Research Article
BibTex RIS Cite

Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm

Year 2018, Volume: 6 Issue: 2, 96 - 109, 24.12.2018

Abstract



Manganese dioxide decorated carboxylated graphene
oxide (Mn-GO-COOH) attached onto the glassy carbon (GC) electrode to develop a
new method for the simultaneous determination of Cd2+ and Pb2+
ions in rice samples. Graphene oxide (GO) was attached on 4-aminophenyl
covalently modified glassy carbon surface via amide reaction. As-prepared modified
material was characterized with XPS, SEM and electrochemical methods. A novel
differential pulse anodic stripping voltammetric (DPASV) method was developed
for the simultaneous determination of Cd2+ and Pb2+ on
the GC/Mn-GO-COOH nanoplatform electrode. A linear response was found for the
heavy metals in the range from 5 to 100
mg/L. The limit of detections (LODs) of Cd2+ and
Pb2+ were 0.04
mg/L and 0.08 mg/L respectively. Manganese dioxide decorated
carboxylated graphene oxide electrode was applied to the detection of Cd2+
and Pb2+ present in different rice samples by developed
voltammetric method, and the accessed results were found to be in accordance
with that of ICP-OES.

References

  • [1] Keawkim, K., et al., Determination of lead and cadmium in rice samples by sequential injection/anodic stripping voltammetry using a bismuth film/crown ether/Nafion modified screen-printed carbon electrode. Food Control, 31, (2013), 14-21.
  • [2] Qiao, J., et al., EDTA-assisted leaching of Pb and Cd from contaminated soil. Chemosphere, 167, (2017), 422-428.
  • [3] Koduru, J.R. and K.D. Lee, Evaluation of thiosemicarbazone derivative as chelating agent for the simultaneous removal and trace determination of Cd(II) and Pb(II) in food and water samples. Food Chemistry, 150, (2014), 1-8.
  • [4] Çelik, G.K., et al., 3,8-Diaminobenzo[c]Cinnoline Derivatived Graphene Oxide Modified Graphene Oxide Sensor for the Voltammetric Determination of Cd2+ and Pb2+. Electrocatalysis. 7, (2016), 207-214.
  • [5] Wu, Y., et al., The effective determination of Cd(ii) and Pb(ii) simultaneously based on an aluminum silicon carbide-reduced graphene oxide nanocomposite electrode. Analyst, 142, (2017), 2741-2747.
  • [6] Guo, Z., et al., Simultaneous determination of trace Cd(II), Pb(II) and Cu(II) by differential pulse anodic stripping voltammetry using a reduced graphene oxide-chitosan/poly-l-lysine nanocomposite modified glassy carbon electrode. Journal of Colloid and Interface Science. 190, (2017) 11-22.
  • [7] Wei, Y., et al., SnO2/Reduced Graphene Oxide Nanocomposite for the Simultaneous Electrochemical Detection of Cadmium(II), Lead(II), Copper(II), and Mercury(II): An Interesting Favorable Mutual Interference. The Journal of Physical Chemistry C. 116 (2012) 1034-1041.
  • [8] Xuan, X., M.F. Hossain, and J.Y. Park, A Fully Integrated and Miniaturized Heavy-metal-detection Sensor Based on Micro-patterned Reduced Graphene Oxide. Sci Rep. 6 (2016) 33125.
  • [9] White, R.L., et al., Comparative studies on copper adsorption by graphene oxide and functionalized graphene oxide nanoparticles. Journal of the Taiwan Institute of Chemical Engineers. 85 (2018), 18-28
  • [10] Meng, N., et al., Carboxylated graphene oxide functionalized with β-cyclodextrin—Engineering of a novel nanohybrid drug carrier. International Journal of Biological Macromolecules. 93 (2016) 117-122.
  • [11] Sun, X., et al., Nano-Graphene Oxide for Cellular Imaging and Drug Delivery. Nano Res, 1 (2008), 203-212.
  • [12] Yu, L., et al., Graphene oxide and carboxylated graphene oxide: Viable two-dimensional nanolabels for lateral flow immunoassays. Talanta. 165 (2017) 167-175.
  • [13] Kalfa, O.M., et al., Analysis of tincal ore waste by energy dispersive X-ray fluorescence (EDXRF) Technique. Journal of Quantitative Spectroscopy and Radiative Transfer 103, (2007) 424-427.
  • [14] Üstündağ, Z., İ. Üstündağ, and Y. Kağan Kadıoğlu, Multi-element analysis of pyrite ores using polarized energy-dispersive X-ray fluorescence spectrometry. Applied Radiation and Isotopes. 65, (2007) 809-813.
  • [15] Üstündağ, İ., et al., Geochemical compositions of trona samples by PEDXRF and their identification under confocal Raman spectroscopy: Beypazarı-Ankara, Turkey. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 254, (2007), 153-159.
