Conducting Polymer Films on Zn Deposited Carbon Electrode

Year 2023, Volume: 8 Issue: 2, 129 - 139, 07.08.2023

Ali Tuncay Ozyilmaz

https://doi.org/10.28978/nesciences.1342013

Cited By: 2

Abstract

Zn plating on carbon steel (CS) was achieved applying current of 4 mA with galvanostatic technique in acidic medium. Zn particles had homogenous, smooth with spherical structure. It was shown that the Zn particles exhibited active behavior on CS substrate. Poly(aniline), poly(pyrrole), poly(N-methylpyrrole) and poly(o-anisidine) homopolymer films were obtained on CS/Zn electrode. Evaluation of anticorrosion performance of these homopolymer coatings in 3.5 % NaCl solution was investigated by using AC impedance spectroscopy (EIS) technique, anodic polarization and the Eocp-time curves. Homopolymer films exhibited significant physical barrier behavior on Zn plated carbon steel, in longer exposure time.

Keywords

Homopolymer, zinc plating, corrosion

References

• Bagherzadeh, M., Haddadi H., Iranpour M. (2016) Electrochemical evaluation and surface study of magnetite/PANI nanocomposite for carbon steel protection in 3.5 % NaCl. Progress in Organic Coatings, 101, 149-160. https://doi.org/10.1016/j.porgcoat.2016.08.011.
• Bajat, J.B., Maksimovic, M.D., Miskovic-Stankovic, V.B., Zec, S. (2001). Electrodeposition and characterization of Zn-Ni alloys as sublayers for epoxy coating deposition. Journal of Applied Electrochemistry, 31, 355-361. https://doi.org/10.1023/A:1017580019551.
• Camalet, J. L., Lacroix, J. C., Aeiyach, S., Chane-Ching, K., & Lacaze, P. C. (1998). Electrosynthesis of adherent polyaniline films on iron and mild steel in aqueous oxalic acid medium. Synthetic Metals, 93(2), 133-142. https://doi.org/10.1016/S0379-6779(97)04099-X.
• Guenbour, A., Kacemi A., Benbachir, A. (2000). Corrosion protection of copper by polyaminophenol films. Progress in Organic Coatings, 39, 151-155. https://doi.org/10.1016/S0300-9440(00)00141-7.
• Kilinççeker, G., & Galip, H. (2008). The effects of acetate ions (CH3COO−) on electrochemical behavior of copper in chloride solutions. Materials Chemistry and Physics, 110(2-3), 380-386. https://doi.org/10.1016/j.matchemphys.2008.02.026
• Kilinççeker, G., & Demir, H. (2013). The inhibition effects of methionine on corrosion behavior of copper in 3.5% NaCl solution at pH= 8.5. Protection of Metals and Physical Chemistry of Surfaces, 49, 788-797. https://doi.org/10.1134/S2070205113060221.
• Kim, Y., Teshima, K., & Kobayashi, N. (2000). Improvement of reversible photoelectrochromic reaction of polyaniline in polyelectrolyte composite film with the dichloroethane solution system. Electrochimica Acta, 45(8-9), 1549-1553. https://doi.org/10.1016/S0013-4686(99)00373-4.
• Mansfeld, F. (1995). Use of electrochemical impedance spectroscopy for the study of corrosion protection by polymer coatings. Journal of Applied Electrochemistry, 25(3), 187-202. https://doi.org/10.1007/BF00262955.
• Martins, J. I., Reis, T. C., Bazzaoui, M., Bazzaoui, E. A., & Martins, L. (2004). Polypyrrole coatings as a treatment for zinc-coated steel surfaces against corrosion. Corrosion Science, 46(10), 2361-2381. https://doi.org/10.1016/j.corsci.2004.02.006.
• Ozyılmaz, A. T., Kardaş, G., & Erbil, M. (2005). The corrosion performance of polyaniline on nickel plated mild steel. Applied Surface Science, 242(1-2), 97-106. https://doi.org/10.1016/j.apsusc.2004.08.002.
• Ozyilmaz, A.T. (2006). The corrosion performance of polyaniline film modified on nickel plated copper in aqueous p-toluenesulfonic acid solution. Surface & Coatings Technology, 200, 3918-3925. https://doi.org/10.1016/j.surfcoat.2005.01.058.
• Ozyilmaz, A.T., Akdag, A. (2011). Polyaniline, poly (N-methylaniline) and poly (aniline-co-N-methylaniline) coatings on stainless steel. Transactions of the IMF, 89(4), 215-224. https://doi.org/10.1179/174591911X13077162170188.
• Ozyilmaz, A.T., Akdag, A. (2013a). Corrosion protection provided by homo- and copolymer films synthesized in various oxalic and sulphamic acid electrolyte mixtures. Transactions of the IMF., 91 (1), 44-51. https://doi.org/10.1179/0020296712Z.00000000063.
• Ozyilmaz, A. T., Akdag, A., Karahan, I. H., & Ozyilmaz, G. (2013). The influence of polyaniline (PANI) coating on corrosion behaviour of zinc–cobalt coated carbon steel electrode. Progress in Organic Coatings, 76(6), 993-997. https://doi.org/10.1016/j.porgcoat.2012.10.020.
• Ozyilmaz, G., Özyılmaz, A.T., Ağçam, S. (2018). Using Response Surface Methodology for Amperometric Glucose Biosensor Construction. Natural and Engineering Sciences, 3 (1), 1-15. https://doi.org/10.28978/nesciences.379311.
• Shah, K., & Iroh, J. (2002). Electrochemical synthesis and corrosion behavior of poly (N-ethyl aniline) coatings on Al-2024 alloy. Synthetic Metals, 132(1), 35-41. https://doi.org/10.1016/S0379-6779(02)00213-8.
• Sohi, M. H., & Jalali, M. (2003). Study of the corrosion properties of zinc–nickel alloy electrodeposits before and after chromating. Journal of Materials Processing Technology, 138(1-3), 63-66. https://doi.org/10.1016/S0924-0136(03)00050-5.
• Yalçınkaya, S., & Çakmak, D. (2021). Immobilization of CoII‐(N, N′‐bis (salicylidene)‐2‐aminobenzylamine) on poly (pyrrole‐co‐o‐anisidine)/chitosan composite films: Application to electrocatalytic oxidation of catechol. Electroanalysis, 33(3), 755-765. https://doi.org/10.1002/elan.202060243.
• Walter, G. W. (1986). A review of impedance plot methods used for corrosion performance analysis of painted metals. Corrosion Science, 26(9), 681-703. https://doi.org/10.1016/0010-938X(86)90033-8.