Year 2024,
Volume: 12 Issue: 2, 215 - 223, 27.12.2024
Sevda Esma Darama
,
Semra Çoruh
,
Selim Ceylan
,
Elif Hatice Gürkan
Project Number
PYO.MUH.1901.18.002
References
- [1]. Adegoke, K.A. and O.S. Bello, "Dye sequestration using agricultural wastes as adsorbents", Water
Resources and Industry, 12, (2015), 8-24.
- [2]. Mahmoodi, N.M., O. Masrouri, and F. Najafi, "Dye removal using polymeric adsorbent from wastewater
containing mixture of two dyes", Fibers and Polymers, 15, (2014), 1656-1668.
- [3]. Sen, N.E. and Z.M. Senol, "Effective removal of Allura red food dye from water using cross-linked
chitosan-diatomite composite beads", Int J Biol Macromol, 253, (2023), 126632.
- [4]. You, X., et al., "Adsorption of dyes methyl violet and malachite green from aqueous solution on multi-
step modified rice husk powder in single and binary systems: Characterization, adsorption behavior and
physical interpretations", J Hazard Mater, 430, (2022), 128445.
- [5]. Basakcilardan Kabakci, S. and S.S. Baran, "Hydrothermal carbonization of various lignocellulosics: Fuel
characteristics of hydrochars and surface characteristics of activated hydrochars", Waste Manag, 110,
(2019), 259-268.
- [6]. Yahav Spitzer, R., et al., "Biocrude extraction from human-excreta-derived hydrochar for sustainable
energy and agricultural applications", Environ Res, 247, (2024), 118287.
- [7]. Amarasinghe, H.A.H.I., S.K. Gunathilake, and A.K. Karunarathna, "Ascertaining of Optimum Pyrolysis
Conditions in Producing Refuse Tea Biochar as a Soil Amendment", Procedia Food Science, 6, (2016), 97-102.
- [8]. Krishna Veni, D., et al., "Biochar from green waste for phosphate removal with subsequent disposal",
Waste Manag, 68, (2017), 752-759.
- [9]. Zi, W., et al., "Pyrolysis, morphology and microwave absorption properties of tobacco stem materials",
Sci Total Environ, 683, (2019), 341-350.
- [10]. Wang, Y., R. Yin, and R. Liu, "Characterization of biochar from fast pyrolysis and its effect on
chemical properties of the tea garden soil", Journal of Analytical and Applied Pyrolysis, 110, (2014), 375-381.
- [11]. Zhang, P., et al., "Characteristics of tetracycline adsorption by cow manure biochar prepared at
different pyrolysis temperatures", Bioresour Technol, 285, (2019), 121348.
- [12]. Jalilian, M., et al., "A review: Hydrochar as potential adsorbents for wastewater treatment and
CO(2) adsorption", Sci Total Environ, 914, (2024), 169823.
- [13]. Goel, C., et al., "CO2 adsorption by KOH-activated hydrochar derived from banana peel waste",
Chemical Papers, 78, (2024), 3845-3856.
- [14]. Zhou, N., et al., "Effect of pyrolysis condition on the adsorption mechanism of heavy metals on
tobacco stem biochar in competitive mode", Environ Sci Pollut Res Int, 26, (2019), 26947-26962.
- [15]. Kibet, J.K., A. Jebet, and T. Kinyanjui, "Molecular oxygenates from the thermal degradation of
tobacco and material characterization of tobacco char", Scientific African, (2019), 5.
- [16]. Wei, M., et al., "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment",
Energies, 13, (2020), 18.
- [17]. Onorevoli, B., et al., "Characterization of feedstock and biochar from energetic tobacco seed waste
pyrolysis and potential application of biochar as an adsorbent", Journal of Environmental Chemical
Engineering, 6, (2018), 1279-1287.
- [18]. Blankenship, L.S. and R. Mokaya, "Cigarette butt-derived carbons have ultra-high surface area and
unprecedented hydrogen storage capacity", Energy & Environmental Science, 10, (2017), 2552-2562.
- [19]. Lima, H.H.C., et al., "Hydrochars based on cigarette butts as a recycled material for the adsorption
of pollutants", Journal of Environmental Chemical Engineering, 6, (2018), 7054-7061.