  • [16] Paus, P.E., Determination of some heavy metals in sea water by atomic absorption spectrophotometry. Fresenius' Zeitschrift für analytische Chemie. 264, (1973), 118-122.
  • [17] Martinez–Lopez, C., M. Sakayanagi, and J.R. Almirall, Elemental analysis of packaging tapes by LA-ICP-MS and LIBS. Forensic Chemistry, 2018.[18] Xia, J., et al., Lead speciation analysis in rice by reversed phase chromatography with inductively coupled plasma mass spectrometry. Journal of Food Composition and Analysis. 60, (2017), 74-80.
  • [19] Silwana, B., et al., Amperometric determination of cadmium, lead, and mercury metal ions using a novel polymer immobilised horseradish peroxidase biosensor system. J Environ Sci Health A Tox Hazard Subst Environ Eng. 13, (2014), 1501-11.
  • [20] Wei, J., et al., Ultrasensitive and Ultraselective Impedimetric Detection of Cr(VI) Using Crown Ethers as High-Affinity Targeting Receptors. Analytical Chemistry, 2015. 87(3): p. 1991-1998.
  • [21] Üstündağ, İ., et al., Gold nanoparticle included graphene oxide modified electrode: Picomole detection of metal ions in seawater by stripping voltammetry. Journal of Analytical Chemistry, 2016. 71(7): p. 685-695.
  • [22] Erkal, A., et al., An Electrochemical Application of MnO2 Decorated Graphene Supported Glassy Carbon Ultrasensitive Electrode: Pb2+ and Cd2+ Analysis of Seawater Samples. Journal of the Electrochemical Society, 2015. 162(4): p. H213-H219.
  • [23] Üstündağ, İ. and A. Erkal, Determination of Dopamine in the Presence of Ascorbic Acid on Digitonin-Doped Coal Tar Pitch Carbonaceous Electrode. Sensors and Materials. 29, (2017), 85-94.
  • [24] Yavuz, S., et al., Carbonaceous Materials-12: a Novel Highly Sensitive Graphene Oxide-Based Carbon Electrode: Preparation, Characterization, and Heavy Metal Analysis in Food Samples. Food Analytical Methods. 9, (2016), 322-331.
  • [25] Erkal, A., et al., Electrografting and Surface Properties of Some Substituted Nitrophenols on Glassy Carbon Electrode and Simultaneous Pb2+ - Cd2+ Analysis via Assist of Graphene Oxide Terminated Surface. Journal of the Electrochemical Society. 161, (2014), H696-H704.
  • [26] Ye, Q.-Y., et al., Determination of Trace Cadmium in Rice by Flow Injection On-Line Filterless Precipitation-Dissolution Preconcentration Coupled with Flame Atomic Absorption Spectrometry. J. Agric. Food Chem. 51, (2003), 2111-2114.
  • [27] Muthoosamy, K., et al., Exceedingly biocompatible and thin-layered reduced graphene oxide nanosheets using an eco-friendly mushroom extract strategy. International Journal of Nanomedicine. 10 (2015), 1505-1519.
  • [28] Bocchetta, P., et al., Accurate Assessment of the Oxygen Reduction Electrocatalytic Activity of Mn/Polypyrrole Nanocomposites Based on Rotating Disk Electrode Measurements, Complemented with Multitechnique Structural Characterizations. Journal of Analytical Methods in Chemistry. 203, (2016), 1-16.
  • [29] Priya, T., et al., A novel voltammetric sensor for the simultaneous detection of Cd2+ and Pb2+ using graphene oxide/κ-carrageenan/l-cysteine nanocomposite. Carbohydrate Polymers. 182, (2018), 199-206.
  • [30] Wang, Z., et al., Electrochemical determination of lead and cadmium in rice by a disposable bismuth/electrochemically reduced graphene/ionic liquid composite modified screen-printed electrode. Sensors and Actuators B: Chemical. 199, (2014), 7-14.
  • [31] Vu, H.D., et al., Anodic stripping voltammetric determination of Cd2+ and Pb2+ using interpenetrated MWCNT/P1,5-DAN as an enhanced sensing interface. Ionics. 21, (2014), 571-578.
  • [32] Buica, G.-O., et al., Voltammetric sensing of lead and cadmium using poly(4-azulen-1-yl-2,6-bis(2-thienyl)pyridine) complexing films. Journal of Electroanalytical Chemistry. 693, (2013), 67-72.
  • [33] Huang, H., et al., Ultrasensitive and simultaneous detection of heavy metal ions based on three-dimensional graphene-carbon nanotubes hybrid electrode materials. Analytica Chimica Acta. 852,(2014), 45-54.
  • [34] Xiao, L., et al., An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II). Electrochimica Acta. 222, (2016), 1371-1377.
Year 2018, Volume: 6 Issue: 2, 96 - 109, 24.12.2018

