Research Article
BibTex RIS Cite

Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology

Year 2020, Volume: 8 Issue: 2, 125 - 131, 21.12.2020
https://doi.org/10.51354/mjen.800161

Abstract

In the present work, the removal of Zn(II) ions from aquatic environments onto 3-mercaptopropyl trimethoxysilane modified kaolin (MK) was investigated in a batch system. Moreover, the optimization and effects of independent parameters such as pH, initial Zn(II) concentration (Co, mg/L) and contact time (min) on the uptake of Zn(II) onto MK were examined by response surface methodology (RSM). Central composite design (CCD) in RSM, the most popular statistical technique, was successfully applied to optimize and model the selected parameters (pH, Co, contact time) for Zn(II)% adsorption onto MK. The number of experiments based on CDD was 20, a total of 20 sets which included fourteen factorial points and six center points were performed to obtain the maximum Zn(II) uptake from aqueous solutions. The optimum points obtained from CCD were 6.39, 50.09 mg/L and 76.10 min for pH, Co, and contact time, in their given order. In these optimal conditions, the maximum removal percentage was found to be 86.19%. The results indicated that the removal yield of Zn(II) from aqueous media onto MK was successfully performed by CCD in RSM. It can be concluded that MK is also a promising material for the uptake of other heavy metals similar to Zn.

References

  • Vojoudi H., Badiei A., Amiri A., Banaei A., Ziarani G.M., Schenk-Joß K., "Pre-concentration of Zn(II) ions from aqueous solutions using meso-porous pyridine-enrobed magnetite nanostructures", Food Chemistry, 257, (2018), 189-195.
  • Mousavi S.J., Parvini M., Ghorbani M., "Experimental design data for the zinc ions adsorption based on mesoporous modified chitosan using central composite design method", Carbohydrate Polymers, 188, (2018), 197-212.
  • Karri R.R., Sahu J.N., "Modeling and optimization by particle swarm embedded neural network for adsorption of zinc (II) by palm kernel shell based activated carbon from aqueous environment", Journal of Environmental Management, 206, (2018), 178-191.
  • Shanmugaprakash M., Venkatachalam S., Rajendran K., Pugazhendhi A., "Biosorptive removal of Zn(II) ions by Pongamia oil cake (Pongamia pinnata) in batch and fixed-bed column studies using response surface methodology and artificial neural network", Journal of Environmental Management, 227, (2018), 216-228.
  • Ahmadi A., Heidarzadeh S., Mokhtari A.R., Darezereshki E., Harouni H.A., "Optimization of heavy metal removal from aqueous solutions by maghemite (γ-Fe2O3) nanoparticles using response surface methodology", Journal of Geochemical Exploration, 147, (2014), 151-158.
  • Yılmaz Ş., Zengin A., Şahan T., "A novel material poly(N-acryloyl-L-serine)-brush grafted kaolin for efficient elimination of malachite green dye from aqueous environments", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 601, (2020), 125041.
  • Dev V.V., Baburaj G., Antony S., Arun V., Krishnan K.A., "Zwitterion-chitosan bed for the simultaneous immobilization of Zn(II), Cd(II), Pb(II) and Cu(II) from multi-metal aqueous systems", Journal of Cleaner Production, 255, (2020), 120309.
  • Corda N., Kini M.S., "Recent studies in adsorption of Pb(II), Zn(II) and Co(II) using conventional and modified materials:a review", Separation Science and Technology, 55, (2020), 2679-2698.
  • Olu-Owolabi B.I., Unuabonah E.I., "Adsorption of Zn2+ and Cu2+ onto sulphate and phosphate-modified bentonite", Applied Clay Science, 51, (2011), 170-173.
  • Jemima W.S., Magesan P., Chiranjeevi P., Umapathy M.J., "Sorption properties of organo modified montmorillonite clay for the reclamation of chromium (VI) from waste water", Silicon, 11, (2019), 925-933.
  • Bezerra M.A., Santelli R.E., Oliveira E.P., Villar L.S., Escaleira L.A., "Response surface methodology (RSM) as a tool for optimization in analytical chemistry", Talanta, 76, (2008), 965-977.
  • Yılmaz Ş., Şahan T., Karabakan A., "Response surface approach for optimization of Hg(II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution", Korean Journal of Chemical Engineering, 34, (2017), 2225-2235.
  • Liu X., Han B., Su C.-l., Han Q., Chen K.-j., Chen Z.-q., "Optimization and mechanisms of biosorption process of Zn(II) on rape straw powders in aqueous solution", Environmental Science and Pollution Research, 26, (2019), 32151-32164.
  • Biswas S., Bal M., Behera S.K., Sen T.K., Meikap B.C., "Process optimization study of Zn2+ adsorption on biochar-alginate composite adsorbent by response surface methodology (RSM)", Water, 11, (2019), 325.
  • Košak A., Lobnik A., Bauman M., "Adsorption of mercury(II), lead(II), cadmium(II) and zinc(II) from aqueous solutions using mercapto-modified silica particles", International Journal of Applied Ceramic Technology, 12, (2015), 461-472.
  • Hao J., Han M.-J., Wang C., Meng X., "Enhanced removal of arsenite from water by a mesoporous hybrid material – Thiol-functionalized silica coated activated alumina", Microporous and Mesoporous Materials, 124, (2009), 1-7.
  • Li G., Zhao Z., Liu J., Jiang G., "Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica", Journal of Hazardous Materials, 192, (2011), 277-283.
  • Mirzaee S.S., Salahi E., Khanlarkhani A., "Kinetics, isotherms and thermodynamic modeling of Mn2+ and Zn2+ single and binary removal using mercapto functionalized silica aerogel", Journal of Dispersion Science and Technology, 40, (2019), 657-667.
Year 2020, Volume: 8 Issue: 2, 125 - 131, 21.12.2020
https://doi.org/10.51354/mjen.800161

