Year 2020, Volume 8 , Issue 1, Pages 22 - 27 2020-06-30

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Nevroz ASLAN ERTAŞ [1] , Arif KIVRAK [2]


In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids form the new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl-1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reaction between 2 and arylboronic acids give a new rearrangement reaction involving free radicals. Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones. This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.
ferrocene, naphthoquinone, rearrangement reactions
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Primary Language en
Subjects Engineering
Journal Section Research Article
Authors

Orcid: 0000-0003-3590-5961
Author: Nevroz ASLAN ERTAŞ
Institution: VAN YÜZÜNCÜ YIL ÜNİVERSİTESİ, FEN FAKÜLTESİ
Country: Turkey


Orcid: 0000-0003-4770-2686
Author: Arif KIVRAK (Primary Author)
Institution: VAN YÜZÜNCÜ YIL ÜNİVERSİTESİ, FEN FAKÜLTESİ
Country: Turkey


Supporting Institution TUBITAK
Project Number 114Z042
Thanks We want to express our thanks to the Scientific and Technical Research Council of Turkey (TUBİTAK-114Z042) for financial supports of Microwave Reactor and Van Yüzüncü Yil University (FBA-2019-7910) for financial supports of chemicals. N. A. also thanks to YÖK 100/2000 for scholarships.
Dates

Publication Date : June 30, 2020

Bibtex @research article { mjen744852, journal = {MANAS Journal of Engineering}, issn = {1694-7398}, eissn = {1694-7398}, address = {}, publisher = {Kyrgyz-Turkish Manas University}, year = {2020}, volume = {8}, pages = {22 - 27}, doi = {}, title = {Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones}, key = {cite}, author = {Aslan Ertaş, Nevroz and Kıvrak, Arif} }
APA Aslan Ertaş, N , Kıvrak, A . (2020). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MANAS Journal of Engineering , 8 (1) , 22-27 . Retrieved from https://dergipark.org.tr/en/pub/mjen/issue/55261/744852
MLA Aslan Ertaş, N , Kıvrak, A . "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones". MANAS Journal of Engineering 8 (2020 ): 22-27 <https://dergipark.org.tr/en/pub/mjen/issue/55261/744852>
Chicago Aslan Ertaş, N , Kıvrak, A . "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones". MANAS Journal of Engineering 8 (2020 ): 22-27
RIS TY - JOUR T1 - Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones AU - Nevroz Aslan Ertaş , Arif Kıvrak Y1 - 2020 PY - 2020 N1 - DO - T2 - MANAS Journal of Engineering JF - Journal JO - JOR SP - 22 EP - 27 VL - 8 IS - 1 SN - 1694-7398-1694-7398 M3 - UR - Y2 - 2020 ER -
EndNote %0 MANAS Journal of Engineering Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones %A Nevroz Aslan Ertaş , Arif Kıvrak %T Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones %D 2020 %J MANAS Journal of Engineering %P 1694-7398-1694-7398 %V 8 %N 1 %R %U
ISNAD Aslan Ertaş, Nevroz , Kıvrak, Arif . "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones". MANAS Journal of Engineering 8 / 1 (June 2020): 22-27 .
AMA Aslan Ertaş N , Kıvrak A . Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MJEN. 2020; 8(1): 22-27.
Vancouver Aslan Ertaş N , Kıvrak A . Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. MANAS Journal of Engineering. 2020; 8(1): 27-22.