Abstract

References

  • [1] Keawkim, K., et al., Determination of lead and cadmium in rice samples by sequential injection/anodic stripping voltammetry using a bismuth film/crown ether/Nafion modified screen-printed carbon electrode. Food Control, 31, (2013), 14-21.
  • [2] Qiao, J., et al., EDTA-assisted leaching of Pb and Cd from contaminated soil. Chemosphere, 167, (2017), 422-428.
  • [3] Koduru, J.R. and K.D. Lee, Evaluation of thiosemicarbazone derivative as chelating agent for the simultaneous removal and trace determination of Cd(II) and Pb(II) in food and water samples. Food Chemistry, 150, (2014), 1-8.
  • [4] Çelik, G.K., et al., 3,8-Diaminobenzo[c]Cinnoline Derivatived Graphene Oxide Modified Graphene Oxide Sensor for the Voltammetric Determination of Cd2+ and Pb2+. Electrocatalysis. 7, (2016), 207-214.
  • [5] Wu, Y., et al., The effective determination of Cd(ii) and Pb(ii) simultaneously based on an aluminum silicon carbide-reduced graphene oxide nanocomposite electrode. Analyst, 142, (2017), 2741-2747.
  • [6] Guo, Z., et al., Simultaneous determination of trace Cd(II), Pb(II) and Cu(II) by differential pulse anodic stripping voltammetry using a reduced graphene oxide-chitosan/poly-l-lysine nanocomposite modified glassy carbon electrode. Journal of Colloid and Interface Science. 190, (2017) 11-22.
  • [7] Wei, Y., et al., SnO2/Reduced Graphene Oxide Nanocomposite for the Simultaneous Electrochemical Detection of Cadmium(II), Lead(II), Copper(II), and Mercury(II): An Interesting Favorable Mutual Interference. The Journal of Physical Chemistry C. 116 (2012) 1034-1041.
  • [8] Xuan, X., M.F. Hossain, and J.Y. Park, A Fully Integrated and Miniaturized Heavy-metal-detection Sensor Based on Micro-patterned Reduced Graphene Oxide. Sci Rep. 6 (2016) 33125.
  • [9] White, R.L., et al., Comparative studies on copper adsorption by graphene oxide and functionalized graphene oxide nanoparticles. Journal of the Taiwan Institute of Chemical Engineers. 85 (2018), 18-28
  • [10] Meng, N., et al., Carboxylated graphene oxide functionalized with β-cyclodextrin—Engineering of a novel nanohybrid drug carrier. International Journal of Biological Macromolecules. 93 (2016) 117-122.
  • [11] Sun, X., et al., Nano-Graphene Oxide for Cellular Imaging and Drug Delivery. Nano Res, 1 (2008), 203-212.
  • [12] Yu, L., et al., Graphene oxide and carboxylated graphene oxide: Viable two-dimensional nanolabels for lateral flow immunoassays. Talanta. 165 (2017) 167-175.
  • [13] Kalfa, O.M., et al., Analysis of tincal ore waste by energy dispersive X-ray fluorescence (EDXRF) Technique. Journal of Quantitative Spectroscopy and Radiative Transfer 103, (2007) 424-427.
  • [14] Üstündağ, Z., İ. Üstündağ, and Y. Kağan Kadıoğlu, Multi-element analysis of pyrite ores using polarized energy-dispersive X-ray fluorescence spectrometry. Applied Radiation and Isotopes. 65, (2007) 809-813.
  • [15] Üstündağ, İ., et al., Geochemical compositions of trona samples by PEDXRF and their identification under confocal Raman spectroscopy: Beypazarı-Ankara, Turkey. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 254, (2007), 153-159.
  • [16] Paus, P.E., Determination of some heavy metals in sea water by atomic absorption spectrophotometry. Fresenius' Zeitschrift für analytische Chemie. 264, (1973), 118-122.
  • [17] Martinez–Lopez, C., M. Sakayanagi, and J.R. Almirall, Elemental analysis of packaging tapes by LA-ICP-MS and LIBS. Forensic Chemistry, 2018.[18] Xia, J., et al., Lead speciation analysis in rice by reversed phase chromatography with inductively coupled plasma mass spectrometry. Journal of Food Composition and Analysis. 60, (2017), 74-80.
