Research Article
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Year 2024, Volume: 5 Issue: 2, 52 - 55, 30.12.2024
https://doi.org/10.46572/naturengs.1586386

Abstract

Project Number

TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056

References

  • Al Zoubi, W., Kamil, M. P., Fatimah, S., Nashrah, N., & Ko, Y. G. (2020). Recent advances in hybrid organic-inorganic materials with spatial architecture for state-of the- art applications. Progress in Materials Science, 112, 100663.
  • Sıdır, İ., Sıdır, Y. G., Khan, N., & Berber, H. (2021). Optoelectronic and photonic properties of π-conjugated benzonitrile derivative bis-Schiff base by solution technique. Optik, 241, 166825.
  • Al Zoubi, W., Khan, M. E., & Ko, Y. G. (2022). A simple method to functionalize the surface of plasma electrolysis produced inorganic coatings for growing different organic structure. Progress in Organic Coatings, 171, 107008.
  • Mantur, S., Patil, M. K., Najare, M. S., Nadaf, A. A., Yaseen, M., Gaonkar, S., & Kamble, R. R. (2021). Design and synthesis of D-π-A form of p-nitrophenylacrylonitrile substituted triphenylamine chromophores; Photophysical, electrochemical properties, DFT and thermal studies. ChemistrySelect, 6(45), 12811-12819.
  • Gündüz, B. (2013). Effects of molarity and solvents on the optical properties of the solutions of tris [4-(5- dicyanomethylidenemethyl-2-thienyl) phenyl] amine (TDCV-TPA) and structural properties of its film. Optical Materials, 36(2), 425-436.
  • Turan, N., Buldurun, K., & Gündüz, B. (2017). Synthesis and structures of Fe (II), Zn (II) and Pd (II) complexes with a Schiff base derived from methyl 2-amino-6-methyl-4, 5, 6, 7-tetrahydrothieno [2, 3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities. Journal of Nanoelectronics and Optoelectronics, 12(9), 1028-1040.
  • Sun, H., Chen, S., Zhong, A., Sun, R., Jin, J., Yang, J.,& Lu, S. (2023). Tuning photophysical properties via positional isomerization of the pyridine ring in donor– acceptor-structured aggregation-induced emission luminogens based on phenylmethylene pyridineacetonitrile derivatives. Molecules, 28(7), 3282.
  • Zhu, L., & Zhao, Y. (2013). Cyanostilbene-based intelligent organic optoelectronic materials. Journal of Materials Chemistry C, 1(6), 1059-1065.
  • Kim, M. J., An, T. K., Kim, S. O., Cha, H., Kim, H. N., Xiofeng, T., & Kim, Y. H. (2015). Molecular design and ordering effects of alkoxy aromatic donor in a DPP copolymer on OTFTs and OPVs. Materials Chemistry and Physics, 153, 63-71.
  • Fang, J. K., Sun, T., Tian, Y., Zhang, Y., Jin, C., Xu, Z., ... & Wang, H. (2017). Novel diyne-bridged dyes for efficient dye-sensitized solar cells. Materials Chemistry and Physics, 195, 1-9.
  • Sharma, G. D., Patel, K. R., Roy, M. S., & Misra, R. (2014). Characterization of two new (A–π) 2–D–A type dyes with different central D unit and their application for dye sensitized solar cells. Organic Electronics, 15(8), 1780- 1790.
  • Jeong, H. G., Khim, D., Jung, E., Yun, J. M., Kim, J., Ku, J., & Kim, D. Y. (2013). Synthesis and characterization of a novel ambipolar polymer semiconductor based on a fumaronitrile core as an electron-withdrawing group. Journal of Polymer Science Part A: Polymer Chemistry, 51(5), 1029-1039.
  • Mao, G., Orita, A., Fenenko, L., Yahiro, M., Adachi, C., & Otera, J. (2009). Blue emitting fluorophores of phenyleneethynylenes substituted by diphenylethenyl terminal groups for organic light-emitting diodes. Materials Chemistry and Physics, 115(1), 378- 384.
  • Guillot, R., Loupy, A., Meddour, A., Pellet, M., & Petit, A. (2005). Solvent-free condensation of arylacetonitrile with aldehydes. Tetrahedron, 61(42), 10129-10137.
  • Yakalı, G., Çoban, M. B., Özen, F., Özen, L. B., Gündüz, B., & Cin, G. T. (2021). The importance of polymorphism dependent aggregation induced enhanced emission of the acrylonitrile derivative: Helical J type and antiparallel h type stacking modes. ChemistrySelect, 6(41), 11392- 11406.
  • Tripathy, S. K. (2015). Refractive indices of semiconductors from energy gaps. Optical materials, 46, 240-246.

Concentration-Driven Enhancement of Optical Properties in 3MeO-4ClAN for Advanced Photonic Applications

Year 2024, Volume: 5 Issue: 2, 52 - 55, 30.12.2024
https://doi.org/10.46572/naturengs.1586386

Abstract

In this study, we investigated the photophysical properties of 2-(4-chlorophenyl)-3-(3-methoxyphenyl)acrylonitrile (3MeO-4ClAN) at various concentrations in DMSO solvent. We specifically examined the effect of different solute concentrations on the optoelectronic properties of this compound, with a focus on applications requiring a low optical band gap. The results demonstrate the potential of 3MeO-4ClAN for optoelectronic applications across a range of concentrations. Experimental optical measurements were performed at different molarities, covering wavelengths from 190 to 1100 nm, using ultraviolet-visible (UV-vis) spectral analysis at room temperature.

