Year 2020, Volume 8 , Issue 2, Pages 99 - 105 2020-12-21

Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels

Tuba ERŞEN DUDU [1]


p(DMAAm-co-APTMACl) based hydrogels were synthesized at different molar ratios by the redox polymerization technique using N,N-Dimethylacrylamide (DMAAm) and 3-acrlylamidopropil-trimethyl ammonium chloride (APTMACl) monomers and a crosslinker. In this study was aimed to improve the swelling properties and dye sorption of the prepared hydrogels. The balance swelling values of hydrogels were determined by the gravimetric method in deionized water and different pH values, and their structural characterizations were carried out by Fourier transform infrared spectroscopy (FT-IR) and thermal gravimetric analysis (TGA) techniques. Sorption efficiencies and sorption capacities of the synthesized hydrogels were determined using aqueous solutions containing phenol red dye at 25°C. In sorption studies, the effects of different concentrations (5-50 ppm) and different pH values (2-12) on sorption were examined. When the swelling analysis in deionized water was examined, it was determined that there was a significant increase in the balance swelling value of p(DMAAm-co-APTMACl) based hydrogel as the mole ratio of APTMACl increased. In addition, the increase in the molar ratio of APTMACl was found to increase the phenol red dye sorption capacity and removal percentage. It was observed that p(DMAAm-co-APTMACl) (2:8) based hydrogel had a maximum sorption capacity in the range of 5-50 ppm and reached 122.2 mg/g. Experimental data showed that the synthesized p (DMAAm-co-APTMACl) based hydrogel was effective in removing dye from wastewater and could be increased of dyestuff removal by synthesizing at different molar ratios.
N,N-Dimethylacrylamide, 3-Acrlylamidopropil-Trimethyl Ammonium Chloride, Hydrogel, Phenol Red, Sorption
  • [1] Gong R.M., Li M., Yang C., Sun Y.Z., Chen J., “Removal of cationic dyes from aqueous solution by adsorption on peanut hull”, Journal of Hazard Mater, 121, (2005), 247-250.
  • [2] Sudipta C., Dae S.L., Min W.L., Seung H.W., “Congo red adsorption from aqueous solutions by using chitosan hydrogel beads impregnated with nonionic or anionic surfactant”, Bioresource Technology, 100, (2009), 3862-3868.
  • [3] Wen-Tien T., Kuo-Jong H., Hsin-Chieh H., “Adsorption of organic compounds from aqueous solution onto the synthesized zeolite”, Journal of Hazardous Materials, 166, (2009), 635-641.
  • [4] Aksakal O., Ucun H., “Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L”, Journal of Hazardous Materials, 181, (2010), 666-672.
  • [5] Deveci T., Unyayar A., Mazmanci M.A., “Production of Remazol Brilliant Blue R decolourising oxygenase from the culture filtrate of Funalia trogii ATCC 200800”, Journal of Molecular Catalysis B: Enzymatic, 30, (2004), 25-32.
  • [6] Badu M., Boateng I.W., Boadi N.O., “Evaluation of adsorption of textile dyes by wood sawdust”, Research Journal of Physical and Applied Sciences, 3(1) (2014), 6-14.
  • [7] Dulman V., Cucu-Man S.M., “Sorption of some textile dyes by beech wood sawdust”, Journal of Hazardous Materials, 162, (2009), 1457-1464.
  • [8] Yang Y., Wyatt D.T., Bahorshky M., “Decolorization of dyes using UV/H2O2 photochemical oxidation”, Textile Chemist and Colorist, 30, (1998), 27-35.
  • [9] Konsowa A.H., “Decolorization of wastewater containing direct dye by ozonation in a batch bubble column reactor”, Desalination, 158, (2003), 233-240.
  • [10] Ong S.A, Toorisaka E., Hirata M., Hano T., “Treatment of azo dye orange II in aerobic and anaerobic-SBR systems”, Process Biochemistry, 40, (2005), 2097-2914.
  • [11] Kim T.H., Park C., Kim S., “Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration”, Journal of Cleaner Production, 13, (2005), 779-786.
  • [12] Shirsath D.S., Shrivastava V.S., “Removal of hazardous dye Ponceau-S by using chitin: An organic bioadsorbent”, African Journal of Environmental Science and Technology, 6(2), (2012), 115-124.
  • [13] Mohsen M., Maziad N.A., Gomaa E., Hassan Aly E., Mohammed R., “Characterization of some hydrogels used in water purification: correlation of swelling and free-volume properties”, Open Journal of Organic Polymer Materials, 5, (2015), 79-88.
  • [14] Kavaklı P.A., Yılmaz Z., Şen M., “Investigation of heavy metal ion adsorption characteristics of poly(N,N Dimethylamino Ethylmethacrylate) hydrogels”, Separation Science and Technology, 42, (2007), 1245-1254.
  • [15] Al-qudah Y.H.F., Mahmoud G.A., Abdel Khalek M.A., “Radiation crosslinked poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions”, Journal of Radiation Research and Applied Sciences, 7, (2014), 135-145.
