Research Article
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Year 2020, Volume: 8 Issue: 1, 1 - 10, 30.06.2020

Abstract

References

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  • Chia S.R, Ong H.C, Chew K.W, Show P.L, Phang S.-M et al. Sustainable approaches for algae utilisation in bioenergy production. Renewable Energy 2018; 129: 838-852.
  • El-Nagar G.A, Derr I, Fetyan A, Roth C. One-pot synthesis of a high performance chitosan-nickel oxyhydroxide nanocomposite for glucose fuel cell and electro-sensing applications. Applied Catalysis B: Environmental 2017; 204: 185-199.
  • Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells: A review. International journal of hydrogen Energy 2005; 30: 1297-1302. 5. Peighambardoust S.J, Rowshanzamir S, Amjadi M. Review of the proton exchange membranes for fuel cell applications. International journal of hydrogen energy 2010; 35: 9349-9384.
  • Hosseini H, Mahyari M, Bagheri A, Shaabani A. Pd and PdCo alloy nanoparticles supported on polypropylenimine dendrimer-grafted graphene: a highly efficient anodic catalyst for direct formic acid fuel cells. Journal of Power Sources 2014; 247: 70-77.
  • Brites Helú M.A, Fernandez W.V, Fernández J.L. Ordered Array Electrodes Fabricated by a Mask-Assisted Electron-Beam Method as Platforms for Studying Kinetic and Mass-Transport Phenomena on Electrocatalysts. ChemElectroChem 2018; 5: 2620-2629.
  • Ulas B, Caglar A, Kivrak A, Kivrak H. Atomic molar ratio optimization of carbon nanotube supported PdAuCo catalysts for ethylene glycol and methanol electrooxidation in alkaline media. Chemical Papers 2018; 73: 425-434.
  • Sahin O, Kivrak H. A comparative study of electrochemical methods on Pt–Ru DMFC anode catalysts: The effect of Ru addition. International Journal of Hydrogen Energy 2013; 38: 901-909.
  • Atbas D, Çağlar A, Kivrak H, Kivrak A. Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities. American Journal of Nanomaterials 2016; 4: 8-11.
  • Sahin O, Duzenli D, Kivrak H. An ethanol electrooxidation study on carbon-supported Pt-Ru nanoparticles for direct ethanol fuel cells. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 2016; 38: 628-634.
  • Ulas B, Caglar A, Sahin O, Kivrak H. Composition Dependent Activity of PdAgNi Alloy Catalysts for Formic Acid Electrooxidation. Journal of Colloid and Interface Science 2018; 532: 47-57.
  • Caglar A, Sahan T, Cogenli M.S, Yurtcan A.B, Aktas N, Kivrak H. A novel Central Composite Design based response surface methodology optimization study for the synthesis of Pd/CNT direct formic acid fuel cell anode catalyst. International Journal of Hydrogen Energy 2018; 43: 11002-11011.
  • Chen C, Xu H, Shang H, Jin L, Song T et al. Ultrafine PtCuRh nanowire catalysts with alleviated poisoning effect for efficient ethanol oxidation. Nanoscale 2019; 11: 20090-20095.
  • Wang Y, Zheng M, Sun H, Zhang X, Luan C et al. Catalytic Ru containing Pt3Mn nanocrystals enclosed with high-indexed facets: Surface alloyed Ru makes Pt more active than Ru particles for ethylene glycol oxidation. Applied Catalysis B: Environmental 2019; 253: 11-20.
  • Hosseini M.G, Rashidi N, Mahmoodi R, Omer M. Preparation of Pt/G and PtNi/G nanocatalysts with high electrocatalytic activity for borohydride oxidation and investigation of different operation condition on the performance of direct borohydride- hydrogen peroxide fuel cell. Materials Chemistry and Physics 2018; 208: 207-219.
  • Olu P.-Y, Barros C.R, Job N, Chatenet M. Electrooxidation of NaBH4 in Alkaline Medium on Well-defined Pt Nanoparticles Deposited onto Flat Glassy Carbon Substrate: Evaluation of the Effects of Pt Nanoparticle Size, Inter-Particle Distance, and Loading. Electrocatalysis 2014; 5: 288-300.
