Research Article
BibTex RIS Cite

Sıvı kristaller ve nanopartikül arasındaki etkileşimlerin belirlenmesi üzerine çalışma: Nanopartikül katkılı sıvı kristallerin floresan spektrumları

Year 2023, Volume: 8 Issue: 1, 50 - 64, 30.06.2023
https://doi.org/10.56171/ojn.1225833

Abstract

Maddenin katı hali ile sıvı hali arasında bulunan sıvı kristaller ilginç moleküler yapılara sahip malzemelerdir. Hem katı kristallerin özelliklerini hem de sıvıların özelliklerini gösteren moleküler malzemelerdir. Fiziksel özellikleri parçacık boyutuna bağlı olarak değişen, boyutları nanometre düzeyinde olan malzemeler nanoparçacıklardır. Nanopartiküller boyutlarına ve yapısal şekillerine bağlı olarak birçok farklı tipte üretilebilir. Sıvı kristaller ve nanoparçacıkları üç farklı özellikteki çözücülerde birleştirerek floresans grafikleri elde ettik. Bu çalışmada kullandığımız sıvı kristaller 4-Pentilfenil 4-Metoksibenzoat (4PP4MetoxB), 4-Pentilfenil 4-Pentilbenzot (4PP4PentB) ve 4-Pentilfenil 4-(Oktiloksi)Benzoattır (4PP4OktoksB). Kullandığımız diğer malzemeler ZnS, CdSe ve CdS nanoparçacıklarıdır. Bu sıvı kristalleri ve nanopartikülleri solventlerde birleştirerek yeni malzemeler yarattık. Yeni oluşan malzemelerdeki sıvı kristaller ve nanoparçacıkların çözücüler içinde etkileşime girip girmediğini ve sıvı kristallerin floresans grafiklerine göre floresans grafiklerinin nasıl değiştiğini inceledik.

