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Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması

Year 2023, Volume: 12 Issue: 1, 265 - 271, 15.01.2023
https://doi.org/10.28948/ngumuh.1178087

Abstract

Bu çalışmada, metilal/metanol ikili karışımlarının pervaporasyon prosesi ile saflaştırılması için UiO-66 katkılı PEI nanokompozit membranlar hazırlanmıştır. Membranlar, Taramalı elektron mikroskobu (SEM), Fourier dönüşümlü kızılötesi spektroskopisi (FTIR) ve Termogravimetrik analiz (TGA) ile karakterize edilmiştir. Pervaporasyon testleri farklı operasyon sıcaklıklarında, besleme metanol konsantrasyonunda, UiO-66 yükleme oranında ve membran kalınlığında gerçekleştirilmiştir. Optimum çalışma koşulları 30oC çalışma sıcaklığı, ağırlıkça %6 besleme metanol konsantrasyonu, ağırlıkça %0.5 UiO-66 katkılı PEI nanokompozit membran ve 50 µm membran kalınlığı olarak belirlenmiştir. Bu koşullar altında akı ve metanol seçicilik değerleri sırasıyla 1.48 kg/m2.h ve 80126 olarak elde edilmiştir. Elde edilen sonuçlar, pervaporasyon işlemi ile yüksek saflıkta metilal yakıt biyokatkı maddesi ve yeşil solvent elde edilebileceğini göstermektedir.

Supporting Institution

Bursa Teknik Üniversitesi Bilimsel Araştırma Projeleri birimi

Project Number

210ÖAP03

Thanks

Bu çalışma Bursa Teknik Üniversitesi Bilimsel Araştırma Projeleri birimi tarafından 210ÖAP03 numaralı proje kapsamında desteklenmiştir.