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  • Song C, Li B, Cheng K, Ye K, Zhu K et al. Synthesis and investigation of a high- activity catalyst: Au nanoparticles modified metalic Ti microrods for NaBH4 electrooxidation. International Journal of Hydrogen Energy 2018; 43: 3688-3696.
  • Ajmal S, Bibi I, Majid F, Ata S, Kamran K et al. Effect of Fe and Bi doping on LaCoO3 structural, magnetic, electric and catalytic properties. Journal of Materials Research and Technology 2019; 8: 4831-4842.
  • Bibi I, Hussain S, Majid F, Kamal S, Ata S et al. Structural, dielectric and magnetic studies of perovskite [Gd1− xMxCrO3 (M= La, Co, Bi)] nanoparticles: photocatalytic degradation of dyes. Zeitschrift für Physikalische Chemie 2019; 233: 1431-1445.
  • Majid F, Malik A, Ata S, Hussain Z, Bibi I et al. Structural and Optical Properties of Multilayer Heterostructure of CdTe/CdSe Thin Films. Zeitschrift für Physikalische Chemie 2019; 233: 1215-1231.
  • Majid F, Rauf J, Ata S, Bibi I, Yameen M et al. Hydrothermal Synthesis of Zinc Doped Nickel Ferrites: Evaluation of Structural, Magnetic and Dielectric Properties. Zeitschrift für Physikalische Chemie 2019; 233: 1411-1430.
  • Majid F, Nazir A, Ata S, Bibi I, Mehmood H.S et al. Effect of Hydrothermal Reaction Time on Electrical, Structural and Magnetic Properties of Cobalt Ferrite. Zeitschrift für Physikalische Chemie 2019; 234: 323-354.
  • Aal R.M.A, Gitru M.A, Essam Z.M. Novel synthetized near infrared cyanine dyes as sensitizer for dye sensitized solar cells based on nano-TiO2. Chemistry International 2017; 3: 358-367.
  • Pramanik H, Rathoure A.K. Electrooxidation study of NaBH4 in a membraneless microfluidic fuel cell with air breathing cathode for portable power application. International Journal of Hydrogen Energy 2017; 42: 5340-5350.
  • Yang F, Cheng K, Ye K, Wei X, Xiao X et al. High performance of Au nanothorns supported on Ni foam substrate as the catalyst for NaBH4 electrooxidation. Electrochimica Acta 2014; 115: 311-316.
  • Ye K, Ma X, Huang X, Zhang D, Cheng K et al. The optimal design of Co catalyst morphology on a three-dimensional carbon sponge with low cost, inducing better sodium borohydride electrooxidation activity. RSC Advances 2016; 6: 41608-41617.
  • Duan D, Yin X, Wang Q, Liu S, Wang Y. Performance evaluation of borohydride electrooxidation reaction with ternary alloy Au–Ni–Cu/C catalysts. Journal of Applied Electrochemistry 2018; 48: 835-847.
  • Šljukić B, Milikić J, Santos D.M.F, Sequeira C.A.C. Carbon-supported Pt0.75M0.25 (M=Ni or Co) electrocatalysts for borohydride oxidation. Electrochimica Acta 2013; 107: 577-583.
  • Jin W, Liu J, Wang Y, Yao Y, Gu J, Zou Z. Direct NaBH4–H2O2 fuel cell based on nanoporous gold leaves. International Journal of Hydrogen Energy 2013; 38: 10992- 10997.
  • Ojani R, Raoof J.-b, Valiollahi R. Pt nanoparticles/graphene paste electrode for sodium borohydride electrooxidation. Journal of Solid State Electrochemistry 2013; 17: 217-221.
  • Šljukić B, Milikić J, Santos D.M.F, Sequeira C.A.C, Macciò D et al. Electrocatalytic performance of Pt–Dy alloys for direct borohydride fuel cells. Journal of Power Sources 2014; 272: 335-343.
  • Oliveira R.C.P, Milikić J, Daş E, Yurtcan A.B, Santos D.M.F et al. Platinum/polypyrrole-carbon electrocatalysts for direct borohydride-peroxide fuel cells. Applied Catalysis B: Environmental 2018; 238: 454-464.
  • Pei F, Wang Y, Wang X, He P.Y, Liu L et al. Preparation and Performance of Highly Efficient Au Nanoparticles Electrocatalyst for the Direct Borohydride Fuel Cell. Fuel Cells 2011; 11: 595-602.
