Research Article
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Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies

Year 2023, , 872 - 882, 15.07.2023

Şeyda Somaklı , Sultan Bütün Şengel

https://doi.org/10.28948/ngumuh.1262687

Abstract

The hydro(solvo)thermal synthesis method was used to successfully synthesize bare silica aerogels and nano- and microparticle-embedded silica aerogels containing SiO2 and carbon microparticles in this study. New groups were added to these structures through modification. In the study, first, the effect of the variables was systematically examined to determine the optimum conditions. The most suitable recipe for silica aerogel was created. SiO2 and CP particles were synthesized, and modified silica aerogels were prepared with these particles and agents containing amine. For the characterization of synthesized silica aerogel, particles (SiO2, CP) and particle-embedded silica aerogels, TGA, SEM, DLS and BET-BJH techniques were used. These structures were used as adsorbent in environmental applications such as removing organic pollutants like 4-nitro phenol, methylene blue, Victoria blue, bromophenol blue etc. from aqueous media. In this environmental application, the adsorption capacity (mg/g) was determined by using UV-vis spectroscopy. The prepared structures are good adsorbents, and the adsorption capacity can be increased 18-fold with modification.

Keywords

Hydro(solvo)thermal synthesis Silica aerogel CP/SiO2- silica aerogel Adsorption

Supporting Institution

Eskisehir Osmangazi University

Project Number

2021/15A104

Thanks

Eskisehir Osmangazi University (ESOGU) is thanked for financial support. This work has been supported by Eskisehir Osmangazi University Scientific Research Projects Coordination Unit under grant number 2021/15A104.

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Hidro(solvo)termal destekli silika aerojellerin sentezi, modifikasyonu ve onların adsorpsiyon çalışmalarında kullanımı

Year 2023, , 872 - 882, 15.07.2023

Şeyda Somaklı , Sultan Bütün Şengel

https://doi.org/10.28948/ngumuh.1262687

Abstract

Hidro(solvo)termal sentez yöntemi, bu çalışmada SiO2 ve karbon mikropartikülleri gibi nano- ve mikropartikül katkılı silika aerojelleri ile boş silika aerojellerini başarılı bir şekilde sentezlemek için kullanılmıştır. Hazırlanan bu yapılara modifikasyon yoluyla yeni gruplar eklenmiştir. Çalışmada öncelikle optimum koşulların belirlenmesi için değişkenlerin etkisi sistematik olarak incelenmiştir. Silika aerojel için en uygun reçete oluşturulmuştur. SiO2, CP partikülleri sentezlenmiş ve bu partiküller ile ve amin içeren ajanlar ile modifiye silika aerojeller hazırlanmıştır. Sentezlenen silika aerojel, partiküller (SiO2, CP) ve partiküller gömülü silika aerojellerin karakterizasyonu için; TGA, SEM, DLS ve BET-BJH teknikleri kullanıldı. Hazırlanan bu yapılar 4-nitro fenol, metilen mavisi, victoria mavisi, bromofenol mavisi vb. organik kirleticilerin sulu ortamdan uzaklaştırılması gibi çevresel uygulamada adsorban olarak kullanılmıştır. Bu çevresel uygulamada adsorpsiyon kapasitesi (mg/g) UV-vis spektroskopisi ile belirlenmiştir. Hazırlanan yapıların iyi bir adsorban olduğu ve modifikasyon ile adsorpsiyon kapasitesinin 18 kat arttırılabileceği ortaya konulmuştur.