Supporting Institution

TÜBİTAK and Akdeniz University

Project Number

TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056

Thanks

We would like to thank the Scientific and Technological Research Council of Turkey (TÜBİTAK, KBAG-119Z608) and Akdeniz University Scientific Research Projects Unit (AU-BAP, FBA-2020-5403 and FDK-2022-6056) for their financial support.

References

  • Al Zoubi, W., Kamil, M. P., Fatimah, S., Nashrah, N., & Ko, Y. G. (2020). Recent advances in hybrid organic-inorganic materials with spatial architecture for state-of the- art applications. Progress in Materials Science, 112, 100663.
  • Sıdır, İ., Sıdır, Y. G., Khan, N., & Berber, H. (2021). Optoelectronic and photonic properties of π-conjugated benzonitrile derivative bis-Schiff base by solution technique. Optik, 241, 166825.
  • Al Zoubi, W., Khan, M. E., & Ko, Y. G. (2022). A simple method to functionalize the surface of plasma electrolysis produced inorganic coatings for growing different organic structure. Progress in Organic Coatings, 171, 107008.
  • Mantur, S., Patil, M. K., Najare, M. S., Nadaf, A. A., Yaseen, M., Gaonkar, S., & Kamble, R. R. (2021). Design and synthesis of D-π-A form of p-nitrophenylacrylonitrile substituted triphenylamine chromophores; Photophysical, electrochemical properties, DFT and thermal studies. ChemistrySelect, 6(45), 12811-12819.
  • Gündüz, B. (2013). Effects of molarity and solvents on the optical properties of the solutions of tris [4-(5- dicyanomethylidenemethyl-2-thienyl) phenyl] amine (TDCV-TPA) and structural properties of its film. Optical Materials, 36(2), 425-436.
  • Turan, N., Buldurun, K., & Gündüz, B. (2017). Synthesis and structures of Fe (II), Zn (II) and Pd (II) complexes with a Schiff base derived from methyl 2-amino-6-methyl-4, 5, 6, 7-tetrahydrothieno [2, 3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities. Journal of Nanoelectronics and Optoelectronics, 12(9), 1028-1040.
  • Sun, H., Chen, S., Zhong, A., Sun, R., Jin, J., Yang, J.,& Lu, S. (2023). Tuning photophysical properties via positional isomerization of the pyridine ring in donor– acceptor-structured aggregation-induced emission luminogens based on phenylmethylene pyridineacetonitrile derivatives. Molecules, 28(7), 3282.
  • Zhu, L., & Zhao, Y. (2013). Cyanostilbene-based intelligent organic optoelectronic materials. Journal of Materials Chemistry C, 1(6), 1059-1065.
  • Kim, M. J., An, T. K., Kim, S. O., Cha, H., Kim, H. N., Xiofeng, T., & Kim, Y. H. (2015). Molecular design and ordering effects of alkoxy aromatic donor in a DPP copolymer on OTFTs and OPVs. Materials Chemistry and Physics, 153, 63-71.
  • Fang, J. K., Sun, T., Tian, Y., Zhang, Y., Jin, C., Xu, Z., ... & Wang, H. (2017). Novel diyne-bridged dyes for efficient dye-sensitized solar cells. Materials Chemistry and Physics, 195, 1-9.
  • Sharma, G. D., Patel, K. R., Roy, M. S., & Misra, R. (2014). Characterization of two new (A–π) 2–D–A type dyes with different central D unit and their application for dye sensitized solar cells. Organic Electronics, 15(8), 1780- 1790.
  • Jeong, H. G., Khim, D., Jung, E., Yun, J. M., Kim, J., Ku, J., & Kim, D. Y. (2013). Synthesis and characterization of a novel ambipolar polymer semiconductor based on a fumaronitrile core as an electron-withdrawing group. Journal of Polymer Science Part A: Polymer Chemistry, 51(5), 1029-1039.
  • Mao, G., Orita, A., Fenenko, L., Yahiro, M., Adachi, C., & Otera, J. (2009). Blue emitting fluorophores of phenyleneethynylenes substituted by diphenylethenyl terminal groups for organic light-emitting diodes. Materials Chemistry and Physics, 115(1), 378- 384.
  • Guillot, R., Loupy, A., Meddour, A., Pellet, M., & Petit, A. (2005). Solvent-free condensation of arylacetonitrile with aldehydes. Tetrahedron, 61(42), 10129-10137.
  • Yakalı, G., Çoban, M. B., Özen, F., Özen, L. B., Gündüz, B., & Cin, G. T. (2021). The importance of polymorphism dependent aggregation induced enhanced emission of the acrylonitrile derivative: Helical J type and antiparallel h type stacking modes. ChemistrySelect, 6(41), 11392- 11406.
  • Tripathy, S. K. (2015). Refractive indices of semiconductors from energy gaps. Optical materials, 46, 240-246.
There are 16 citations in total.

Details

Primary Language English
Subjects Photonics, Optoelectronics and Optical Communications, Organic Chemical Synthesis
Journal Section Research Articles
Authors

Leyla Babali Özen 0000-0001-9023-6604

Furkan Özen 0000-0003-1178-1167

Günseli Turgut Cin 0000-0001-9658-8344

Bayram Gündüz 0000-0002-1447-7534

Project Number TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056
Publication Date December 30, 2024
Submission Date November 16, 2024
Acceptance Date December 9, 2024
Published in Issue Year 2024 Volume: 5 Issue: 2

Cite

APA Babali Özen, L., Özen, F., Turgut Cin, G., Gündüz, B. (2024). Concentration-Driven Enhancement of Optical Properties in 3MeO-4ClAN for Advanced Photonic Applications. NATURENGS, 5(2), 52-55. https://doi.org/10.46572/naturengs.1586386