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Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels

Year 2021, Volume: 9 Issue: 2, 104 - 114, 06.12.2021
https://doi.org/10.51354/mjen.936970

Abstract

Acrylonitrile (AN) and 1-vinyl imidazole (VI) based hydrogel was prepared in bulk (macro) dimensions via redox polymerization technique. Afterward, this hydrogel was quaternized (positively charged) and exposed to the amidoximation reaction. The prepared hydrogels (quart-p(AN-co-VI), amid-p(AN-co-VI) and p(VI)) characterized using fourier transform infrared spectroscopy (FT-IR) and thermal gravimetric analysis (TGA). Swelling experiments were performed gravimetrically at room temperature in deionized water and different pH solution. Water absorbencies of both amidoximated hydrogels and quaternized hydrogels were founded to be high. Prepared hydrogels were used to remove heavy metal ions such as arsenic(V) (As(V)), Chromium(VI) (Cr(VI)) and Chromium(III) (Cr(III)) from aqueous media. The sorption of As(V), Cr(VI) and Cr(III) metal ions by hydrogels were carried out at different initial metal ion concentrations, different pHs, different times in batch sorption experiments at 25oC. The maximum metal ion sorption capacity by all hydrogels was in the order: As(VI)>Cr(VI)>Cr(III). The maximum sorption capacity for As(VI), Cr(VI) and Cr(III) ions was found to be 598, 303.8 and 4.9 mg g-1 for amid-p(AN-co-VI), respectively. As result of, amidoximated hydrogels have more sorption capacity to metal ions than quaternized hydrogels. Three different kinetic models (pseudo first order, pseudo second order and intraparticle diffusion model) were also used to investigate the sorption mechanisms. Furthermore, the Langmuir and Freundlich sorption isotherms were investigated for these metal ions. As a result of, amidoximation and quaternization of AN and VI based hydrogels have been a promising technique to increase the sorption rate and capacity of hydrogels and are thought to provide great advantages in the removal of metal ions from wastewaters. Especially, among the p(AN-co-VI) modification processes, amidoximation reaction was found to give better results than quaternization reaction. Prepared hydrogels were found to be more selective than Cr(III) versus As(V) and Cr(VI).

Supporting Institution

Van Yüzüncü Yıl Üniversitesi

Project Number

FBA-2018-7277.

Thanks

This work is supported by the Van Yuzuncu Yıl University BAP with grant # FBA-2018-7277.

References

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  • Gupta NV and Shivakumar HG 2012 Iran J. Pharm. Res. 11(2) 481.
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Year 2021, Volume: 9 Issue: 2, 104 - 114, 06.12.2021
https://doi.org/10.51354/mjen.936970

Abstract

Project Number

FBA-2018-7277.

