THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE

Elif Vargün; Ceren Küçükuysal; Özden Evren; Merve Gülcan; Öykü Ataytür; Cansu Güngör

doi:10.22531/muglajsci.357263

Research Article

KUVATERNER TUZLARININ TÜRÜ VE MİKTARININ ÇANAKKALE BENTONİTİNİN MODİFİKASYONU ÜZERİNE ETKİLERİ

Year 2017, Volume: 3 Issue: 2, 178 - 183, 24.12.2017

Elif Vargün Ceren Küçükuysal Özden Evren Merve Gülcan Öykü Ataytür Cansu Güngör

https://doi.org/10.22531/muglajsci.357263

Abstract

Kil minerallerinin düzgün dağılımı, polimer kil
nanokompozit üretiminde önemli bir role sahiptir. Bu bakımdan, kompozitlerin
interkale/eksfoliye yapılarını elde etmek için kilin farklı organomodifikasyon
yöntemleri denenmiştir. Bu çalışmada, Çanakkale bentonitinin tetrametilamonyum
klorür (TMAC), hekzadesilpiridinyum klorür (HDPC), hekzadesiltrimetilamonyum
bromür (HDAB), feniltrimetilamonyum klorür (PMAC) olmak üzere dört farklı
kuvaterner amonyum tuzu ile organomodifikasyonu incelenmiştir.
Organobentonitler Fourier transform infrared spektroskopi (FTIR), X-ışını
kırınımı (XRD) analizi ve termogravimetrik analiz (TGA) ile karakterize
edilmiştir. HDAB ve HDPC tuzları kullanılarak bentonitin bazal aralığı 14.9
Å'dan sırasıyla 20.7 Å'a ve 21.4 Å'a kadar artırılmıştır. Bununla birlikte,
diğer modifiye edici tuzlar d-aralıklarında önemli değişikliklere neden
olamamışlardır.

Keywords

Polimer kil nanokompozit, organomodifikasyon, bentonit

References

Dr. Ruhan Benlikaya ruhan@balikesir.edu.tr
Dr. Metin Ak metinak@pau.edu.tr
Dr. Pınar Çamurlu pinarcamurlu@gmail.com

THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE

Year 2017, Volume: 3 Issue: 2, 178 - 183, 24.12.2017

Elif Vargün Ceren Küçükuysal Özden Evren Merve Gülcan Öykü Ataytür Cansu Güngör

https://doi.org/10.22531/muglajsci.357263

Abstract

The improved dispersion of clay minerals
has an essential role for polymer clay nanocomposite manufacturing. In this
regard, different organomodifications of clay have been attempted to obtain
intercalated/exfoliated structures of composites. In present study, Çanakkale
bentonite was organically modified by four different quaternary ammonium salts:
tetramethylammonium chloride (TMAC), hexadecylpyridinium chloride (HDPC),
hexadecyltrimethylammonium bromide (HDAB), phenyltrimethylammonium chloride
(PMAC). Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD)
analysis and thermogravimetric analysis (TGA) were performed to characterize
the organobentonites. The results revealed that there is an increment of basal
spacing of bentonite with HDAB and HDPC salts from 14.9
Å to 20.7 Å and 21.4 Å, respectively. However, other
modifiers cannot lead to significant changes in d-spacings.

Keywords

polymer clay nanocomposite, organomodification, bentonite

References

Dr. Ruhan Benlikaya ruhan@balikesir.edu.tr
Dr. Metin Ak metinak@pau.edu.tr
Dr. Pınar Çamurlu pinarcamurlu@gmail.com

There are 3 citations in total.

Details

Subjects	Engineering
Journal Section	Geological Engineering
Authors	Elif Vargün Ceren Küçükuysal Özden Evren This is me Merve Gülcan Öykü Ataytür Cansu Güngör This is me
Publication Date	December 24, 2017
Published in Issue	Year 2017 Volume: 3 Issue: 2

Cite

APA	Vargün, E., Küçükuysal, C., Evren, Ö., Gülcan, M., et al. (2017). THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology, 3(2), 178-183. https://doi.org/10.22531/muglajsci.357263
AMA	Vargün E, Küçükuysal C, Evren Ö, Gülcan M, Ataytür Ö, Güngör C. THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology. December 2017;3(2):178-183. doi:10.22531/muglajsci.357263
Chicago	Vargün, Elif, Ceren Küçükuysal, Özden Evren, Merve Gülcan, Öykü Ataytür, and Cansu Güngör. “THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE”. Mugla Journal of Science and Technology 3, no. 2 (December 2017): 178-83. https://doi.org/10.22531/muglajsci.357263.
EndNote	Vargün E, Küçükuysal C, Evren Ö, Gülcan M, Ataytür Ö, Güngör C (December 1, 2017) THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology 3 2 178–183.
IEEE	E. Vargün, C. Küçükuysal, Ö. Evren, M. Gülcan, Ö. Ataytür, and C. Güngör, “THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE”, Mugla Journal of Science and Technology, vol. 3, no. 2, pp. 178–183, 2017, doi: 10.22531/muglajsci.357263.
ISNAD	Vargün, Elif et al. “THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE”. Mugla Journal of Science and Technology 3/2 (December 2017), 178-183. https://doi.org/10.22531/muglajsci.357263.
JAMA	Vargün E, Küçükuysal C, Evren Ö, Gülcan M, Ataytür Ö, Güngör C. THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology. 2017;3:178–183.
MLA	Vargün, Elif et al. “THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE”. Mugla Journal of Science and Technology, vol. 3, no. 2, 2017, pp. 178-83, doi:10.22531/muglajsci.357263.
Vancouver	Vargün E, Küçükuysal C, Evren Ö, Gülcan M, Ataytür Ö, Güngör C. THE EFFECTS OF TYPE AND AMOUNT OF QUATERNARY SALTS ON MODIFICATION OF ÇANAKKALE BENTONITE. Mugla Journal of Science and Technology. 2017;3(2):178-83.