- [20]. Calabuig, E., N. Juárez-Serrano, and A. Marcilla, "TG-FTIR study of evolved gas in the decomposition
of different types of tobacco", Effect of the addition of SBA-15. Thermochimica Acta, 671, (2019), 209-219.
- [21]. Sevilla, M., J.A. Maciá-Agulló, and A.B. Fuertes, "Hydrothermal carbonization of biomass as a route
for the sequestration of CO2: Chemical and structural properties of the carbonized products", Biomass and
Bioenergy, 35, (2011), 3152-3159.
- [22]. Tomczyk, A., et al., "Purification of Aqueous Media by Biochars: Feedstock Type Effect on Silver
Nanoparticles Removal", Molecules, 25, (2020), 12.
- [23]. Pathy, A., et al., "Malachite green removal using algal biochar and its composites with kombucha
SCOBY: An integrated biosorption and phycoremediation approach", Surfaces and Interfaces, (2022), 30.
- [24]. Donat, R., et al., "Thermodynamic parameters and sorption of U(VI) on ACSD", Journal of
Radioanalytical and Nuclear Chemistry, 279, (2008), 271-280.
- [25]. Zhang, X., et al., "Adsorption-reduction removal of Cr(VI) by tobacco petiole pyrolytic biochar:
Batch experiment, kinetic and mechanism studies", Bioresour Technol, 268, (2018), 149-157.
- [26]. Haladu, S.A., "Highly efficient adsorption of malachite green dye onto a cross-linked pH-responsive
cycloterpolymer resin: Kinetic, equilibrium and thermodynamic studies", Journal of Molecular Liquids,
(2022), 357.
Hydrochar Production from Cigarette Butts and Tobacco for Dye Adsorption
Year 2024,
Volume: 12 Issue: 2, 215 - 223, 27.12.2024
Sevda Esma Darama
,
Semra Çoruh
,
Selim Ceylan
,
Elif Hatice Gürkan
Abstract
In this study, tobacco waste generated from cigarette and cigar production, as well as discarded cigarette butts resulting from cigarette use, were recycled and their use as adsorbent materials was investigated. For this purpose, both products underwent various thermal and chemical treatments and were converted into hydrochar form. Chemically activated hydrochar was used in dye removal experiments due to its high surface area and adsorbent properties. Malachite green was selected as the dye material for the project. Adsorption experiments were conducted at different initial concentrations, adsorbent doses, and contact times. In experiments on the removal of malachite green with butts and tobacco waste hydrochars, removal rates as high as 99% were obtained. As a result of adsorption experiments carried out with both hydrochars, it was observed that the adsorption fits the Langmuir isotherm model and the Pseudo-Second-Order kinetic model. Tobacco waste and discarded cigarette butts, which are cheap, readily available, and abundant, were found to be effective alternative adsorbents for malachite green removal.
Ethical Statement
not required
Supporting Institution
Ondokuz Mayıs University
Project Number
PYO.MUH.1901.18.002
Thanks
Ondokuz Mayıs University, Scientific Research Projects Coordination Unit
References
- [1]. Adegoke, K.A. and O.S. Bello, "Dye sequestration using agricultural wastes as adsorbents", Water
Resources and Industry, 12, (2015), 8-24.
- [2]. Mahmoodi, N.M., O. Masrouri, and F. Najafi, "Dye removal using polymeric adsorbent from wastewater
containing mixture of two dyes", Fibers and Polymers, 15, (2014), 1656-1668.
- [3]. Sen, N.E. and Z.M. Senol, "Effective removal of Allura red food dye from water using cross-linked
chitosan-diatomite composite beads", Int J Biol Macromol, 253, (2023), 126632.
- [4]. You, X., et al., "Adsorption of dyes methyl violet and malachite green from aqueous solution on multi-
step modified rice husk powder in single and binary systems: Characterization, adsorption behavior and
physical interpretations", J Hazard Mater, 430, (2022), 128445.
- [5]. Basakcilardan Kabakci, S. and S.S. Baran, "Hydrothermal carbonization of various lignocellulosics: Fuel
characteristics of hydrochars and surface characteristics of activated hydrochars", Waste Manag, 110,
(2019), 259-268.
- [6]. Yahav Spitzer, R., et al., "Biocrude extraction from human-excreta-derived hydrochar for sustainable
energy and agricultural applications", Environ Res, 247, (2024), 118287.