  • Santos D.M.F, Sequeira C.A.C. Cyclic voltammetry investigation of borohydride oxidation at a gold electrode. Electrochimica Acta 2010; 55: 6775-6781. 38. Olu P.-Y, Bonnefont A, Braesch G, Martin V, Savinova E. R et al. Influence of the concentration of borohydride towards hydrogen production and escape for borohydride oxidation reaction on Pt and Au electrodes – experimental and modelling insights. Journal of Power Sources 2018; 375: 300-309.
  • Yan P, Zhang D, Cheng K, Wang Y, Ye K et al. Preparation of Au nanoparticles modified TiO2/C core/shell nanowire array and its catalytic performance for NaBH4 oxidation. Journal of Electroanalytical Chemistry 2015; 745: 56-60.
  • Cheng K, Xu Y, Miao R.R, Yang F, Yin J.L et al. Pd Modified MmNi50.6Co10.2Mn5.4Al1.2 Alloy as the Catalyst of NaBH4 Electrooxidation. Fuel Cells 2012; 12: 869-875.
  • Braesch G, Bonnefont A, Martin V, Savinova E.R, Chatenet M. Borohydride oxidation reaction mechanisms and poisoning effects on Au, Pt and Pd bulk electrodes: From model (low) to direct borohydride fuel cell operating (high) concentrations. Electrochimica Acta 2018; 273: 483-494.
  • Cheng K, Jiang J, Kong S, Gao Y, Ye K et al. Pd nanoparticles support on rGO- C@TiC coaxial nanowires as a novel 3D electrode for NaBH4 electrooxidation. International Journal of Hydrogen Energy 2017; 42: 2943-2951.
  • Sanli A.E, Aytaç A, Uysal B.Z, Aksu M.L. Recovery of NaBH4 from BH3OH− hydrolyzed intermediate on the AgI surface treated with different electrochemical methods. Catalysis Today 2011; 170: 120-125.
  • Zhang D, Ye K, Cao D, Wang B, Cheng K et al. Co@MWNTs-Plastic: A novel electrode for NaBH4 oxidation. Electrochimica Acta 2015; 156: 102-107.
  • Zhang D, Ye K, Cheng K, Cao D, Yin J et al. High electrocatalytic activity of cobalt– multiwalled carbon nanotubes–cosmetic cotton nanostructures for sodium borohydride electrooxidation. International Journal of Hydrogen Energy 2014; 39: 9651-9657.
  • Guo S, Sun J, Zhang Z, Sheng A, Gao M et al. Study of the electrooxidation of borohydride on a directly formed CoB/Ni-foam electrode and its application in membraneless direct borohydride fuel cells. Journal of Materials Chemistry A 2017; 5: 15879-15890.
  • Simões M, Baranton S, Coutanceau C. Influence of bismuth on the structure and activity of Pt and Pd nanocatalysts for the direct electrooxidation of NaBH4. Electrochimica Acta 2010; 56: 580-591.
  • Wang B, Zhang D, Ye K, Cheng K, Cao D et al. Plastic supported platinum modified nickel electrode and its high electrocatalytic activity for sodium borohydride electrooxidation. Journal of Energy Chemistry 2015; 24: 497-502.
  • Iotov P.I, Kalcheva S.V, Kanazirski I.A. On the enhanced electrocatalytic performance of PtAu alloys in borohydride oxidation. Electrochimica Acta 2013; 108: 540-546.
  • Simões M, Baranton S, Coutanceau C. Electrooxidation of Sodium Borohydride at Pd, Au, and PdxAu1−x Carbon-Supported Nanocatalysts. The Journal of Physical Chemistry C 2009; 113: 13369-13376.
  • Guo M, Cheng Y, Yu Y, Hu J. Ni-Co nanoparticles immobilized on a 3D Ni foam template as a highly efficient catalyst for borohydride electrooxidation in alkaline medium. Applied Surface Science 2017; 416: 439-445.
  • Duan D, Liu H, Wang Q, Wang Y, Liu S. Kinetics of sodium borohydride direct oxidation on carbon supported Cu-Ag bimetallic nanocatalysts. Electrochimica Acta 2016; 198: 212-219.
  • Caglar A, Ulas B, Cogenli M.S, Yurtcan A.B, Kivrak H. Synthesis and characterization of Co, Zn, Mn, V modified Pd formic acid fuel cell anode catalysts. Journal of Electroanalytical Chemistry 2019; 850: 113402.
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Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading

Year 2020, Volume: 8 Issue: 1, 1 - 10, 30.06.2020

Abstract

At present, monometallic CNT supported Pd electrocatalysts (Pd/CNT) are prepared at varying Pd loadings via sodium borohydride (NaBH4) reduction method to investigate their NaBH4 electrooxidation activities. These monometallic Pd/CNT catalysts are characterized by X-ray Diffraction (XRD), N2 adsorption-desorption, Fourier-Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy-Energy Dispersive X-ray analysis (SEM-EDX). Characterization results are revealed that Pd/CNT metallic Pd with a face center cubic structure is detected. The crystallite size corresponding to (1 1 1 ) plane is found as 5.87 nm for 30% Pd/CNT catalyst. The average pore size, pore-volume, and Brunauer, Emmet ve Teller (BET) surface area of Pd/CNT are obtained as 24.5 nm, 0.93 cm³/g, and 129.48 cm2/g, respectively. From the SEM-EDX results, it indicates that the Pd metal is homogeneously distributed in the carbon structures. NaBH4 electrooxidation measurements are performed with cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS). The effect of Pd loading (0.1-70.0 %) for NaBH4 electrooxidation is investigated via CV. The 30% Pd/CNT catalyst exhibits the highest electrochemical activity with a current density of 16.5 mA cm-2. By altering Pd loading, catalyst surface electronic structure changes significantly, leading to enhanced NaBH4 electrooxidation activity. CA and EIS measurement results are agreement with CV results. As a conclusion, it is clear that Pd/CNT catalysts are promising catalysts for direct borohydride fuel cells.

