An experimental study on interlaminar shear strength and fracture toughness: Carbon fiber reinforced epoxy composites enhanced with the CaCO3 nanoparticles

Year 2021, , 777 - 783, 27.07.2021

Halil Burak Kaybal

https://doi.org/10.28948/ngumuh.838807

Cited By: 1

Abstract

This study examines the effect of nano-CaCO3 particles on interlaminar shear strength (ILSS) and fracture toughness properties for carbon fiber reinforced epoxy composites. The nano-CaCO3 modified carbon fiber epoxy composites (nC-CFECs) were prepared using the vacuum assisted resin infusion (VARI) method. The short beam shear (SBS) test and single edge notch bending (SENB) test were conducted to calculate ILSS and fracture toughness, respectively. The results illustrate that the introduction of 2% wt. nano-CaCO3 into the epoxy increased the ILSS by up to 24%. Moreover, the fracture toughness in the nanoreinforced composite was 32.3% higher than the unmodified composite. Overall, the nanocomposite material has shown better mechanical performance in terms of ILSS and SENB tests.

Keywords

Carbon fiber, composite, nano-CaCO3, ILSS, SENB

Tabakalararası kayma mukavemeti ve kırılma tokluğu üzerine deneysel bir çalışma: CaCO3 nanoparçacıkları ile iyileştirilmiş karbon fiber takviyeli epoksi kompozitler

Abstract

Bu çalışma, nano-CaCO3 partiküllerin, karbon fiber takviyeli epoksi kompozitlerin tabakalar arası kayma mukavemeti (ILSS) ve kırılma tokluğu özellikleri üzerindeki etkisini incelemek üzere gerçekleştirilmiştir. Nano-CaCO3 ile modifiye edilmiş karbon fiber epoksi kompozit malzemeler (nC-CFEC) vakum destekli reçine infüzyon (VARI) yöntemi kullanılarak hazırlanmıştır. ILSS ve kırılma tokluğunu hesaplamak için sırasıyla kısa kiriş kesme (SBS) testi ve tek kenar çentik eğilme (SENB) testi yapılmıştır. Sonuçlar, epoksiye ağırlıkça %2 nano-CaCO3 eklenmesinin ILSS 'yi %24'e kadar artırdığını göstermektedir. Dahası, nano-takviyeli kompozit malzemede kırılma tokluğu, nano takviyesiz kompozitten %32.3 daha yüksek bulunmuştur. Genel olarak, nanokompozit malzeme, ILSS ve SENB testleri açısından daha iyi bir mekanik performans göstermiştir.

