Year 2019, Volume 5 , Issue 2, Pages 62 - 67 2019-12-11

CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL
CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL

Gulhan CAKMAK [1]


Al and Co doped LiNixMnyFezO2 (NMF) was synthesized using sol-gel method. The effect of dopants on the structural stability of LiNixMnyFezO2 (NMF) cathode material was investigated. For this purpose, the powder preparation was carried out using an aqueous solution of the nitrate precursors followed by calcination at 850 °C 5h. The chemical composition of LiNixMnyFezO2 base material was selected as 622 (Ni/Mn/Fe atomic ratio) and were successfully synthesized in layered form. Chemical composition of the obtained powders was determined by Energy dispersive spectroscopy. Scanning electron microscopy was applied to investigate the morphology of the powders. The crystal structure of the samples was analyzed using X-ray diffraction and Rietveld analysis. Average crystallite size from Rietveld refinement was calculated to be between 60-70 nm. Co-doped and Al-doped 622 cathode materials showed [006]/[102] and [108]/[110] doublets, which is the sign of layered structure with hexagonal ordering

 

Al ve Co katkılı LiNixMnyFezO2 (NMF) sol-gel yöntemi kullanılarak sentezlenmiştir. Katkıların LiNixMnyFezO2 (NMF) katot malzemelerinin yapısal stabilitesi üzerindeki etkisi araştırılmıştır. Bu amaçla, tozlar, nitrat öncüllerinin sulu bir çözeltisi kullanılarak hazırlanmış ve 850 ° C'de 5 saatte kalsine edilmiştir. LiNixMnyFezO2 sisteminin kimyasal bileşimi 622 (Ni / Mn / Fe atomik oran) olarak seçilmiş başarıyla sentezlenmiştir. Elde edilen tozların kimyasal bileşimi enerji saçılım spektroskopisi ile kontrol edilmiştir. Tozların morfolojisi taramalı elektron mikroskobu kullanılarak incelenmiştir. Numunelerin kristal yapısı, X ışını kırınımı ve Rietveld analizi kullanılarak analiz edilmiş ve ortalama kristal büyüklüğü 60-70 nm arasında hesaplanmıştır. Co katkılı ve Al katkılı 622 katot malzemelerin tabakalı yapıya sahip olduğu [006] / [102] ve [108] / [110] difraksiyon çiftleri ile görülmüştür.

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Primary Language tr
Subjects Engineering
Journal Section Journals
Authors

Orcid: 0000-0001-8121-1333
Author: Gulhan CAKMAK (Primary Author)
Institution: MUĞLA SITKI KOÇMAN ÜNİVERSİTESİ
Country: Turkey


Dates

Publication Date : December 11, 2019

Bibtex @research article { muglajsci596341, journal = {Mugla Journal of Science and Technology}, issn = {2149-3596}, address = {}, publisher = {Muğla Sıtkı Koçman Üniversitesi}, year = {2019}, volume = {5}, pages = {62 - 67}, doi = {10.22531/muglajsci.596341}, title = {CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL}, key = {cite}, author = {CAKMAK, Gulhan} }
APA CAKMAK, G . (2019). CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL. Mugla Journal of Science and Technology , 5 (2) , 62-67 . DOI: 10.22531/muglajsci.596341
MLA CAKMAK, G . "CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL". Mugla Journal of Science and Technology 5 (2019 ): 62-67 <https://dergipark.org.tr/en/pub/muglajsci/issue/49054/596341>
Chicago CAKMAK, G . "CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL". Mugla Journal of Science and Technology 5 (2019 ): 62-67
RIS TY - JOUR T1 - CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL AU - Gulhan CAKMAK Y1 - 2019 PY - 2019 N1 - doi: 10.22531/muglajsci.596341 DO - 10.22531/muglajsci.596341 T2 - Mugla Journal of Science and Technology JF - Journal JO - JOR SP - 62 EP - 67 VL - 5 IS - 2 SN - 2149-3596- M3 - doi: 10.22531/muglajsci.596341 UR - https://doi.org/10.22531/muglajsci.596341 Y2 - 2019 ER -
EndNote %0 Mugla Journal of Science and Technology CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL %A Gulhan CAKMAK %T CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL %D 2019 %J Mugla Journal of Science and Technology %P 2149-3596- %V 5 %N 2 %R doi: 10.22531/muglajsci.596341 %U 10.22531/muglajsci.596341
ISNAD CAKMAK, Gulhan . "CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL". Mugla Journal of Science and Technology 5 / 2 (December 2019): 62-67 . https://doi.org/10.22531/muglajsci.596341
AMA CAKMAK G . CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL. Mugla Journal of Science and Technology. 2019; 5(2): 62-67.
Vancouver CAKMAK G . CHEMICAL SYNTHESIS OF Al AND Co DOPED LiNi6Mn2Fe2O2 (NMF) CATHODE MATERIAL. Mugla Journal of Science and Technology. 2019; 5(2): 67-62.