References

  • Kurata M, Matsui N, Ikemoto Y, Tsuboi H. Do determinants of adopting solar home systems differ between households and micro-enterprises? Evidence from rural Bangladesh. Renewable Energy 2018; 129: 309-316.
  • Chia S.R, Ong H.C, Chew K.W, Show P.L, Phang S.-M et al. Sustainable approaches for algae utilisation in bioenergy production. Renewable Energy 2018; 129: 838-852.
  • El-Nagar G.A, Derr I, Fetyan A, Roth C. One-pot synthesis of a high performance chitosan-nickel oxyhydroxide nanocomposite for glucose fuel cell and electro-sensing applications. Applied Catalysis B: Environmental 2017; 204: 185-199.
  • Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells: A review. International journal of hydrogen Energy 2005; 30: 1297-1302. 5. Peighambardoust S.J, Rowshanzamir S, Amjadi M. Review of the proton exchange membranes for fuel cell applications. International journal of hydrogen energy 2010; 35: 9349-9384.
  • Hosseini H, Mahyari M, Bagheri A, Shaabani A. Pd and PdCo alloy nanoparticles supported on polypropylenimine dendrimer-grafted graphene: a highly efficient anodic catalyst for direct formic acid fuel cells. Journal of Power Sources 2014; 247: 70-77.
  • Brites Helú M.A, Fernandez W.V, Fernández J.L. Ordered Array Electrodes Fabricated by a Mask-Assisted Electron-Beam Method as Platforms for Studying Kinetic and Mass-Transport Phenomena on Electrocatalysts. ChemElectroChem 2018; 5: 2620-2629.
  • Ulas B, Caglar A, Kivrak A, Kivrak H. Atomic molar ratio optimization of carbon nanotube supported PdAuCo catalysts for ethylene glycol and methanol electrooxidation in alkaline media. Chemical Papers 2018; 73: 425-434.
  • Sahin O, Kivrak H. A comparative study of electrochemical methods on Pt–Ru DMFC anode catalysts: The effect of Ru addition. International Journal of Hydrogen Energy 2013; 38: 901-909.
  • Atbas D, Çağlar A, Kivrak H, Kivrak A. Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities. American Journal of Nanomaterials 2016; 4: 8-11.
  • Sahin O, Duzenli D, Kivrak H. An ethanol electrooxidation study on carbon-supported Pt-Ru nanoparticles for direct ethanol fuel cells. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 2016; 38: 628-634.
  • Ulas B, Caglar A, Sahin O, Kivrak H. Composition Dependent Activity of PdAgNi Alloy Catalysts for Formic Acid Electrooxidation. Journal of Colloid and Interface Science 2018; 532: 47-57.
  • Caglar A, Sahan T, Cogenli M.S, Yurtcan A.B, Aktas N, Kivrak H. A novel Central Composite Design based response surface methodology optimization study for the synthesis of Pd/CNT direct formic acid fuel cell anode catalyst. International Journal of Hydrogen Energy 2018; 43: 11002-11011.
  • Chen C, Xu H, Shang H, Jin L, Song T et al. Ultrafine PtCuRh nanowire catalysts with alleviated poisoning effect for efficient ethanol oxidation. Nanoscale 2019; 11: 20090-20095.
  • Wang Y, Zheng M, Sun H, Zhang X, Luan C et al. Catalytic Ru containing Pt3Mn nanocrystals enclosed with high-indexed facets: Surface alloyed Ru makes Pt more active than Ru particles for ethylene glycol oxidation. Applied Catalysis B: Environmental 2019; 253: 11-20.
  • Hosseini M.G, Rashidi N, Mahmoodi R, Omer M. Preparation of Pt/G and PtNi/G nanocatalysts with high electrocatalytic activity for borohydride oxidation and investigation of different operation condition on the performance of direct borohydride- hydrogen peroxide fuel cell. Materials Chemistry and Physics 2018; 208: 207-219.
  • Olu P.-Y, Barros C.R, Job N, Chatenet M. Electrooxidation of NaBH4 in Alkaline Medium on Well-defined Pt Nanoparticles Deposited onto Flat Glassy Carbon Substrate: Evaluation of the Effects of Pt Nanoparticle Size, Inter-Particle Distance, and Loading. Electrocatalysis 2014; 5: 288-300.
  • Zhang D, Wang G, Yuan Y, Li Y, Jiang S et al. Three-dimensional functionalized graphene networks modified Ni foam based gold electrode for sodium borohydride electrooxidation. International Journal of Hydrogen Energy 2016; 41: 11593-11598.
