Fractal adsorption characteristics and statistical analysis approach of complex dye molecule on metal oxide particles—A case study of Reactive Black 5(RB 5) adsorption onto NiO nanoparticles

Year 2022, Volume: 7 Issue: 2, 81 - 93, 31.12.2022

Ferda GONEN Gizem BİÇER

https://doi.org/10.56171/ojn.1065924

Cited By: 1

Abstract

In this study, environmental conditions for high efficient dye adsorption; initial pH, initial dye concentration, temperature, adsorbent concentration were determined as 6.0, 40oC, 100 mgL-1 and 1 g L-1, respectively. Obtained results from SEM, FT-IR and XRD analyzes were evaluated and compared with foundings in literature.
It was found that the equilibrium data can be best represented with Langmuir isotherm model, and it was concluded that RB 5-NiO adsorption system behaviour was explained the pseudo-second order kinetic model successfully. It was concluded that dye-nanoadsorbent system was exothermic (ΔH <0) and voluntary (ΔG<0). In thermodynamic analysis, RB 5 to NiO system adsorption proved that system has no structural change (S <0) at the adsobent-solution interface.
RSM (Response Surface Method) was used to express the interaction between process variables and responses and to examine the adsorption data. Removal percentages were determined theoretically using Design Expert 9.0.6 software program, and quadratic regression model was developed. It was seen that the adsorption parameters for the highest color removal obtained by the classical method were compared with the parameters found from RSM approach obtained under the same experimental conditions support each other.

Keywords

adsorption, RSM, nanotechnology

Supporting Institution

Mersin Üniversitesi

Thanks

We would like to thank Mersin University Cemical Engineering Laboratories and Advanced Technology Education, Research and Application Center, which was used in determination of particle surface properties in experimental studies.

Metal oksit parçacıkları üzerinde kompleks boya molekülünün fraktal adsorpsiyon özellikleri ve istatistiksel analiz yaklaşımı—NiO nanoparçacıkları üzerine Reaktif Siyah 5(RB 5) adsorpsiyonu çalışması

Abstract

Bu çalışmada, yüksek verimli boya adsorpsiyonu için çevre koşulları; başlangıç ​​pH, başlangıç ​​boya konsantrasyonu, sıcaklık, adsorban konsantrasyonu sırasıyla 6.0, 40oC, 100 mgL-1 ve 1 g L-1 olarak belirlenmiştir. SEM, FT-IR ve XRD analizlerinden elde edilen sonuçlar değerlendirilmiş ve literatürdeki temel bilgilerle karşılaştırılmıştır.
Denge verilerinin en iyi Langmuir izoterm modeli ile temsil edilebileceği bulunmuş ve RB 5-NiO adsorpsiyon sistem davranışının yalancı ikinci dereceden kinetik modeli başarıyla açıkladığı sonucuna varılmıştır. Boya-nanoadsorban sisteminin ekzotermik (ΔH <0) ve gönüllü (ΔG<0) olduğu sonucuna varılmıştır. Termodinamik analizde, RB 5 ila NiO sistem adsorpsiyonu, adsorpsiyon-çözelti arayüzünde sistemin yapısal bir değişikliğinin (S <0) olmadığını kanıtlamıştır.
Proses değişkenleri ve tepkiler arasındaki etkileşimi ifade etmek ve adsorpsiyon verilerini incelemek için RSM (Yanıt Yüzey Metodu) kullanılmıştır. Giderim yüzdeleri, Design Expert 9.0.6 yazılım programı kullanılarak teorik olarak belirlenmiş ve ikinci dereceden regresyon modeli geliştirilmiştir. Klasik yöntemle en yüksek renk giderimi için elde edilen adsorpsiyon parametrelerinin, aynı deneysel koşullar altında RSM yaklaşımından bulunan parametrelerle örtüştüğü ve birbirini desteklediği görülmüştür.

Keywords

adsorpsiyon, nanoparçacık, RSM

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