KAPYA BİBER ARTIĞI KULLANILARAK BİYOSORPSİYONLA ATIKSULARDAN NİKEL GİDERİMİ

Year 2020, Volume: 9 Issue: 1, 84 - 95, 30.01.2020

Levent Gürel Tuğba Meşe Arife Şeker Aslı Kılıç Ali Serkan Yıldırım

https://doi.org/10.28948/ngumuh.549787

Abstract

Nikel, alıcı ortamlar
için ciddi zararlı etkilere yol açabilen bir ağır metal olup, deşarj edilmeden
önce uygun arıtım yöntemleri kullanılarak giderilmesi gerekmektedir. Bu amaçla,
atıksulardan yeni bir biyosorbent materyali olan kapya biber çekirdeğinin nikel
giderim performansını değerlendirmek için biyosorpsiyon çalışmaları
gerçekleştirilmiştir. Bu çalışmada başlangıç pH değerinin, biyosorbent
dozajının, başlangıç nikel konsantrasyonunun ve zamanın biyosorpsiyon üzerine
olan etkileri araştırılmış, ayrıca kinetik ve denge analizleri de
gerçekleştirilmiştir. Bu çalışmada kullanılan biyosorbent materyali 125 µm ile
250 µm aralığında yer almaktadır. Yapılan çalışmaların neticesinde
biyosorpsiyon verilerinin yalancı ikinci derece reaksiyon kinetik modeli ile çok
iyi bir şekilde tanımlandığı bulunmuş olup, Langmuir izoterm modelinin de deney
sonuçları ile oldukça tutarlı olduğu anlaşılmıştır. Biyosorpsiyon çalışmasında
optimum pH değerinin 5,5 olduğu tespit edilmiştir. Maksimum giderim verimi 28
g/L biyosorbent materyali kullanılarak elde edilmiştir. Maksimum biyosorpsiyon
tutma kapasitesi 4,17 mg/g olarak hesaplanmıştır. Bu çalışma ile atıksulardan
nikel iyonlarının giderimi için bu biyokütlenin bir potansiyele sahip olduğu
bulunmuştur.

Keywords

nikel giderimi, biyosorpsiyon, kapya biber çekirdeği, izoterm, kinetik

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