  • Martins M, Metin Ö, Sevim M, Šljukić B, Sequeira C.A.C et al. Monodisperse Pd nanoparticles assembled on reduced graphene oxide-Fe3O4 nanocomposites as electrocatalysts for borohydride fuel cells. International Journal of Hydrogen Energy 2018; 43: 10686-10697.
  • Song C, Li B, Cheng K, Ye K, Zhu K et al. Synthesis and investigation of a high- activity catalyst: Au nanoparticles modified metalic Ti microrods for NaBH4 electrooxidation. International Journal of Hydrogen Energy 2018; 43: 3688-3696.
  • Ajmal S, Bibi I, Majid F, Ata S, Kamran K et al. Effect of Fe and Bi doping on LaCoO3 structural, magnetic, electric and catalytic properties. Journal of Materials Research and Technology 2019; 8: 4831-4842.
  • Bibi I, Hussain S, Majid F, Kamal S, Ata S et al. Structural, dielectric and magnetic studies of perovskite [Gd1− xMxCrO3 (M= La, Co, Bi)] nanoparticles: photocatalytic degradation of dyes. Zeitschrift für Physikalische Chemie 2019; 233: 1431-1445.
  • Majid F, Malik A, Ata S, Hussain Z, Bibi I et al. Structural and Optical Properties of Multilayer Heterostructure of CdTe/CdSe Thin Films. Zeitschrift für Physikalische Chemie 2019; 233: 1215-1231.
  • Majid F, Rauf J, Ata S, Bibi I, Yameen M et al. Hydrothermal Synthesis of Zinc Doped Nickel Ferrites: Evaluation of Structural, Magnetic and Dielectric Properties. Zeitschrift für Physikalische Chemie 2019; 233: 1411-1430.
  • Majid F, Nazir A, Ata S, Bibi I, Mehmood H.S et al. Effect of Hydrothermal Reaction Time on Electrical, Structural and Magnetic Properties of Cobalt Ferrite. Zeitschrift für Physikalische Chemie 2019; 234: 323-354.
  • Aal R.M.A, Gitru M.A, Essam Z.M. Novel synthetized near infrared cyanine dyes as sensitizer for dye sensitized solar cells based on nano-TiO2. Chemistry International 2017; 3: 358-367.
  • Pramanik H, Rathoure A.K. Electrooxidation study of NaBH4 in a membraneless microfluidic fuel cell with air breathing cathode for portable power application. International Journal of Hydrogen Energy 2017; 42: 5340-5350.
  • Yang F, Cheng K, Ye K, Wei X, Xiao X et al. High performance of Au nanothorns supported on Ni foam substrate as the catalyst for NaBH4 electrooxidation. Electrochimica Acta 2014; 115: 311-316.
  • Ye K, Ma X, Huang X, Zhang D, Cheng K et al. The optimal design of Co catalyst morphology on a three-dimensional carbon sponge with low cost, inducing better sodium borohydride electrooxidation activity. RSC Advances 2016; 6: 41608-41617.
  • Duan D, Yin X, Wang Q, Liu S, Wang Y. Performance evaluation of borohydride electrooxidation reaction with ternary alloy Au–Ni–Cu/C catalysts. Journal of Applied Electrochemistry 2018; 48: 835-847.
  • Šljukić B, Milikić J, Santos D.M.F, Sequeira C.A.C. Carbon-supported Pt0.75M0.25 (M=Ni or Co) electrocatalysts for borohydride oxidation. Electrochimica Acta 2013; 107: 577-583.
  • Jin W, Liu J, Wang Y, Yao Y, Gu J, Zou Z. Direct NaBH4–H2O2 fuel cell based on nanoporous gold leaves. International Journal of Hydrogen Energy 2013; 38: 10992- 10997.
  • Ojani R, Raoof J.-b, Valiollahi R. Pt nanoparticles/graphene paste electrode for sodium borohydride electrooxidation. Journal of Solid State Electrochemistry 2013; 17: 217-221.
  • Šljukić B, Milikić J, Santos D.M.F, Sequeira C.A.C, Macciò D et al. Electrocatalytic performance of Pt–Dy alloys for direct borohydride fuel cells. Journal of Power Sources 2014; 272: 335-343.
  • Oliveira R.C.P, Milikić J, Daş E, Yurtcan A.B, Santos D.M.F et al. Platinum/polypyrrole-carbon electrocatalysts for direct borohydride-peroxide fuel cells. Applied Catalysis B: Environmental 2018; 238: 454-464.
  • Pei F, Wang Y, Wang X, He P.Y, Liu L et al. Preparation and Performance of Highly Efficient Au Nanoparticles Electrocatalyst for the Direct Borohydride Fuel Cell. Fuel Cells 2011; 11: 595-602.