References

  • J. Beeckman, “Liquid-crystal photonic applications,” Optical Engineering, vol. 50, no. 8, p. 081202, 2011, doi: 10.1117/1.3565046.
  • T. Ikeda, “Photomodulation of liquid crystal orientations for photonic applications,” Journal of Materials Chemistry, vol. 13, no. 9, pp. 2037–2057, 2003, doi: 10.1039/b306216n.
  • H. Kawamoto, “The History of Liquid-Crystal Displays,” vol. 90, no. 4, 2006.
  • S. J. Woltman, G. D. Jay, and G. P. Crawford, “Liquid-crystal materials find a new order in biomedical applications,” Nature Materials, vol. 6, no. 12, pp. 929–938, 2007, doi: 10.1038/nmat2010.
  • J. P. F. Lagerwall and G. Scalia, “A new era for liquid crystal research: Applications of liquid crystals in soft matter nano-, bio- and microtechnology,” Current Applied Physics, vol. 12, no. 6, pp. 1387–1412, 2012, doi: 10.1016/j.cap.2012.03.019.
  • C. Noël and P. Navard, “Liquid crystal polymers,” Progress in Polymer Science, vol. 16, no. 1, pp. 55–110, Jan. 1991, doi: 10.1016/0079-6700(91)90007-8.
  • I. I. Smalyukh, “Liquid Crystal Colloids,” Annual Review of Condensed Matter Physics, vol. 9, no. November 2017, pp. 207–226, 2018, doi: 10.1146/annurev-conmatphys-033117-054102.
  • M. Bangal et al., “Semiconductor nanoparticles,” Hyperfine Interactions, vol. 160, no. 1–4, pp. 81–94, 2005, doi: 10.1007/s10751-005-9151-y.
  • K. J. Si, Y. Chen, Q. Shi, and W. Cheng, “Nanoparticle Superlattices: The Roles of Soft Ligands,” Advanced Science, vol. 5, no. 1, 2018, doi: 10.1002/advs.201700179.
  • J. R. Lakowicz, I. Gryczynski, Z. Gryczynski, and C. J. Murphy, “Luminescence spectral properties of CdS nanoparticles,” Journal of Physical Chemistry B, vol. 103, no. 36, pp. 7613–7620, 1999, doi: 10.1021/jp991469n.
  • T. Hegmann, H. Qi, and V. M. Marx, “Nanoparticles in liquid crystals: Synthesis, self-assembly, defect formation and potential applications,” Journal of Inorganic and Organometallic Polymers and Materials, vol. 17, no. 3, pp. 483–508, 2007, doi: 10.1007/s10904-007-9140-5.
  • R. K. Shukla, Y. G. Galyametdinov, R. R. Shamilov, and W. Haase, “Effect of CdSe quantum dots doping on the switching time, localised electric field and dielectric parameters of ferroelectric liquid crystal,” Liquid Crystals, vol. 41, no. 12, pp. 1889–1896, 2014, doi: 10.1080/02678292.2014.959571.
  • V. Kumar, A. Kumar, A. M. Biradar, G. B. Reddy, D. Sachdev, and R. Pasricha, “Enhancement of electro-optical response of ferroelectric liquid crystal: the role of graphene quantum dots,” Liquid Crystals, vol. 41, no. 12, pp. 1719–1725, 2014, doi: 10.1080/02678292.2014.949888.
  • A. Anczykowska, S. Bartkiewicz, M. Nyk, and J. Myśliwiec, “Enhanced photorefractive effect in liquid crystal structures co-doped with semiconductor quantum dots and metallic nanoparticles,” Applied Physics Letters, vol. 99, no. 19, pp. 1–4, 2011, doi: 10.1063/1.3659485.
  • L. J. Martínez-Miranda, K. M. Traister, I. Meĺndez-Rodríguez, and L. Salamanca-Riba, “Liquid crystal-ZnO nanoparticle photovoltaics: Role of nanoparticles in ordering the liquid crystal,” Applied Physics Letters, vol. 97, no. 22, 2010, doi: 10.1063/1.3511736.
  • T. Zhang, C. Zhong, and J. Xu, “CdS-Nanoparticle-doped liquid crystal displays showing low threshold voltage,” Japanese Journal of Applied Physics, vol. 48, no. 5, pp. 0550021–0550026, 2009, doi: 10.1143/JJAP.48.055002.
  • J. Tauc and A. Menth, “States in the gap,” Journal of Non-Crystalline Solids, vol. 8–10, no. C, pp. 569–585, 1972, doi: 10.1016/0022-3093(72)90194-9.
  • J. C. Tauc, “Semiconductor Amorphous and Liquid,” p. 195, 1974.
  • O. Baytar, O. Sahin, H. Kilicvuran, and S. Horoz, “Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 6, pp. 4564–4568, 2018, doi: 10.1007/s10854-017-8406-0.
  • S. Horoz et al., “CdSe quantum dots synthesized by laser ablation in water and their photovoltaic applications,” Applied Physics Letters, vol. 101, no. 22, pp. 1–5, 2012, doi: 10.1063/1.4768706.
  • O. Sahin and S. Horoz, “Synthesis of Ni:ZnS quantum dots and investigation of their properties,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 19, pp. 16775–16781, 2018, doi: 10.1007/s10854-018-9771-z.
  • OriginPro19b (Version 9.5), OriginLab Corporation, Northampton, MA (USA), 2022.
  • SpectraGryph 1.2, Spectroscopy Software, https://www.effemm2.de/spectragryph/down.html.
  • Y. Li, L. Ma, X. Zhang, A. G. Joly, Z. Liu, and W. Chen, “Synthesis and optical properties of sulfide nanoparticles prepared in dimethylsulfoxide,” Journal of Nanoscience and Nanotechnology, vol. 8, no. 11, pp. 5646–5651, Nov. 2008, doi: 10.1166/JNN.2008.474.
  • F. Rodríguez‐mas, J. C. Ferrer, J. L. Alonso, S. F. de Ávila, and D. Valiente, “Reduced Graphene Oxide Inserted into PEDOT:PSS Layer to Enhance the Electrical Behaviour of Light-Emitting Diodes,” Nanomaterials 2021, Vol. 11, Page 645, vol. 11, no. 3, p. 645, Mar. 2021, doi: 10.3390/NANO11030645.

