalyst as a new promising supercapacitor electrode: A dual functional material”, International Journal of Hydrogen Energy, 46(21), (2021), 21534-21541.
• Rangabhashiyam S., Behera B., Aly N., Balasubramanian, P.,”Biodiesel from microalgae as a promising strategy for renewable bioenergy production-A review”, Journal of Environment & Biotechnology Research, 6(4), (2017), 260-269.
• Ahlström-Silversand A F., Odenbrand C.U.I., “Modelling catalytic combustion of carbon monoxide and hydrocarbons over catalytically active wire meshes”, Chemical Engineering Journal, 73(3), (1999), 205-216.
• Brack P., Dann S E., Wijayantha K. U.,” Heterogeneous and homogenous catalysts for hydrogen generation by hydrolysis of aqueous sodium borohydride (NaBH4) solutions”, Energy Science & Engineering, 3(3), (2015), 174-188.
• Sahiner,N., Demirci S.,” Natural microgranular cellulose as alternative catalyst to metal nanoparticles for H2 production from NaBH4 methanolysis.”,Applied Catalysis B: Environmental, 202, (2017), 199-206.
• Mustafa K.A.Y.A., BekiroğullarI, M., “Tarımsal Atıktan Elde Edilen Aktif Karbon Destekli Co-B Katalizörü Varlığında Sodyum Borhidrürün Metanolizi”, Türkiye Tarımsal Araştırmalar Dergisi, 6(1), (2019), 80-86.
• Kaya M., Ceyhan A.A., Şahin Ö.,” Effects of different temperatures and additives on the metastable zone width precipitation kinetics of NaBO 2”, Russian Journal of Physical Chemistry A, 88(3), (2014), 402-408.
• Demirci S., Yildiz M., Inger E., Sahiner N.,”Porous carbon particles as metal-free superior catalyst for hydrogen release from methanolysis of sodium borohydride”, Renewable Energy, 147, (2020), 69-76.
• Wang A., Yin H., Lu H., Xue J., Ren M., Jiang T.,” Effect of organic Modifiers on the structure of nickel nanoparticles and catalytic activity in the hydrogenation of p -nitrophenol to p –Aminophenol,Langmuir”, 25, (2009), 12736-12741
• Bekirogullari M.,” Catalytic activities of non-noble metal catalysts (CuB, FeB, and NiB) with C. Vulgaris microalgal strain support modified by using phosphoric acid for hydrogen generation from sodium borohydride methanolysis”, International Journal of Hydrogen Energy, 44(29), (2019), 14981-14991.
• Wang F., Zhang Y., Luo Y., Wang Y., Zhu H.,” Preparation of dandelion-like Co–Mo–P/CNTs-Ni foam catalyst and its performance in hydrogen production by alcoholysis of sodium borohydride”, International Journal of Hydrogen Energy, 45(55), (2020), 30443-30454.
• Xu D., Zhao L., Dai P., Ji S.,” Hydrogen generation from methanolysis of sodium borohydride over Co/Al2O3 catalyst”, Journal of natural gas chemistry, 21(5), (2012), 488-494.