References

  • Y. Dong, C. Dai and Z. Lei, Extractive distillation of methylal/methanol mixture using the mixture of dimethylformamide (DMF) and ionic liquid as entrainers. Fuel, 216, 503–512, 2018. https://doi.org/10.1016/j.fuel.2017.12.043
  • X. Lu, J. Ma, L. Ji and Z. Huang, Experimental Study on the Combustion Characteristics and Emissions of Biodiesel Fueled Compression Ignition Engines with Premixed Dimethoxymethane. Energy & Fuels, 21, 3144–3150, 2007. https://doi.org/10.1021/ef070099w.
  • Q. Wang, B. Yu and C. Xu, Design and Control of Distillation System for Methylal/Methanol Separation. Part 1: Extractive Distillation Using DMF as an Entrainer. Industrial & Engineering Chemistry Research, 2012, 51, 1281–1292, 2012. https://doi.org/10.1021/ie201946d.
  • E. Carretier, P. Moulin, M. Beaujean and F. Charbit, Purification and dehydration of methylal by pervaporation. Journal of Membrane Science, 217, 159–171, 2003. https://doi.org/10.1016/S0376-7388(03)00125-X.
  • X. Zhang, S. Zhang and C. Jian, Synthesis of methylal by catalytic distillation. Chemical Engineering Research and Design, 89, 573–580, 2011. https://doi.org/10.1016/j.cherd.2010.09.002.
  • I. D. Wilson, E. D. Adlard, M. Cooke and C. F. Poole, Encyclopedia of Separation Science. Academic Press, Germany, 2006.
  • A., Basile, M.D. Falco, G. Centi and G. Iaquaniello, Membrane Reactor Engineering: Applications for a Greener Process Industry.Wiley, United Kingdom, 2016.
  • A. Basile, A. Figoli and M. Khayet, Pervaporation, Vapour Permeation and Membrane Distillation: Principles and Applications. Woodhead Publishing, UK, 2015.
  • S. Das, A. K. Banthia and B. Adhikari, Improved conversion to ethyl acetate through removal of water of esterification by membrane pervaporation. Indian Journal of Chemical Technology, 14, 552-559, 2007.
  • G. Mensitieri, G. Scherillo, P.L. Manna and P. Musto, Sorption Thermodynamics of CO2, H2O, and CH3OH in a Glassy Polyetherimide: A Molecular Perspective. Membranes, 9, 1-30, 2019. https://doi.org/10.3390/membranes9020023.
  • Y.M. Xu and T.S. Chung, High-performance UiO-66/polyimide mixed matrix membranes for ethanol, isopropanol and n-butanol dehydration via pervaporation. Journal of Membrane Science, 531, 16–26, 2017. https://doi.org/10.1016/j.memsci.2017.02.041.
  • N. Wang, G. Zhang, L. Wang, J. Li, Q. An and S. Ji, Pervaporation dehydration of acetic acid using NH2-UiO-66/PEI mixed matrix membranes. Separation and Purification Technology, 186, 20-27, 2017. https://doi.org/10.1016/j.seppur.2017.05.046.
  • J. Li, X. Si, X. Li, N. Wang, Q. An and S. Ji, Preparation of acid-resistant PEI/SA composite membranes for the pervaporation dehydration of ethanol at low pH. Separation and Purification Technology, 192, 205–212, 2018. https://doi.org/10.1016/j.seppur.2017.09.038.
  • R. Gao, Q. Zhang, R. Lv, F. Soyekwo, A. Zhu and Q. Liu, Highly efficient polymer-MOF nanocomposite membrane for pervaporation separation of water/methanol/MTBE ternary mixture. Chemical Engineering Research and Design, 117, 688-697, 2017. https://doi.org/10.1016/j.cherd.2016.11.027.
  • B. K. Chen, C. Su, T. Tseng and M.C. Tsay, Preparation of Polyetherimide Nanocomposites with Improved Thermal, Mechanical and Dielectric Properties. Polymer Bulletin, 57, 671-681, 2006. https://doi.org/10.1007/s00289-006-0630-3.
  • B. Liu, D. Li, J. Yao and H. Sun, Improved CO2 separation performance and interfacial affinity of mixed matrix membrane by incorporating UiO-66-PEI@[bmim][Tf2N] particles. Separation and Purification Technology, 239, 116519, 2020. https://doi.org/10.1016/j.seppur.2020.116519.
  • W. Ma, T. Li, Q. Zhang, J. Zhong and H. Matsuyama, Preparation of hybrid membranes by incorporating hydrophilic UiO-66 nanoparticles for high-performance pervaporation dehydration of aprotic solvents. Journal of Nanoparticle Research, 22(3),64, 2020. https://doi.org/10.1007/s11051-020-4778-9.
  • F. Demirciyeva, Membran Yöntemi Kullanarak Metan-Karbondioksit Gaz Karışımından Metanın Ayrıştırılması, Yüksek Lisans Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun, Türkiye, 2006.
  • W.F. Guo, T.S. Chung and T. Matsuura, Pervaporation study on the dehydration of aqueous butanol solutions: a comparison of flux vs. permeance, separation factor vs. selectivity. Journal of Membrane Science, 245, 199–210, 2004. https://doi.org/10.1007/s11051-020-4778-9.
  • S. Zhang, Y. Zou, T. Wei, C. Mu, X. Liu and Z. Tong, Pervaporation dehydration of binary and ternary mixtures of n-butyl acetate, n-butanol and water using PVA-CS blended membranes. Separation and Purification Technology, 173, 314–322, 2017. https://doi.org/10.1016/j.seppur.2016.09.047.
  • T.A. Jalal, N.M.S. Bettahalli, N.L. Le and S.P. Nunes, Hydrophobic Hyflon AD/Poly(vinylidene fluoride) Membranes for Butanol Dehydration via Pervaporation. Industrial & Engineering Chemistry Research, 54, 11180–11187, 2015. https://doi.org/10.1021/acs.iecr.5b02754.
  • A.A. Kittur, B.K. Jeevankumar, M.Y. Kariduraganavar and S.D.M College, Pervaporation separation of water-dioxane mixtures through poly (vinyl alcohol)-silicone based hybrid membranes. International Journal of Current Engineering and Technology, 1, 148–156, 2013.
  • C.H. Tsou, Q.F. An, S.C. Lo, M.D. Guzman, W.S. Hung, C.C. Hu and J.Y. Lai, Effect of microstructure of graphene oxide fabricated through different self-assembly techniques on 1-butanol dehydration. Journal of Membrane Science, 477, 93–100, 2015. https://doi.org/10.1016/j.memsci.2014.12.039.
  • H. Zhu, R. Li, G. Liu, Y. Pan, J. Li, Z. Wang, Y. Guo, G. Liu, Liu and W. Liu, Efficient separation of methanol/dimethyl carbonate mixtures by UiO-66 MOF incorporated chitosan mixed-matrix membrane, Journal of Membrane Science, 652, 120473, 2022. https://doi.org/10.1016/j.memsci.2022.120473.