Keywords

Karbon elyaf, kompozit, nano-CaCO3, ILSS, SENB

References

• X. Han, Y. Zhao, J-m. Sun, Y. Li, J-d. Zhang and Y. Hao, Effect of graphene oxide addition on the interlaminar shear property of carbon fiber-reinforced epoxy composites. New Carbon Materials, 32(1), 48-55, 2017. https://doi.org/10.1016/S18725805(17) 60107-0
• W. Mao, J. Chen, M. Si, R. Zhang, Z. Peng and C. Dai, Study of mechanical properties and cracking extension resistance behavior of c/sic composites by single edge notched beam and digital image correlation techniques. Materials Science and Engineering: A, 649, 222-228, 2016. https://doi.org/10.1016/j.msea.2015.09.101
• Z. Fan, M. H. Santare and S. G. Advani, Interlaminar shear strength of glass fiber reinforced epoxy composites enhanced with multi-walled carbon nanotubes. Composites Part A: Applied science and manufacturing, 39(3), 540-554, 2008. https://doi.org/ 10.1016/j.compositesa.2007.11.013
• H. Ulus, H. B. Kaybal, V. Eskizeybek and A. Avcı, Halloysite nanotube reinforcement endows ameliorated fracture resistance of seawater aged basalt/epoxy composites. Journal of Composite Materials, 0021998320902821, 2020. https://doi.org/10.1177/ 0021998320902821
• S. Shadlou, E. Alishahi and M. Ayatollahi, Fracture behavior of epoxy nanocomposites reinforced with different carbon nano-reinforcements. Composite Structures, 95, 577-581, 2013. https://doi.org/10.1016/ j.compstruct.2012.08.002
• H. Ulus, T. Üstün, V. Eskizeybek, Ö. S. Şahin, A. Avcı and M. Ekrem, Boron nitride-mwcnt/epoxy hybrid nanocomposites: Preparation and mechanical properties. Applied Surface Science, 318, 37-42, 2014. https://doi.org/10.1016/j.apsusc.2013.12.070
• A. B. Sengul and E. Asmatulu, Toxicity of metal and metal oxide nanoparticles: A review. Environmental Chemistry Letters, 1-25, 2020. https://doi.org/10.1007/s10311-020-01033-6
• H. Ulus, H. B. Kaybal, V. Eskizeybek and A. Avcı, Enhanced salty water durability of halloysite nanotube reinforced epoxy/basalt fiber hybrid composites. Fibers and Polymers, 20(10), 2184-2199, 2019. https://doi.org/10.1007/s12221-019-9316-y
• A. Rathi and S. I. Kundalwal, Mechanical and fracture behavior of mwcnt/zro2/epoxy nanocomposite systems: Experimental and numerical study. Polymer Composites, 2020. https://doi.org/10.1002 /pc.25551
• T. Yokozeki, Y. Iwahori and S. Ishiwata, Matrix cracking behaviors in carbon fiber/epoxy laminates filled with cup-stacked carbon nanotubes (cscnts). Composites Part A: Applied Science and Manufacturing, 38(3), 917-924, 2007. https://doi.org/10.1016/j.compositesa.2006.07.005
• J. Cha, J. Kim, S. Ryu and S. H. Hong, Comparison to mechanical properties of epoxy nanocomposites reinforced by functionalized carbon nanotubes and graphene nanoplatelets. Composites Part B: Engineering, 162, 283-288, 2019. https://doi.org/10.1016/j.compositesb.2018.11.011
• W. Naous, X. Y. Yu, Q. X. Zhang, K. Naito and Y. Kagawa, Morphology, tensile properties, and fracture toughness of epoxy/al2o3 nanocomposites. Journal of Polymer Science Part B: Polymer Physics, 44(10), 1466-1473, 2006. https://doi.org/10.1002/ polb.20800
• H. He and F. Gao, Resin modification on interlaminar shear property of carbon fiber/epoxy/nano‐caco3 hybrid composites. Polymer Composites, 38(9), 2035-2042, 2017. https://doi.org/10.1002/pc.23775
• H. He and K. Li, Silane coupling agent modification on interlaminar shear strength of carbon fiber/epoxy/nano‐caco3 composites. Polymer composites, 33(10), 1755-1758, 2012. https://doi.org/10.1002/pc.22311
• V. Eskizeybek, H. Ulus, H. B. Kaybal, Ö. S. Şahin and A. Avcı, Static and dynamic mechanical responses of caco3 nanoparticle modified epoxy/carbon fiber nanocomposites. Composites Part B: Engineering, 140, 223-231, 2018. https://doi.org/10.1016/j.compositesb. 2017.12.013
• X. Zhang, H. Peng, A. Limmack and F. Scarpa, Viscoelastic damping behaviour of cup stacked carbon nanotube modified epoxy nanocomposites with tailored interfacial condition and re-agglomeration. Composites science and technology, 105, 66-72, 2014. https://doi.org/ 10.1016/j.compscitech.2014.09.020.
• H. Ulus, The impact of seawater aging on basalt/graphene nanoplatelet-epoxy composites: Performance evaluating by dynamic mechanical analysis (dma) and short beam shear (sbs) tests. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 10(1), 412-419. https://doi.org/10.28948/ ngumuh.791161
• E. F. Şükür, Dry sliding friction and wear properties of caco3 nanoparticle filled epoxy/carbon fiber composites. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 9(2), 1108-1117. https://doi.org/10.28948/ngumuh.725631