  • Santos D.M.F, Sequeira C.A.C. Cyclic voltammetry investigation of borohydride oxidation at a gold electrode. Electrochimica Acta 2010; 55: 6775-6781. 38. Olu P.-Y, Bonnefont A, Braesch G, Martin V, Savinova E. R et al. Influence of the concentration of borohydride towards hydrogen production and escape for borohydride oxidation reaction on Pt and Au electrodes – experimental and modelling insights. Journal of Power Sources 2018; 375: 300-309.
  • Yan P, Zhang D, Cheng K, Wang Y, Ye K et al. Preparation of Au nanoparticles modified TiO2/C core/shell nanowire array and its catalytic performance for NaBH4 oxidation. Journal of Electroanalytical Chemistry 2015; 745: 56-60.
  • Cheng K, Xu Y, Miao R.R, Yang F, Yin J.L et al. Pd Modified MmNi50.6Co10.2Mn5.4Al1.2 Alloy as the Catalyst of NaBH4 Electrooxidation. Fuel Cells 2012; 12: 869-875.
  • Braesch G, Bonnefont A, Martin V, Savinova E.R, Chatenet M. Borohydride oxidation reaction mechanisms and poisoning effects on Au, Pt and Pd bulk electrodes: From model (low) to direct borohydride fuel cell operating (high) concentrations. Electrochimica Acta 2018; 273: 483-494.
  • Cheng K, Jiang J, Kong S, Gao Y, Ye K et al. Pd nanoparticles support on rGO- C@TiC coaxial nanowires as a novel 3D electrode for NaBH4 electrooxidation. International Journal of Hydrogen Energy 2017; 42: 2943-2951.
  • Sanli A.E, Aytaç A, Uysal B.Z, Aksu M.L. Recovery of NaBH4 from BH3OH− hydrolyzed intermediate on the AgI surface treated with different electrochemical methods. Catalysis Today 2011; 170: 120-125.
  • Zhang D, Ye K, Cao D, Wang B, Cheng K et al. Co@MWNTs-Plastic: A novel electrode for NaBH4 oxidation. Electrochimica Acta 2015; 156: 102-107.
  • Zhang D, Ye K, Cheng K, Cao D, Yin J et al. High electrocatalytic activity of cobalt– multiwalled carbon nanotubes–cosmetic cotton nanostructures for sodium borohydride electrooxidation. International Journal of Hydrogen Energy 2014; 39: 9651-9657.
  • Guo S, Sun J, Zhang Z, Sheng A, Gao M et al. Study of the electrooxidation of borohydride on a directly formed CoB/Ni-foam electrode and its application in membraneless direct borohydride fuel cells. Journal of Materials Chemistry A 2017; 5: 15879-15890.
  • Simões M, Baranton S, Coutanceau C. Influence of bismuth on the structure and activity of Pt and Pd nanocatalysts for the direct electrooxidation of NaBH4. Electrochimica Acta 2010; 56: 580-591.
  • Wang B, Zhang D, Ye K, Cheng K, Cao D et al. Plastic supported platinum modified nickel electrode and its high electrocatalytic activity for sodium borohydride electrooxidation. Journal of Energy Chemistry 2015; 24: 497-502.
  • Iotov P.I, Kalcheva S.V, Kanazirski I.A. On the enhanced electrocatalytic performance of PtAu alloys in borohydride oxidation. Electrochimica Acta 2013; 108: 540-546.
  • Simões M, Baranton S, Coutanceau C. Electrooxidation of Sodium Borohydride at Pd, Au, and PdxAu1−x Carbon-Supported Nanocatalysts. The Journal of Physical Chemistry C 2009; 113: 13369-13376.
  • Guo M, Cheng Y, Yu Y, Hu J. Ni-Co nanoparticles immobilized on a 3D Ni foam template as a highly efficient catalyst for borohydride electrooxidation in alkaline medium. Applied Surface Science 2017; 416: 439-445.
  • Duan D, Liu H, Wang Q, Wang Y, Liu S. Kinetics of sodium borohydride direct oxidation on carbon supported Cu-Ag bimetallic nanocatalysts. Electrochimica Acta 2016; 198: 212-219.
  • Caglar A, Ulas B, Cogenli M.S, Yurtcan A.B, Kivrak H. Synthesis and characterization of Co, Zn, Mn, V modified Pd formic acid fuel cell anode catalysts. Journal of Electroanalytical Chemistry 2019; 850: 113402.
  • Caglar A, Kivrak H. Highly active carbon nanotube supported PdAu alloy catalysts for ethanol electrooxidation in alkaline environment. International Journal of Hydrogen Energy 2019; 44: 11734-11743.
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There are 64 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