- [7]. Amarasinghe, H.A.H.I., S.K. Gunathilake, and A.K. Karunarathna, "Ascertaining of Optimum Pyrolysis
Conditions in Producing Refuse Tea Biochar as a Soil Amendment", Procedia Food Science, 6, (2016), 97-102.
- [8]. Krishna Veni, D., et al., "Biochar from green waste for phosphate removal with subsequent disposal",
Waste Manag, 68, (2017), 752-759.
- [9]. Zi, W., et al., "Pyrolysis, morphology and microwave absorption properties of tobacco stem materials",
Sci Total Environ, 683, (2019), 341-350.
- [10]. Wang, Y., R. Yin, and R. Liu, "Characterization of biochar from fast pyrolysis and its effect on
chemical properties of the tea garden soil", Journal of Analytical and Applied Pyrolysis, 110, (2014), 375-381.
- [11]. Zhang, P., et al., "Characteristics of tetracycline adsorption by cow manure biochar prepared at
different pyrolysis temperatures", Bioresour Technol, 285, (2019), 121348.
- [12]. Jalilian, M., et al., "A review: Hydrochar as potential adsorbents for wastewater treatment and
CO(2) adsorption", Sci Total Environ, 914, (2024), 169823.
- [13]. Goel, C., et al., "CO2 adsorption by KOH-activated hydrochar derived from banana peel waste",
Chemical Papers, 78, (2024), 3845-3856.
- [14]. Zhou, N., et al., "Effect of pyrolysis condition on the adsorption mechanism of heavy metals on
tobacco stem biochar in competitive mode", Environ Sci Pollut Res Int, 26, (2019), 26947-26962.
- [15]. Kibet, J.K., A. Jebet, and T. Kinyanjui, "Molecular oxygenates from the thermal degradation of
tobacco and material characterization of tobacco char", Scientific African, (2019), 5.
- [16]. Wei, M., et al., "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment",
Energies, 13, (2020), 18.
- [17]. Onorevoli, B., et al., "Characterization of feedstock and biochar from energetic tobacco seed waste
pyrolysis and potential application of biochar as an adsorbent", Journal of Environmental Chemical
Engineering, 6, (2018), 1279-1287.
- [18]. Blankenship, L.S. and R. Mokaya, "Cigarette butt-derived carbons have ultra-high surface area and
unprecedented hydrogen storage capacity", Energy & Environmental Science, 10, (2017), 2552-2562.
- [19]. Lima, H.H.C., et al., "Hydrochars based on cigarette butts as a recycled material for the adsorption
of pollutants", Journal of Environmental Chemical Engineering, 6, (2018), 7054-7061.
- [20]. Calabuig, E., N. Juárez-Serrano, and A. Marcilla, "TG-FTIR study of evolved gas in the decomposition
of different types of tobacco", Effect of the addition of SBA-15. Thermochimica Acta, 671, (2019), 209-219.
- [21]. Sevilla, M., J.A. Maciá-Agulló, and A.B. Fuertes, "Hydrothermal carbonization of biomass as a route
for the sequestration of CO2: Chemical and structural properties of the carbonized products", Biomass and
Bioenergy, 35, (2011), 3152-3159.
- [22]. Tomczyk, A., et al., "Purification of Aqueous Media by Biochars: Feedstock Type Effect on Silver
Nanoparticles Removal", Molecules, 25, (2020), 12.
- [23]. Pathy, A., et al., "Malachite green removal using algal biochar and its composites with kombucha
SCOBY: An integrated biosorption and phycoremediation approach", Surfaces and Interfaces, (2022), 30.
- [24]. Donat, R., et al., "Thermodynamic parameters and sorption of U(VI) on ACSD", Journal of
Radioanalytical and Nuclear Chemistry, 279, (2008), 271-280.
- [25]. Zhang, X., et al., "Adsorption-reduction removal of Cr(VI) by tobacco petiole pyrolytic biochar:
Batch experiment, kinetic and mechanism studies", Bioresour Technol, 268, (2018), 149-157.
- [26]. Haladu, S.A., "Highly efficient adsorption of malachite green dye onto a cross-linked pH-responsive
cycloterpolymer resin: Kinetic, equilibrium and thermodynamic studies", Journal of Molecular Liquids,
(2022), 357.