Purification of fuel bioadditive and green solvent methylal by pervaporation process using UiO-66 doped PEI nanocomposite membrane

Year 2023, Volume: 12 Issue: 1, 265 - 271, 15.01.2023
https://doi.org/10.28948/ngumuh.1178087

Abstract

In this study, UiO-66 doped PEI nanocomposite membranes were prepared for the purification of methylal/methanol binary mixtures by pervaporation process. Membranes were characterized by Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and, Thermogravimetric analysis (TGA). Pervaporation tests were performed at different operation temperature, feed methanol concentration, UiO-66 loading ratio and membrane thickness. The optimum operation conditions were determined as 30oC of operation temperature, 6 wt. % of feed methanol concentration, 0.5 wt. % doped PEI membrane and 50 µm of membrane thickness. Under these conditions, flux and methanol selectivity values were 1.48 kg/m2.h and 80126, respectively. The obtained results show that high purity methylal fuel bioadditive and green solvent can be acquired by pervaporation process.

Project Number

210ÖAP03

References

  • Y. Dong, C. Dai and Z. Lei, Extractive distillation of methylal/methanol mixture using the mixture of dimethylformamide (DMF) and ionic liquid as entrainers. Fuel, 216, 503–512, 2018. https://doi.org/10.1016/j.fuel.2017.12.043
  • X. Lu, J. Ma, L. Ji and Z. Huang, Experimental Study on the Combustion Characteristics and Emissions of Biodiesel Fueled Compression Ignition Engines with Premixed Dimethoxymethane. Energy & Fuels, 21, 3144–3150, 2007. https://doi.org/10.1021/ef070099w.
  • Q. Wang, B. Yu and C. Xu, Design and Control of Distillation System for Methylal/Methanol Separation. Part 1: Extractive Distillation Using DMF as an Entrainer. Industrial & Engineering Chemistry Research, 2012, 51, 1281–1292, 2012. https://doi.org/10.1021/ie201946d.
  • E. Carretier, P. Moulin, M. Beaujean and F. Charbit, Purification and dehydration of methylal by pervaporation. Journal of Membrane Science, 217, 159–171, 2003. https://doi.org/10.1016/S0376-7388(03)00125-X.
  • X. Zhang, S. Zhang and C. Jian, Synthesis of methylal by catalytic distillation. Chemical Engineering Research and Design, 89, 573–580, 2011. https://doi.org/10.1016/j.cherd.2010.09.002.
  • I. D. Wilson, E. D. Adlard, M. Cooke and C. F. Poole, Encyclopedia of Separation Science. Academic Press, Germany, 2006.
  • A., Basile, M.D. Falco, G. Centi and G. Iaquaniello, Membrane Reactor Engineering: Applications for a Greener Process Industry.Wiley, United Kingdom, 2016.
  • A. Basile, A. Figoli and M. Khayet, Pervaporation, Vapour Permeation and Membrane Distillation: Principles and Applications. Woodhead Publishing, UK, 2015.
  • S. Das, A. K. Banthia and B. Adhikari, Improved conversion to ethyl acetate through removal of water of esterification by membrane pervaporation. Indian Journal of Chemical Technology, 14, 552-559, 2007.
  • G. Mensitieri, G. Scherillo, P.L. Manna and P. Musto, Sorption Thermodynamics of CO2, H2O, and CH3OH in a Glassy Polyetherimide: A Molecular Perspective. Membranes, 9, 1-30, 2019. https://doi.org/10.3390/membranes9020023.
  • Y.M. Xu and T.S. Chung, High-performance UiO-66/polyimide mixed matrix membranes for ethanol, isopropanol and n-butanol dehydration via pervaporation. Journal of Membrane Science, 531, 16–26, 2017. https://doi.org/10.1016/j.memsci.2017.02.041.