Hilal Demir Kıvrak 0000-0001-8001-7854

Aykut Caglar This is me 0000-0002-0681-1096

Tulin Avcı Hansu This is me 0000-0001-5441-4696

Ömer Şahin 0000-0003-4575-3762

Publication Date June 30, 2020
Published in Issue Year 2020 Volume: 8 Issue: 1

Cite

APA Demir Kıvrak, H., Caglar, A., Avcı Hansu, T., Şahin, Ö. (2020). Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading. MANAS Journal of Engineering, 8(1), 1-10.
AMA Demir Kıvrak H, Caglar A, Avcı Hansu T, Şahin Ö. Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading. MJEN. June 2020;8(1):1-10.
Chicago Demir Kıvrak, Hilal, Aykut Caglar, Tulin Avcı Hansu, and Ömer Şahin. “Carbon Nanotube Supported Direct Borohydride Fuel Cell Anode Catalysts: The Effect of Catalyst Loading”. MANAS Journal of Engineering 8, no. 1 (June 2020): 1-10.
EndNote Demir Kıvrak H, Caglar A, Avcı Hansu T, Şahin Ö (June 1, 2020) Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading. MANAS Journal of Engineering 8 1 1–10.
IEEE H. Demir Kıvrak, A. Caglar, T. Avcı Hansu, and Ö. Şahin, “Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading”, MJEN, vol. 8, no. 1, pp. 1–10, 2020.
ISNAD Demir Kıvrak, Hilal et al. “Carbon Nanotube Supported Direct Borohydride Fuel Cell Anode Catalysts: The Effect of Catalyst Loading”. MANAS Journal of Engineering 8/1 (June 2020), 1-10.
JAMA Demir Kıvrak H, Caglar A, Avcı Hansu T, Şahin Ö. Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading. MJEN. 2020;8:1–10.
MLA Demir Kıvrak, Hilal et al. “Carbon Nanotube Supported Direct Borohydride Fuel Cell Anode Catalysts: The Effect of Catalyst Loading”. MANAS Journal of Engineering, vol. 8, no. 1, 2020, pp. 1-10.
Vancouver Demir Kıvrak H, Caglar A, Avcı Hansu T, Şahin Ö. Carbon nanotube supported direct borohydride fuel cell anode catalysts: the effect of catalyst loading. MJEN. 2020;8(1):1-10.

Manas Journal of Engineering 

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