Abstract

References

  • Vojoudi H., Badiei A., Amiri A., Banaei A., Ziarani G.M., Schenk-Joß K., "Pre-concentration of Zn(II) ions from aqueous solutions using meso-porous pyridine-enrobed magnetite nanostructures", Food Chemistry, 257, (2018), 189-195.
  • Mousavi S.J., Parvini M., Ghorbani M., "Experimental design data for the zinc ions adsorption based on mesoporous modified chitosan using central composite design method", Carbohydrate Polymers, 188, (2018), 197-212.
  • Karri R.R., Sahu J.N., "Modeling and optimization by particle swarm embedded neural network for adsorption of zinc (II) by palm kernel shell based activated carbon from aqueous environment", Journal of Environmental Management, 206, (2018), 178-191.
  • Shanmugaprakash M., Venkatachalam S., Rajendran K., Pugazhendhi A., "Biosorptive removal of Zn(II) ions by Pongamia oil cake (Pongamia pinnata) in batch and fixed-bed column studies using response surface methodology and artificial neural network", Journal of Environmental Management, 227, (2018), 216-228.
  • Ahmadi A., Heidarzadeh S., Mokhtari A.R., Darezereshki E., Harouni H.A., "Optimization of heavy metal removal from aqueous solutions by maghemite (γ-Fe2O3) nanoparticles using response surface methodology", Journal of Geochemical Exploration, 147, (2014), 151-158.
  • Yılmaz Ş., Zengin A., Şahan T., "A novel material poly(N-acryloyl-L-serine)-brush grafted kaolin for efficient elimination of malachite green dye from aqueous environments", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 601, (2020), 125041.
  • Dev V.V., Baburaj G., Antony S., Arun V., Krishnan K.A., "Zwitterion-chitosan bed for the simultaneous immobilization of Zn(II), Cd(II), Pb(II) and Cu(II) from multi-metal aqueous systems", Journal of Cleaner Production, 255, (2020), 120309.
  • Corda N., Kini M.S., "Recent studies in adsorption of Pb(II), Zn(II) and Co(II) using conventional and modified materials:a review", Separation Science and Technology, 55, (2020), 2679-2698.
  • Olu-Owolabi B.I., Unuabonah E.I., "Adsorption of Zn2+ and Cu2+ onto sulphate and phosphate-modified bentonite", Applied Clay Science, 51, (2011), 170-173.
  • Jemima W.S., Magesan P., Chiranjeevi P., Umapathy M.J., "Sorption properties of organo modified montmorillonite clay for the reclamation of chromium (VI) from waste water", Silicon, 11, (2019), 925-933.
  • Bezerra M.A., Santelli R.E., Oliveira E.P., Villar L.S., Escaleira L.A., "Response surface methodology (RSM) as a tool for optimization in analytical chemistry", Talanta, 76, (2008), 965-977.
  • Yılmaz Ş., Şahan T., Karabakan A., "Response surface approach for optimization of Hg(II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution", Korean Journal of Chemical Engineering, 34, (2017), 2225-2235.
  • Liu X., Han B., Su C.-l., Han Q., Chen K.-j., Chen Z.-q., "Optimization and mechanisms of biosorption process of Zn(II) on rape straw powders in aqueous solution", Environmental Science and Pollution Research, 26, (2019), 32151-32164.
  • Biswas S., Bal M., Behera S.K., Sen T.K., Meikap B.C., "Process optimization study of Zn2+ adsorption on biochar-alginate composite adsorbent by response surface methodology (RSM)", Water, 11, (2019), 325.
  • Košak A., Lobnik A., Bauman M., "Adsorption of mercury(II), lead(II), cadmium(II) and zinc(II) from aqueous solutions using mercapto-modified silica particles", International Journal of Applied Ceramic Technology, 12, (2015), 461-472.
  • Hao J., Han M.-J., Wang C., Meng X., "Enhanced removal of arsenite from water by a mesoporous hybrid material – Thiol-functionalized silica coated activated alumina", Microporous and Mesoporous Materials, 124, (2009), 1-7.
  • Li G., Zhao Z., Liu J., Jiang G., "Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica", Journal of Hazardous Materials, 192, (2011), 277-283.
  • Mirzaee S.S., Salahi E., Khanlarkhani A., "Kinetics, isotherms and thermodynamic modeling of Mn2+ and Zn2+ single and binary removal using mercapto functionalized silica aerogel", Journal of Dispersion Science and Technology, 40, (2019), 657-667.
There are 18 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