  • N. Wang, G. Zhang, L. Wang, J. Li, Q. An and S. Ji, Pervaporation dehydration of acetic acid using NH2-UiO-66/PEI mixed matrix membranes. Separation and Purification Technology, 186, 20-27, 2017. https://doi.org/10.1016/j.seppur.2017.05.046.
  • J. Li, X. Si, X. Li, N. Wang, Q. An and S. Ji, Preparation of acid-resistant PEI/SA composite membranes for the pervaporation dehydration of ethanol at low pH. Separation and Purification Technology, 192, 205–212, 2018. https://doi.org/10.1016/j.seppur.2017.09.038.
  • R. Gao, Q. Zhang, R. Lv, F. Soyekwo, A. Zhu and Q. Liu, Highly efficient polymer-MOF nanocomposite membrane for pervaporation separation of water/methanol/MTBE ternary mixture. Chemical Engineering Research and Design, 117, 688-697, 2017. https://doi.org/10.1016/j.cherd.2016.11.027.
  • B. K. Chen, C. Su, T. Tseng and M.C. Tsay, Preparation of Polyetherimide Nanocomposites with Improved Thermal, Mechanical and Dielectric Properties. Polymer Bulletin, 57, 671-681, 2006. https://doi.org/10.1007/s00289-006-0630-3.
  • B. Liu, D. Li, J. Yao and H. Sun, Improved CO2 separation performance and interfacial affinity of mixed matrix membrane by incorporating UiO-66-PEI@[bmim][Tf2N] particles. Separation and Purification Technology, 239, 116519, 2020. https://doi.org/10.1016/j.seppur.2020.116519.
  • W. Ma, T. Li, Q. Zhang, J. Zhong and H. Matsuyama, Preparation of hybrid membranes by incorporating hydrophilic UiO-66 nanoparticles for high-performance pervaporation dehydration of aprotic solvents. Journal of Nanoparticle Research, 22(3),64, 2020. https://doi.org/10.1007/s11051-020-4778-9.
  • F. Demirciyeva, Membran Yöntemi Kullanarak Metan-Karbondioksit Gaz Karışımından Metanın Ayrıştırılması, Yüksek Lisans Tezi, Ondokuz Mayıs Üniversitesi Fen Bilimleri Enstitüsü, Samsun, Türkiye, 2006.
  • W.F. Guo, T.S. Chung and T. Matsuura, Pervaporation study on the dehydration of aqueous butanol solutions: a comparison of flux vs. permeance, separation factor vs. selectivity. Journal of Membrane Science, 245, 199–210, 2004. https://doi.org/10.1007/s11051-020-4778-9.
  • S. Zhang, Y. Zou, T. Wei, C. Mu, X. Liu and Z. Tong, Pervaporation dehydration of binary and ternary mixtures of n-butyl acetate, n-butanol and water using PVA-CS blended membranes. Separation and Purification Technology, 173, 314–322, 2017. https://doi.org/10.1016/j.seppur.2016.09.047.
  • T.A. Jalal, N.M.S. Bettahalli, N.L. Le and S.P. Nunes, Hydrophobic Hyflon AD/Poly(vinylidene fluoride) Membranes for Butanol Dehydration via Pervaporation. Industrial & Engineering Chemistry Research, 54, 11180–11187, 2015. https://doi.org/10.1021/acs.iecr.5b02754.
  • A.A. Kittur, B.K. Jeevankumar, M.Y. Kariduraganavar and S.D.M College, Pervaporation separation of water-dioxane mixtures through poly (vinyl alcohol)-silicone based hybrid membranes. International Journal of Current Engineering and Technology, 1, 148–156, 2013.
  • C.H. Tsou, Q.F. An, S.C. Lo, M.D. Guzman, W.S. Hung, C.C. Hu and J.Y. Lai, Effect of microstructure of graphene oxide fabricated through different self-assembly techniques on 1-butanol dehydration. Journal of Membrane Science, 477, 93–100, 2015. https://doi.org/10.1016/j.memsci.2014.12.039.
  • H. Zhu, R. Li, G. Liu, Y. Pan, J. Li, Z. Wang, Y. Guo, G. Liu, Liu and W. Liu, Efficient separation of methanol/dimethyl carbonate mixtures by UiO-66 MOF incorporated chitosan mixed-matrix membrane, Journal of Membrane Science, 652, 120473, 2022. https://doi.org/10.1016/j.memsci.2022.120473.
There are 24 citations in total.