  • [16] Wang W.B., Huang D.J., Kang Y.R., Wang A.Q., “One-step in situ fabrication of a granular semi-IPN hydrogel based on chitosan and gelatin for fast and efficient adsorption of Cu2+ ion”, Colloids and Surfaces B: Biointerfaces, 106, (2013), 51-59.
  • [17] Demirbilek C., Özdemir Dinc C., “Synthesis of diethylaminoethyl dextran hydrogel and its heavy metal ion adsorption characteristics”, Carbohydrate Polymers, 90, (2012), 1159-1167.
  • [18] Ersen Dudu T., Alpaslan D., Uzun Y., Aktas N., “Utilization of hydrogel-fungus composites as absorbents for removal of textile dyes from aqueous media”, International Journal of Environmental Research, 11, (2017), 557-568.
  • [19] Ersen Dudu T., Alpaslan D., Aktas N., “Urea uptake and release by novel macrogels from dimethylacrylamide”, Communications in Soil Science and Plant Analysis, 50, (2019), 2278-2293.
  • [20] Chang C., Duan B., Cai J., Zhang L., “Superabsorbent hydrogels based on cellulose for smart swelling and controllable delivery”, European Polymer Journal, 46, (2010), 92-100.
  • [21] Olak T., Turan A., Alpaslan D., Ersen Dudu T., Aktas N., “Developing poly(Agar-co-Glycerol-co-Thyme Oil) based Organo-hydrogels for the controlled drug release applications”, Journal of Drug Delivery Science and Technology, (2020), https://doi.org/10.1016/j.jddst.2020.102088.
  • [22] Alpaslan D., Ersen Dudu T., Aktas N., “Synthesis of smart food packaging from poly(gelatin-co-dimethyl acrylamide)/citric acid-red apple peel extract”, Soft Materials, (2020), https://doi.org/10.1080/1539445X.2020.1765802.
  • [23] Ersen Dudu T., Sahiner M., Alpaslan D., Demirci S., Aktas N., “Removal of As(V), Cr(III) and Cr(VI) from aqueous environments by poly(acrylonitril-co-acrylamidopropyl-trimethyl ammonium chloride)-based hydrogels”, Journal of environmental management, 161, (2015), 243-251.
  • [24] Kundakcı S., Öğüt H.G., Üzüm Ö.B., Karadağ E., “Equilibrium swelling characterization and dye uptake studies of acrylamide-co-methylenesuccinic acid hydrogels and semi-IPNs with PEG”, Polymer-Plastic Technology and Engineering, 50, (2011), 947-956.
  • [25] Yanfeng C., Min Y., “Swelling kinetics and stimuli-responsiveness of poly(DMAEMA) hydrogels prepared by UV-irradiation”, Radiation Physics and Chemistry, 61, (2001), 65-68.
  • [26] Ji F., Li C., Tang B., Xu J., Lu G., Liu P., “Preparation of cellulose acetate/zeolite composite fiber and its adsorption behavior for heavy metal ions in aqueous solution”, Chemical Engineering Journal, 209, (2012), 325-333.
  • [27] Kurniawan A., Sisnandy V.O.A., Trilestari K., Sunarso J., Indraswati N., Ismadji S., “Performance of durian shell waste as high capacity biosorbent for Cr(VI) removal from synthetic wastewater”, Ecological Engineering, 37, (2011), 940-947.
  • [28] Maziad N.A., Mohsen M., Gomaa E., Mohammed R., “Radiation copolymerization of hydrogels based in polyacrylic acid/polyvinyl alcohol applied in water treatment processes”, Journal of Materials Science and Engineering A, 5(11-12), (2015), 381-390.
  • [29] Kuang Y., Zhang X., Zhou S., “Adsorption of methylene blue in water onto activated carbon by surfactant modification”, Water, 12, (2020), 587. doi:10.3390/w12020587.
  • [30] Langmuir I., “The adsorption of gases on plane surfaces of glass, mica and platinum”, Journal of the American Chemical Society, 40, (1918), 1361.
  • [31] Freundlich H.M.F., “Uber die adsorption in losungen”, Zeitschrift für Physikalische Chemie, 57, (1906), 385-470.
  • [32] Alpaslan D., Ersen Dudu T., Sahiner N., Aktas N., “Synthesis and preparation of responsive poly(Dimethyl acrylamide/gelatin and pomegranat extract) as a novel food packaging material”, Materials Science & Engineering C, 108, (2020), 110339.
  • [33] Alpaslan D., Ersen Dudu T., Aktas N., “Synthesis, Characterization and Modification of Novel Food Packaging Material from Dimethyl acrylamide/Gelatin and Purple Cabbage Extract”, MANAS Journal of Engineering, 6(2), (2018), 110-128.
  • [34] Khare A.R., Peppas N.A., “Swelling/deswelling of anionic copolymer gels”, Biomaterials, 16(7), (1995), 559-567.
  • [35] Aydınoğlu D., “Investigation of pH-dependent swelling behavior and kinetic parameters of novel poly(acrylamide-co-acrylic acid) hydrogels with spirulina”, e-Polymers, 15(2), (2015), 81-93.
  • [36] Nethaji S., Sivasamy A., Mandal A.B., “Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass”, International Journal of Environmental Science and Technology, 10, (2013), 231-242.
Primary Language en
Subjects Engineering
Journal Section Research Article
Authors