Ümit Ecer 0000-0002-1824-982X

Şakir Yılmaz 0000-0001-9797-0959

Tekin Şahan 0000-0001-8776-9338

Publication Date December 21, 2020
Published in Issue Year 2020 Volume: 8 Issue: 2

Cite

APA Ecer, Ü., Yılmaz, Ş., & Şahan, T. (2020). Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology. MANAS Journal of Engineering, 8(2), 125-131. https://doi.org/10.51354/mjen.800161
AMA Ecer Ü, Yılmaz Ş, Şahan T. Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology. MJEN. December 2020;8(2):125-131. doi:10.51354/mjen.800161
Chicago Ecer, Ümit, Şakir Yılmaz, and Tekin Şahan. “Effective Clay Material Enriched With Thiol Groups for Zn(II) Removal from Aqueous Media: A Statistical Approach Based on Response Surface Methodology”. MANAS Journal of Engineering 8, no. 2 (December 2020): 125-31. https://doi.org/10.51354/mjen.800161.
EndNote Ecer Ü, Yılmaz Ş, Şahan T (December 1, 2020) Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology. MANAS Journal of Engineering 8 2 125–131.
IEEE Ü. Ecer, Ş. Yılmaz, and T. Şahan, “Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology”, MJEN, vol. 8, no. 2, pp. 125–131, 2020, doi: 10.51354/mjen.800161.
ISNAD Ecer, Ümit et al. “Effective Clay Material Enriched With Thiol Groups for Zn(II) Removal from Aqueous Media: A Statistical Approach Based on Response Surface Methodology”. MANAS Journal of Engineering 8/2 (December 2020), 125-131. https://doi.org/10.51354/mjen.800161.
JAMA Ecer Ü, Yılmaz Ş, Şahan T. Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology. MJEN. 2020;8:125–131.
MLA Ecer, Ümit et al. “Effective Clay Material Enriched With Thiol Groups for Zn(II) Removal from Aqueous Media: A Statistical Approach Based on Response Surface Methodology”. MANAS Journal of Engineering, vol. 8, no. 2, 2020, pp. 125-31, doi:10.51354/mjen.800161.
Vancouver Ecer Ü, Yılmaz Ş, Şahan T. Effective clay material enriched with thiol groups for Zn(II) removal from aqueous media: A statistical approach based on response surface methodology. MJEN. 2020;8(2):125-31.

Manas Journal of Engineering 

16155