Details

Primary Language Turkish
Subjects Chemical Engineering
Journal Section Chemical Engineering
Authors

Derya Ünlü 0000-0001-5240-5876

Project Number 210ÖAP03
Publication Date January 15, 2023
Submission Date September 21, 2022
Acceptance Date November 18, 2022
Published in Issue Year 2023 Volume: 12 Issue: 1

Cite

APA Ünlü, D. (2023). Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 12(1), 265-271. https://doi.org/10.28948/ngumuh.1178087
AMA Ünlü D. Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması. NOHU J. Eng. Sci. January 2023;12(1):265-271. doi:10.28948/ngumuh.1178087
Chicago Ünlü, Derya. “Yakıt Biyokatkı Maddesi Ve yeşil Solvent Metilalin UiO-66 katkılı PEI Nanokompozit Membran kullanılarak Pervaporasyon Prosesi Ile saflaştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12, no. 1 (January 2023): 265-71. https://doi.org/10.28948/ngumuh.1178087.
EndNote Ünlü D (January 1, 2023) Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12 1 265–271.
IEEE D. Ünlü, “Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması”, NOHU J. Eng. Sci., vol. 12, no. 1, pp. 265–271, 2023, doi: 10.28948/ngumuh.1178087.
ISNAD Ünlü, Derya. “Yakıt Biyokatkı Maddesi Ve yeşil Solvent Metilalin UiO-66 katkılı PEI Nanokompozit Membran kullanılarak Pervaporasyon Prosesi Ile saflaştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 12/1 (January 2023), 265-271. https://doi.org/10.28948/ngumuh.1178087.
JAMA Ünlü D. Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması. NOHU J. Eng. Sci. 2023;12:265–271.
MLA Ünlü, Derya. “Yakıt Biyokatkı Maddesi Ve yeşil Solvent Metilalin UiO-66 katkılı PEI Nanokompozit Membran kullanılarak Pervaporasyon Prosesi Ile saflaştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 12, no. 1, 2023, pp. 265-71, doi:10.28948/ngumuh.1178087.
Vancouver Ünlü D. Yakıt biyokatkı maddesi ve yeşil solvent metilalin UiO-66 katkılı PEI nanokompozit membran kullanılarak pervaporasyon prosesi ile saflaştırılması. NOHU J. Eng. Sci. 2023;12(1):265-71.

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