Orcid: 0000-0001-5564-2834
Author: Tuba ERŞEN DUDU (Primary Author)
Institution: Van Yüzüncü Yıl Üniversitesi
Country: Turkey


Dates

Publication Date : December 21, 2020

Bibtex @research article { mjen799287, journal = {MANAS Journal of Engineering}, issn = {1694-7398}, eissn = {1694-7398}, address = {}, publisher = {Kyrgyz-Turkish Manas University}, year = {2020}, volume = {8}, pages = {99 - 105}, doi = {10.51354/mjen.799287}, title = {Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels}, key = {cite}, author = {Erşen Dudu, Tuba} }
APA Erşen Dudu, T . (2020). Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels . MANAS Journal of Engineering , 8 (2) , 99-105 . DOI: 10.51354/mjen.799287
MLA Erşen Dudu, T . "Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels" . MANAS Journal of Engineering 8 (2020 ): 99-105 <https://dergipark.org.tr/en/pub/mjen/issue/58226/799287>
Chicago Erşen Dudu, T . "Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels". MANAS Journal of Engineering 8 (2020 ): 99-105
RIS TY - JOUR T1 - Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels AU - Tuba Erşen Dudu Y1 - 2020 PY - 2020 N1 - doi: 10.51354/mjen.799287 DO - 10.51354/mjen.799287 T2 - MANAS Journal of Engineering JF - Journal JO - JOR SP - 99 EP - 105 VL - 8 IS - 2 SN - 1694-7398-1694-7398 M3 - doi: 10.51354/mjen.799287 UR - https://doi.org/10.51354/mjen.799287 Y2 - 2020 ER -
EndNote %0 MANAS Journal of Engineering Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels %A Tuba Erşen Dudu %T Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels %D 2020 %J MANAS Journal of Engineering %P 1694-7398-1694-7398 %V 8 %N 2 %R doi: 10.51354/mjen.799287 %U 10.51354/mjen.799287
ISNAD Erşen Dudu, Tuba . "Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels". MANAS Journal of Engineering 8 / 2 (December 2020): 99-105 . https://doi.org/10.51354/mjen.799287
AMA Erşen Dudu T . Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels. MJEN. 2020; 8(2): 99-105.
Vancouver Erşen Dudu T . Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels. MANAS Journal of Engineering. 2020; 8(2): 99-105.
IEEE T. Erşen Dudu , "Removal of anionic phenol red from water solution in the batch system by using N,N-dimethylacrylamide and 3-acrlylamidopropil-trimethyl ammonium chloride-based polymeric hydrogels", MANAS Journal of Engineering, vol. 8, no. 2, pp. 99-105, Dec. 2020, doi:10.51354/mjen.799287