References

  • Üzüm ÖB, Kundakci S and Karadağ E 2007 Polym. Plast. Technol. Eng. 46 775.
  • Kara A, Uzun L, Beşirli N and Denizli A 2004 J. Hazard. Mater. 106 93.
  • El-Hag Ali A, Shawky HA, Abd El Rehim HA and Hegazy EA 2003 Eur. Polym. J. 39 2337.
  • Crini G (2005) Prog. Polym. Sci. 30 38.
  • Sahiner N, Ozay O, Aktas N, Blake DA and John VT 2011 Desalination 279 344.
  • Liu Y, Cao X, Hua R, Wang Y, Liu Y, Pang C and Wang Y 2010 Hydrometallurgy 104 150.
  • Chai Q, Jiao Y and Yu X 2017 Gels doi:10.3390/gels3010006.
  • Bansod BK, Kumar T, Thakur R, Rana S and Singh I 2017 Biosens. Bioelectron. 94 443.
  • Pakdel PM and Peighambardoust SJ 2018 Carbohydr. Polym. 201 264.
  • Rıfi EH, Rastegar F and Brunette JP 1995 Talanta 42(6) 811.
  • Manju GN, Krishnan KA, Vinod VB and Anirudhan TS 2002 J. Hazard. Mater. 91 221.
  • Charerntanyarak L 1999 Water Sci Technol 39 135.
  • Chen Q, Zhu, L, Zhao C and Zheng J 2012 Environ. Anal. Toxicol. doi:10.4172/2161-0525.S2-001
  • Liu X, Chen H, Wang C, Qu R, Ji C, Sun C and Zhang Y 2010 J. Hazard. Mater. 175 1014.
  • Nie FQ, Xu ZK, Ye P, Wu J and Seta P 2004 Polym. 45 399.
  • Liu X, Chen H, Wang C, Qu R, Ji C, Sun C and Zhang Y 2010 J. Hazard. Mater. 175 1014.
  • Das S, Pandey AK, Athawale AA and Manchanda VK 2009 J. Phys. Chem. B 113 6328.
  • Genc F, Uzun C and Guven O 2016 Polym. Bull. 73 179.
  • Erdem B 2016 Anadolu Unv. J. Sci. Technol. A-Appl. Sci. Eng. 17(5) 974.
  • Erdem M, Dikişler Ö and Erdem B 2016 Chem. Eng. Commun. 203 1403,
  • Ersen Dudu T, Sahiner M, Alpaslan D, Demirci S and Aktas N 2015 J. Environ. Manage. 161 243.
  • Ersen Dudu T, Alpaslan D, Uzun Y and Aktas N 2017 Int. J. Environ. Res. 11 557.
  • Chang C, Zhang L, Zhou J, Zhang L and Kennedy JF 2010 Carbohydr. Polym. 82(1) 122.
  • Tang H, Chen H, Duan B, Lu A and Zhang L 2014 J. Mater. Sci. 49(5) 2235.
  • Cardenas G, Orlando P and Edelio T 2001 Int. J. Biol. Macromol. 28 167.
  • Wu N, Li Z (2013) Chem. Eng. J. 215-216 894.
  • Langmuir I 1918 J. Am. Chem. Soc. 40 1361.
  • Freundlich HMF 1906 Z für Phys. Chem. 57 385.
  • Lagergren S 1898 Handlingar 24 1.
  • Blanchard G, Maunaye M and Martin G 1984 Water. Res. 18 1501.
  • Toor M and Jin B 2012 Chem. Eng. J. 187 79.
  • Weber WJ and Morris JC 1963 J. Sanit Eng. Div. Am. Soc. Civ. Eng. 89 31.
  • Alpaslan D, Aktas N, Yilmaz S, Sahiner N and Guven O 2014 Hacettepe J. Biol. Chem. 42(1) 89.
  • Gupta NV and Shivakumar HG 2012 Iran J. Pharm. Res. 11(2) 481.
  • Makris KCSD and Datta R 2006 Chemosphere 64(5) 730.
  • Kim YS, Kim DH, Yang JS and Baek K 2012 Sep. Sci. Technol. 47 2211.
  • Deng S and Bai R 2004 Water Res. 38 2423.
There are 37 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

Duygu Alpaslan 0000-0002-6007-3397

Tuba Erşen Dudu 0000-0001-5564-2834

Project Number FBA-2018-7277.
Publication Date December 6, 2021
Published in Issue Year 2021 Volume: 9 Issue: 2

Cite

APA Alpaslan, D., & Erşen Dudu, T. (2021). Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels. MANAS Journal of Engineering, 9(2), 104-114. https://doi.org/10.51354/mjen.936970
AMA Alpaslan D, Erşen Dudu T. Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels. MJEN. December 2021;9(2):104-114. doi:10.51354/mjen.936970
Chicago Alpaslan, Duygu, and Tuba Erşen Dudu. “Removal of as(V), Cr(VI) and Cr(III) Heavy Metal Ions from Environmental Waters Using Amidoxime and Quaternized Hydrogels”. MANAS Journal of Engineering 9, no. 2 (December 2021): 104-14. https://doi.org/10.51354/mjen.936970.
EndNote Alpaslan D, Erşen Dudu T (December 1, 2021) Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels. MANAS Journal of Engineering 9 2 104–114.
IEEE D. Alpaslan and T. Erşen Dudu, “Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels”, MJEN, vol. 9, no. 2, pp. 104–114, 2021, doi: 10.51354/mjen.936970.
ISNAD Alpaslan, Duygu - Erşen Dudu, Tuba. “Removal of as(V), Cr(VI) and Cr(III) Heavy Metal Ions from Environmental Waters Using Amidoxime and Quaternized Hydrogels”. MANAS Journal of Engineering 9/2 (December 2021), 104-114. https://doi.org/10.51354/mjen.936970.
JAMA Alpaslan D, Erşen Dudu T. Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels. MJEN. 2021;9:104–114.
MLA Alpaslan, Duygu and Tuba Erşen Dudu. “Removal of as(V), Cr(VI) and Cr(III) Heavy Metal Ions from Environmental Waters Using Amidoxime and Quaternized Hydrogels”. MANAS Journal of Engineering, vol. 9, no. 2, 2021, pp. 104-1, doi:10.51354/mjen.936970.
Vancouver Alpaslan D, Erşen Dudu T. Removal of as(V), Cr(VI) and Cr(III) heavy metal ions from environmental waters using amidoxime and quaternized hydrogels. MJEN. 2021;9(2):104-1.

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