Keywords

Hidro(solvo)termal sentez Silika aerojel CP/SiO2-silika aerojel Adsorpsiyon

Project Number

2021/15A104

References

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  • Tafreshi, O. A., Mosanenzadeh, S. G., Karamikamkar, S., Saadatnia, Z., Park, C. B., & Naguib, H. E. A review on multifunctional aerogel fibers: processing, fabrication, functionalization, and applications. Materials Today Chemistry, 23, 100736, 2022. https://doi.org/10.1016/j.mtchem.2021.100736
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  • Peng, H., Xiong, W., Yang, Z., Xu, Z., Cao, J., Jia, M., & Xiang, Y. Advanced MOFs@ aerogel composites: construction and application towards environmental remediation. Journal of Hazardous Materials, 432, 128684, 2022. https://doi.org/10.1016/j.jhazmat.2 022.128684
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  • Xia, Y., Man, J., Wu, X., Huang, S., Lu, A., Shen, X., ... & Fu, G. Oxygen-vacancy-assisted construction of Ce–TiO2 aerogel for efficiently boosting photocatalytic CO2 reduction without any sacrifice agent. Ceramics International, 49(4), 6100-6112, 2023. https://doi.org/10.1016/j.ceramint.2022.10.118
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  • Nadargi, D. Y., Latthe, S. S., Hirashima, H., & Rao, A. V. Studies on rheological properties of methyltriethoxysilane (MTES) based flexible superhydrophobic silica aerogels. Microporous and Mesoporous Materials, 117(3), 617-626, 2009. https://doi.org/10.1016/j.micromeso.2008.08.025
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  • Diascorn, N., Calas, S., Sallée, H., Achard, P., & Rigacci, A. Polyurethane aerogels synthesis for thermal insulation–textural, thermal, and mechanical properties. The Journal of Supercritical Fluids, 106, 76-84, 2015. https://doi.org/10.1016/j.supflu.2015.05.012
  • Luo, Y., Zhou, Y., Bai, X., Cai, X., Luo, X., Deng, X., & Wu, D. Preparation and characterization of toughened polyurea aerogels incorporating linear long‐chain in the structure. Polymer Engineering & Science, 2023. https://doi.org/10.1002/pen.26260
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  • Hasanpour, M., & Hatami, M. Application of three-dimensional porous aerogels as adsorbent for removal of heavy metal ions from water/wastewater: A review study. Advances in Colloid and Interface Science, 284, 102247, 2020. https://doi.org/10.1016/j.cis.2020.102 247
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There are 51 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Chemical Engineering
Authors

Şeyda Somaklı 0000-0002-8664-7475

Sultan Bütün Şengel 0000-0001-7036-2224

Project Number 2021/15A104
Early Pub Date July 13, 2023
Publication Date July 15, 2023
Submission Date March 9, 2023
Acceptance Date June 13, 2023
Published in Issue Year 2023

Cite

APA Somaklı, Ş., & Bütün Şengel, S. (2023). Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 12(3), 872-882. https://doi.org/10.28948/ngumuh.1262687
AMA Somaklı Ş, Bütün Şengel S. Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies. NÖHÜ Müh. Bilim. Derg. July 2023;12(3):872-882. doi:10.28948/ngumuh.1262687
Chicago Somaklı, Şeyda, and Sultan Bütün Şengel. “Synthesis and Modification of hydro(solvo) Thermal-Supported Silica Aerogels and Their Use in Adsorption Studies”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12, no. 3 (July 2023): 872-82. https://doi.org/10.28948/ngumuh.1262687.
EndNote Somaklı Ş, Bütün Şengel S (July 1, 2023) Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12 3 872–882.
IEEE Ş. Somaklı and S. Bütün Şengel, “Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies”, NÖHÜ Müh. Bilim. Derg., vol. 12, no. 3, pp. 872–882, 2023, doi: 10.28948/ngumuh.1262687.
ISNAD Somaklı, Şeyda - Bütün Şengel, Sultan. “Synthesis and Modification of hydro(solvo) Thermal-Supported Silica Aerogels and Their Use in Adsorption Studies”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12/3 (July 2023), 872-882. https://doi.org/10.28948/ngumuh.1262687.
JAMA Somaklı Ş, Bütün Şengel S. Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies. NÖHÜ Müh. Bilim. Derg. 2023;12:872–882.
MLA Somaklı, Şeyda and Sultan Bütün Şengel. “Synthesis and Modification of hydro(solvo) Thermal-Supported Silica Aerogels and Their Use in Adsorption Studies”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 12, no. 3, 2023, pp. 872-8, doi:10.28948/ngumuh.1262687.
Vancouver Somaklı Ş, Bütün Şengel S. Synthesis and modification of hydro(solvo) thermal-supported silica aerogels and their use in adsorption studies. NÖHÜ Müh. Bilim. Derg. 2023;12(3):872-8.

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