KNT ilaveli PET/Cam elyaf takviyeli termoplastik kompozitlerin eğilme özelliklerinin araştırılması
Year 2024,
Volume: 13 Issue: 3, 861 - 872, 15.07.2024
Özgür Demircan
,
Sara Sufyan
,
Ahmed Mohamed Basem
Abstract
Bu çalışma kapsamında, kıvrımsız kumaş (NCF) ile takviyeli hibrit kompozitler üretmek ve saf kompozitlerin mekanik özelliklerini iyileştirmek amacıyla çok duvarlı karbon nanotüpler (ÇDKNT'ler) (ağırlıkça yüzdeleri %0 ve %0.9) ve modifiye edilmiş ÇDKNT'ler (ÇDKNT-karboksilik asit (COOH)) (ağırlıkça yüzdeleri %0 ve %0.9) polietilen tereftalat (PET) termoplastik polimerine ve cam elyaf (GF) takviye elyaflarına ilave edilmiştir. NCF yapısına sahip takviye kumaşlarda 0° ve 90° yönlerinde yönlenmiş elyaflar bulunmaktadır. Üretilen kompozit numunelerinin mekanik özelliklerini belirlemek için 0° ve -45° yönlerinde hazırlanmış test numunelerine üç nokta eğme testleri yapılmıştır. Kompozitlerin mikro yapısı ve morfolojisi taramalı elektron mikroskobu (SEM) ve optik mikroskop (OM) kullanılarak incelenmiştir. ÇDKNT-COOH içeren numuneler, 0° yönünde ÇDKNT-COOH içermeyen numunelerle karşılaştırıldığında %58.6 eğilme modülü ve %14.4 eğilme mukavemeti artışıyla en yüksek eğilme özellikleri değerini sergilemiştir.
Ethical Statement
Bu çalışmanın, özgün bir çalışma olduğunu; çalışmanın hazırlık, veri toplama, analiz
ve bilgilerin sunumu olmak üzere tüm aşamalarından bilimsel etik ilke ve kurallarına uygun
davrandığımı; bu çalışma kapsamında elde edilmeyen tüm veri ve bilgiler için kaynak
gösterdiğimi ve bu kaynaklara kaynakçada yer verdiğimi; kullanılan verilerde herhangi bir
değişiklik yapmadığımı, çalışmanın Committee on Publication Ethics (COPE)' in tüm şartlarını
ve koşullarını kabul ederek etik görev ve sorumluluklara riayet ettiğimi beyan ederim.
Supporting Institution
Bu araştırma Ondokuz Mayıs Üniversitesi araştırma fonu tarafından desteklenmiştir (PYO.MUH.1901.16.001 ve PYO.MUH.1901.18.008).
Project Number
Bu araştırma Ondokuz Mayıs Üniversitesi araştırma fonu tarafından desteklenmiştir (PYO.MUH.1901.16.001 ve PYO.MUH.1901.18.008).
Thanks
Bu araştırma Ondokuz Mayıs Üniversitesi araştırma fonu tarafından desteklenmiştir (PYO.MUH.1901.16.001 ve PYO.MUH.1901.18.008).
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Investigation of the effect of CNTs on the flexural properties of PET/Glass fiber integrated thermoplastic composites
Year 2024,
Volume: 13 Issue: 3, 861 - 872, 15.07.2024
Özgür Demircan
,
Sara Sufyan
,
Ahmed Mohamed Basem
Abstract
Within this study, multi-walled carbon nanotubes (MWCNTs) (weight percentages were 0 and 0.9 wt %) and modified MWCNTs (MWCNTs-Carboxylic acid (COOH)) (weight percentages were 0 and 0.9 wt %) were incorporated into the thermoplastic polymer of polyethylene terephthalate (PET) and reinforcement fibers of the glass fiber (GF) to fabricate hybrid composites with non-crimp fabrics (NCFs) with higher mechanical properties compared to the pristine. NCF reinforcements had fibers which were laid in 0° and 90° directions. The three-point bending tests were performed to understand the mechanical properties of the fabricated composite samples in 0° and -45° directions. The micro-structure and morphology of the composites were studied by using a scanning electron microscope (SEM) and optical microscopy (OM). The specimens with MWCNTs-COOH exhibited highest value of flexural properties with an improvement of 58.6% flexural modulus and 14.4% flexural strength compared to the specimens without MWCNTs-COOH in 0° direction.