  • [19] Silwana, B., et al., Amperometric determination of cadmium, lead, and mercury metal ions using a novel polymer immobilised horseradish peroxidase biosensor system. J Environ Sci Health A Tox Hazard Subst Environ Eng. 13, (2014), 1501-11.
  • [20] Wei, J., et al., Ultrasensitive and Ultraselective Impedimetric Detection of Cr(VI) Using Crown Ethers as High-Affinity Targeting Receptors. Analytical Chemistry, 2015. 87(3): p. 1991-1998.
  • [21] Üstündağ, İ., et al., Gold nanoparticle included graphene oxide modified electrode: Picomole detection of metal ions in seawater by stripping voltammetry. Journal of Analytical Chemistry, 2016. 71(7): p. 685-695.
  • [22] Erkal, A., et al., An Electrochemical Application of MnO2 Decorated Graphene Supported Glassy Carbon Ultrasensitive Electrode: Pb2+ and Cd2+ Analysis of Seawater Samples. Journal of the Electrochemical Society, 2015. 162(4): p. H213-H219.
  • [23] Üstündağ, İ. and A. Erkal, Determination of Dopamine in the Presence of Ascorbic Acid on Digitonin-Doped Coal Tar Pitch Carbonaceous Electrode. Sensors and Materials. 29, (2017), 85-94.
  • [24] Yavuz, S., et al., Carbonaceous Materials-12: a Novel Highly Sensitive Graphene Oxide-Based Carbon Electrode: Preparation, Characterization, and Heavy Metal Analysis in Food Samples. Food Analytical Methods. 9, (2016), 322-331.
  • [25] Erkal, A., et al., Electrografting and Surface Properties of Some Substituted Nitrophenols on Glassy Carbon Electrode and Simultaneous Pb2+ - Cd2+ Analysis via Assist of Graphene Oxide Terminated Surface. Journal of the Electrochemical Society. 161, (2014), H696-H704.
  • [26] Ye, Q.-Y., et al., Determination of Trace Cadmium in Rice by Flow Injection On-Line Filterless Precipitation-Dissolution Preconcentration Coupled with Flame Atomic Absorption Spectrometry. J. Agric. Food Chem. 51, (2003), 2111-2114.
  • [27] Muthoosamy, K., et al., Exceedingly biocompatible and thin-layered reduced graphene oxide nanosheets using an eco-friendly mushroom extract strategy. International Journal of Nanomedicine. 10 (2015), 1505-1519.
  • [28] Bocchetta, P., et al., Accurate Assessment of the Oxygen Reduction Electrocatalytic Activity of Mn/Polypyrrole Nanocomposites Based on Rotating Disk Electrode Measurements, Complemented with Multitechnique Structural Characterizations. Journal of Analytical Methods in Chemistry. 203, (2016), 1-16.
  • [29] Priya, T., et al., A novel voltammetric sensor for the simultaneous detection of Cd2+ and Pb2+ using graphene oxide/κ-carrageenan/l-cysteine nanocomposite. Carbohydrate Polymers. 182, (2018), 199-206.
  • [30] Wang, Z., et al., Electrochemical determination of lead and cadmium in rice by a disposable bismuth/electrochemically reduced graphene/ionic liquid composite modified screen-printed electrode. Sensors and Actuators B: Chemical. 199, (2014), 7-14.
  • [31] Vu, H.D., et al., Anodic stripping voltammetric determination of Cd2+ and Pb2+ using interpenetrated MWCNT/P1,5-DAN as an enhanced sensing interface. Ionics. 21, (2014), 571-578.
  • [32] Buica, G.-O., et al., Voltammetric sensing of lead and cadmium using poly(4-azulen-1-yl-2,6-bis(2-thienyl)pyridine) complexing films. Journal of Electroanalytical Chemistry. 693, (2013), 67-72.
  • [33] Huang, H., et al., Ultrasensitive and simultaneous detection of heavy metal ions based on three-dimensional graphene-carbon nanotubes hybrid electrode materials. Analytica Chimica Acta. 852,(2014), 45-54.
  • [34] Xiao, L., et al., An efficient electrochemical sensor based on three-dimensionally interconnected mesoporous graphene framework for simultaneous determination of Cd(II) and Pb(II). Electrochimica Acta. 222, (2016), 1371-1377.
There are 33 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

