Demir katkılı zeolitik imidazol ağ yapısı katalizörler kullanılarak fenton benzeri oksidasyonu ile kristal viyole gideriminde reaksiyon parametrelerinin ve kinetiğinin incelenmesi

Year 2025, Volume: 14 Issue: 1, 1 - 1

Esra Yılmaz Mertsoy , Burcu Palas

https://doi.org/10.28948/ngumuh.1537619

Abstract

Kristal Viyole (KV), tekstil ve kâğıt endüstrilerinde yaygın olarak kullanılan sentetik bir boyadır. Bu boya, çevreye atıldığında su kaynaklarında kalıcı kirliliğe yol açabilir, biyolojik olarak parçalanması zordur ve toksik etkileri nedeniyle sucul yaşamı olumsuz etkiler. Bu nedenle, KV'nin su kaynaklarından etkin bir şekilde giderilmesi büyük önem taşır. KV'nin giderimi, çevre sağlığının korunması, ekosistem dengesinin sürdürülebilmesi ve insan sağlığının olumsuz etkilenmesinin önlenmesi açısından kritik bir konudur. Bu çalışmada Demir yüklü ZIF-8 sentezi gerçekleştirilmiştir (Fe/ZIF-8). Zeolit imidazol ağ yapıları, yüksek kimyasal stabilite ve esneklik sergileyen ve reaksiyonlarda, gaz ayırma ve saflaştırma, gibi uygulamalarda kullanılan çok sağlam yapıya sahip gözenekli koordinasyon polimerleridir. Düşük üretim maliyetleri, kolay sentez yöntemleri ve işlevselleştirilebilirliği nedeniyle atık su arıtım proseslerinde kullanılmak üzere zeolit imidazol ağ yapıları seçilmiştir. Sentezlenen Fe yüklü ZIF-8 Fenton benzeri oksidasyonu yöntemi ile atık sulardan KV uzaklaştırılmasında kullanılmıştır. Fenton benzeri oksidasyonunda Fe-ZIF-8 kullanımı ile 60 dakikada %99.6 KV giderimi sağlanmış ve gerçekleştirilen kinetik çalışmalarda boya gideriminin birinci mertebeden reaksiyon kinetiğine uyduğu belirlenmiştir.

Keywords

Kristal Viyole, Zeolitik imidazol ağ yapısı, Fenton, ZIF-8

Project Number

Türkiye Bilimsel ve Teknolojik Araştırma Kurumu (TÜBİTAK) (Proje Numarası: 124M775) ve Çankırı Karatekin Üniversitesi Bilimsel Araştırma Projeleri BAP(MF081123B21)

Investigation of reaction parameters and kinetics for crystal violet removal by fenton-like oxidation using iron-doped zeolitic imidazole framework catalysts

Abstract

Crystal Violet (CV) is a synthetic dye widely used in the textile and paper industries. This dye can cause permanent pollution in water resources when discharged into the environment, is difficult to biodegrade and adversely affects aquatic life due to its toxic effects. Therefore, effective removal of CV from water resources is of great importance. Removal of CV is a critical issue in terms of protecting environmental health, maintaining ecosystem balance and preventing negative effects on human health.
In this study, the synthesis of Iron-loaded ZIF-8 (Fe/ZIF-8) was carried out. Zeolite imidazole network structures are porous coordination polymers with very robust structures that exhibit high chemical stability and flexibility and are used in applications such as reactions, gas separation and purification. Zeolite imidazole network structures were selected for use in wastewater treatment processes due to their low production costs, easy synthesis methods and functionalizability. The synthesized Fe-loaded ZIF-8 was used in the removal of CV from wastewater by Fenton-like oxidation method. 99.6% CV removal was achieved in 60 min by using Fe-ZIF-8 in Fenton-like oxidation and the performed kinetic studies determined that the dye removal obeyed the first-order reaction kinetics.

Keywords

Crystal Violet, Zeolitic Imidazolate Framework, Fenton, ZIF-8

Project Number

Türkiye Bilimsel ve Teknolojik Araştırma Kurumu (TÜBİTAK) (Proje Numarası: 124M775) ve Çankırı Karatekin Üniversitesi Bilimsel Araştırma Projeleri BAP(MF081123B21)

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