Project Number
Bu araştırma Ondokuz Mayıs Üniversitesi araştırma fonu tarafından desteklenmiştir (PYO.MUH.1901.16.001 ve PYO.MUH.1901.18.008).
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- K. Bilisik, G. Erdogan and E. Sapanci, Flexural behavior of 3D para-aramid/phenolic/nano (MWCNT) composites. RSC Advances, 8(13), 7213–7224, 2018. https://doi.org/10.1039/C7RA13437A.
- K. Bilisik, N. Karaduman, G. Erdogan, E. Sapanci and S. Gungor, In-plane shear of nanoprepreg/nanostitched three-dimensional carbon/epoxy multiwalled carbon nanotubes composites. Journal of Composite Materials, 53(24), 3413–3431, 2019. https://doi.org/10.1177/0021998319841671.
- H. Hamada, K. Sugimoto, A. Nakai, N. Takeda, S. Gotoh and T. Ishida, Mechanical properties of knitted fabric composites. Journal of Reinforced Plastics and Composites, 19(5), 364–376, 2000. http://dx.doi.org 10.1177/073168440001900502.
- J. B. Khan, A. C. Smith, P. M. Tuohy, M. Gresil, C. Soutis and A. Lambourne, Experimental electrical characterisation of carbon fibre composites for use in future aircraft applications. IET Science, Measurement & Technology, 13(8), 1131–1138, 2019. https://doi.org/10.1049/IET-SMT.2018.5601.
- N. Wiegand and E. Mäder, Commingled yarn spinning for thermoplastic/glass fiber composites. Fibers, 5(3), 26, 2017. https://doi.org/10.3390/FIB5030026.
- Ö. Demircan, S. Ashibe, T. Kosui and A. Nakai, Effect of various knitting techniques on mechanical properties of biaxial weft-knitted thermoplastic composites. Journal of Thermoplastic Composite Materials, 28(6), 896–910, 2014. https://doi.org/10.1177/0892705713519121.
- N. Svensson, R. Shishoo and M. Gilchrist, Manufacturing of thermoplastic composites from commingled yarns-A Review. Journal of Thermoplastic Composite Materials, 11(1), 22–56, 1998. https://doi.org/10.1177/089270579801100102.
- K. Friedrich, Commingled yarns and their use for composites, Polymer Science and Technology Series book series (POLS,volume 2), 81–89, 1999, https://doi.org/10.1007/978-94-011-4421-6_12.
- S. Fakirov, Nano- and microfibrillar single-polymer composites: A Review. Macromolecular Materials and Engineering, 298(1), 9–32, 2013. https://doi.org/10.1002/MAME.201200226.
- S. H. Jin, Y. Bin Park and K. H. Yoon, Rheological and mechanical properties of surface modified multi-walled carbon nanotube-filled PET composite. Composites Science and Technology, 67(15–16), 3434–3441, 2007. https://doi.org/10.1016/J.COMPSCITECH.2007.03.013.
- B. W. Ahn, Y. S. Chi and T. J. Kang, Preparation and characterization of multi-walled carbon nanotube/poly(ethylene terephthalate) nanoweb. Journal of Applied Polymer Science, 110(6), 4055–4063, 2008. https://doi.org/10.1002/APP.28968.
- L. Long, W. Shanyuan and Y. Jianyong, Niscair-Csir, 27(3), 287, 2002.
- Z. Shen, S. Bateman, D. Y. Wu, P. McMahon, M. Dell’Olio and J. Gotama, The effects of carbon nanotubes on mechanical and thermal properties of woven glass fibre reinforced polyamide-6 nanocomposites. Composites Science and Technology, 69(2), 239–244, 2009. https://doi.org/10.1016/J.COMPSCITECH.2008.10.017.
- O. Demircan, A. Al-darkazali, Inanç and V. Eskizeybek, Investigation of the effect of CNTs on the mechanical properties of LPET/glass fiber thermoplastic composites. Journal of Thermoplastic Composite Materials, 33(12), 1652–1673, 2019. https://doi.org/10.1177/0892705719833105.
- N. M. Zulfli, A. A. Bakar and W. S. Chow, Mechanical and water absorption behaviors of carbon nanotube reinforced epoxy/glass fiber laminates. Journal of Reinforced Plastics and Composites, 32(22), 1715–1721, 2013. https://doi.org/10.1177/0731684413501926.
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