İlknur Üstündağ This is me

Aslı Erkal This is me

Zafer Üstündağ

Ali Osman Solak

Publication Date December 24, 2018
Published in Issue Year 2018 Volume: 6 Issue: 2

Cite

APA Üstündağ, İ., Erkal, A., Üstündağ, Z., Solak, A. O. (2018). Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MANAS Journal of Engineering, 6(2), 96-109.
AMA Üstündağ İ, Erkal A, Üstündağ Z, Solak AO. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN. December 2018;6(2):96-109.
Chicago Üstündağ, İlknur, Aslı Erkal, Zafer Üstündağ, and Ali Osman Solak. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering 6, no. 2 (December 2018): 96-109.
EndNote Üstündağ İ, Erkal A, Üstündağ Z, Solak AO (December 1, 2018) Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MANAS Journal of Engineering 6 2 96–109.
IEEE İ. Üstündağ, A. Erkal, Z. Üstündağ, and A. O. Solak, “Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”, MJEN, vol. 6, no. 2, pp. 96–109, 2018.
ISNAD Üstündağ, İlknur et al. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering 6/2 (December 2018), 96-109.
JAMA Üstündağ İ, Erkal A, Üstündağ Z, Solak AO. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN. 2018;6:96–109.
MLA Üstündağ, İlknur et al. “Electrochemical Detection of Cadmium and Lead in Rice on Manganese Dioxide Reinforced Carboxylated Graphene Oxide Nanofilm”. MANAS Journal of Engineering, vol. 6, no. 2, 2018, pp. 96-109.
Vancouver Üstündağ İ, Erkal A, Üstündağ Z, Solak AO. Electrochemical Detection of Cadmium and Lead in Rice on Manganese dioxide Reinforced Carboxylated Graphene Oxide Nanofilm. MJEN. 2018;6(2):96-109.

Manas Journal of Engineering 

16155