Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature

Hasan Erge; Hakan Turan; Ali Riza Kul

doi:10.20863/nsd.277898

Research Article

Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature

Year 2016, , 56 - 61, 15.11.2016

Hasan Erge Hakan Turan Ali Riza Kul

https://doi.org/10.20863/nsd.277898

Abstract

Objective: In this study, the solubility, density,
conductivity and phase equilibria of the Na₂(H₂PO₂)₂-Ba(H₂PO₂)₂-H₂O
ternary system located in the structure of the Na⁺, Ba²⁺, (H₂PO₂)-//H₂O
quaternary reciprocal
water-salt system were investigated using physicochemical analysis methods.

Material and
Methods: Riedel-de Haen and Merck salts were used
to investigate the solubility and phase equilibria of the Na2(H2PO2)2
-Ba(H2PO2)2-H2O ternary water–salt system at room temperature

Results: It was determined that the Na₂(H₂PO₂)₂-Ba(H₂PO₂)₂-H₂O
ternary water-salt system belongs to the simple eutonic system type and the
compositions corresponding to the eutonic point, expressed as mass %, were
50.73, 0.53 and 48.74 (w/w %) for Na₂(H₂PO₂)₂,
Ba(H₂PO₂)₂ and H₂O, respectively

Keywords

Na2(H2PO2)2-Ba(H2PO2)2-H2O Ternary Water-Salt System, Isothermic System, Density, Solubility

References

1. Özdek U. 2009. NaCl-Ba(H2PO2)2-H2O Üçlü Su-Tuz Sisteminin Oda Sıcaklığında İzotermik Yöntemle Çözünürlüğünün ve Faz Dengelerinin Araştırılması (unpublished master’s thesis). YYÜ, Fen Bilimleri Enstitüsü, Van.
2. Alişoğlu V. 1973. Potasyum ve Manganın Bromür ve Sülfatlarını İhtiva Eden Karşılıklı Su-Tuz Sisteminin Fizikokimyasal Araştırılması (doctoral thesis). Bakü.
3. Erge H, Adıgüzel V, Alişoğlu V. Study of the solubility İn Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and İn Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 ◦C. Elsevier. 2013; 344:13–18.
4. Aliev VA, Velieva SM, 1985. Sodium chloride manganese-hypophosphate-water system at 20-degrees-c. Zr. Neorg. Khim. 1985; 30:798-800.
5. Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+ , Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+ , Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+ , Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.
6. Erge H, Adıgüzel V, Kul AR, Karatay O, Yenigün A. BaCl2- Ba(H2PO2)2- H2O üçlü sisteminin 00C ve +250C'de çözünürlüğünün ve faz dengelerinin araştırılması. 25. Ulusal Kimya Kongresi, 27 Haziran-2 Temmuz 2011, Erzurum, Türkiye.
7. Gülensoy H. Kompleksometrinin esasları ve kompleksometrik titrasyonlar kitabı, Türkiye Kimya Derneği Yayınları. 2003; 255: 126-131.
8. Erge H, Adıgüzel V, Kul AR, Alişoğlu V. Na2Cl2/BaCl2/ Ba(H2PO2)2/ H2O sisteminin fizikokimyasal analizi. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2008; 1: 33-36.

Year 2016, , 56 - 61, 15.11.2016

Hasan Erge Hakan Turan Ali Riza Kul

https://doi.org/10.20863/nsd.277898

Abstract

References

1. Özdek U. 2009. NaCl-Ba(H2PO2)2-H2O Üçlü Su-Tuz Sisteminin Oda Sıcaklığında İzotermik Yöntemle Çözünürlüğünün ve Faz Dengelerinin Araştırılması (unpublished master’s thesis). YYÜ, Fen Bilimleri Enstitüsü, Van.
2. Alişoğlu V. 1973. Potasyum ve Manganın Bromür ve Sülfatlarını İhtiva Eden Karşılıklı Su-Tuz Sisteminin Fizikokimyasal Araştırılması (doctoral thesis). Bakü.
3. Erge H, Adıgüzel V, Alişoğlu V. Study of the solubility İn Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and İn Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 ◦C. Elsevier. 2013; 344:13–18.
4. Aliev VA, Velieva SM, 1985. Sodium chloride manganese-hypophosphate-water system at 20-degrees-c. Zr. Neorg. Khim. 1985; 30:798-800.
5. Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+ , Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+ , Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+ , Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.
6. Erge H, Adıgüzel V, Kul AR, Karatay O, Yenigün A. BaCl2- Ba(H2PO2)2- H2O üçlü sisteminin 00C ve +250C'de çözünürlüğünün ve faz dengelerinin araştırılması. 25. Ulusal Kimya Kongresi, 27 Haziran-2 Temmuz 2011, Erzurum, Türkiye.
7. Gülensoy H. Kompleksometrinin esasları ve kompleksometrik titrasyonlar kitabı, Türkiye Kimya Derneği Yayınları. 2003; 255: 126-131.
8. Erge H, Adıgüzel V, Kul AR, Alişoğlu V. Na2Cl2/BaCl2/ Ba(H2PO2)2/ H2O sisteminin fizikokimyasal analizi. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2008; 1: 33-36.

There are 8 citations in total.

Details

Journal Section	Original Articles
Authors	Hasan Erge This is me Hakan Turan This is me Ali Riza Kul
Publication Date	November 15, 2016
Published in Issue	Year 2016

Cite

APA	Erge, H., Turan, H., & Kul, A. R. (2016). Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Natural Science and Discovery, 2(3), 56-61. https://doi.org/10.20863/nsd.277898
AMA	Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. September 2016;2(3):56-61. doi:10.20863/nsd.277898
Chicago	Erge, Hasan, Hakan Turan, and Ali Riza Kul. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery 2, no. 3 (September 2016): 56-61. https://doi.org/10.20863/nsd.277898.
EndNote	Erge H, Turan H, Kul AR (September 1, 2016) Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Natural Science and Discovery 2 3 56–61.
IEEE	H. Erge, H. Turan, and A. R. Kul, “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”, Nat Sci Discov, vol. 2, no. 3, pp. 56–61, 2016, doi: 10.20863/nsd.277898.
ISNAD	Erge, Hasan et al. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery 2/3 (September 2016), 56-61. https://doi.org/10.20863/nsd.277898.
JAMA	Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. 2016;2:56–61.
MLA	Erge, Hasan et al. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery, vol. 2, no. 3, 2016, pp. 56-61, doi:10.20863/nsd.277898.
Vancouver	Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. 2016;2(3):56-61.