The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals

Year 2023, Volume: 8 Issue: 1, 50 - 64, 30.06.2023
https://doi.org/10.56171/ojn.1225833

Abstract

Liquid crystals, which are between the solid state of matter and the liquid state, are materials with interesting molecular structures. They are molecular materials that show both the properties of solid crystals and the properties of liquids. Materials whose physical properties change depending on the particle size, whose dimensions are at the nanometer level, are nanoparticles. Nanoparticles can be produced in many different types, depending on their size and structural shape. We obtained fluorescence graphs by combining liquid crystals and nanoparticles in solvents with three different characteristics. The liquid crystals we used in this study are 4-Pentylphenyl 4-Methoxybenzoate (4PP4MetoxB), 4-Pentylphenyl 4-Pentylbenzote (4PP4PentB), and 4-Pentylphenyl 4-(Octyloxy)Benzoate (4PP4OctoxB). Other materials we use are ZnS, CdSe, and CdS nanoparticles. We created new materials by combining these liquid crystals and nanoparticles in solvents. We examined whether the liquid crystals and nanoparticles in the newly formed materials interact in solvents and how the fluorescence graphs change according to the fluorescence graphs of liquid crystals.

References

  • J. Beeckman, “Liquid-crystal photonic applications,” Optical Engineering, vol. 50, no. 8, p. 081202, 2011, doi: 10.1117/1.3565046.
  • T. Ikeda, “Photomodulation of liquid crystal orientations for photonic applications,” Journal of Materials Chemistry, vol. 13, no. 9, pp. 2037–2057, 2003, doi: 10.1039/b306216n.
  • H. Kawamoto, “The History of Liquid-Crystal Displays,” vol. 90, no. 4, 2006.
  • S. J. Woltman, G. D. Jay, and G. P. Crawford, “Liquid-crystal materials find a new order in biomedical applications,” Nature Materials, vol. 6, no. 12, pp. 929–938, 2007, doi: 10.1038/nmat2010.
  • J. P. F. Lagerwall and G. Scalia, “A new era for liquid crystal research: Applications of liquid crystals in soft matter nano-, bio- and microtechnology,” Current Applied Physics, vol. 12, no. 6, pp. 1387–1412, 2012, doi: 10.1016/j.cap.2012.03.019.
  • C. Noël and P. Navard, “Liquid crystal polymers,” Progress in Polymer Science, vol. 16, no. 1, pp. 55–110, Jan. 1991, doi: 10.1016/0079-6700(91)90007-8.
  • I. I. Smalyukh, “Liquid Crystal Colloids,” Annual Review of Condensed Matter Physics, vol. 9, no. November 2017, pp. 207–226, 2018, doi: 10.1146/annurev-conmatphys-033117-054102.
  • M. Bangal et al., “Semiconductor nanoparticles,” Hyperfine Interactions, vol. 160, no. 1–4, pp. 81–94, 2005, doi: 10.1007/s10751-005-9151-y.
  • K. J. Si, Y. Chen, Q. Shi, and W. Cheng, “Nanoparticle Superlattices: The Roles of Soft Ligands,” Advanced Science, vol. 5, no. 1, 2018, doi: 10.1002/advs.201700179.
  • J. R. Lakowicz, I. Gryczynski, Z. Gryczynski, and C. J. Murphy, “Luminescence spectral properties of CdS nanoparticles,” Journal of Physical Chemistry B, vol. 103, no. 36, pp. 7613–7620, 1999, doi: 10.1021/jp991469n.
  • T. Hegmann, H. Qi, and V. M. Marx, “Nanoparticles in liquid crystals: Synthesis, self-assembly, defect formation and potential applications,” Journal of Inorganic and Organometallic Polymers and Materials, vol. 17, no. 3, pp. 483–508, 2007, doi: 10.1007/s10904-007-9140-5.
  • R. K. Shukla, Y. G. Galyametdinov, R. R. Shamilov, and W. Haase, “Effect of CdSe quantum dots doping on the switching time, localised electric field and dielectric parameters of ferroelectric liquid crystal,” Liquid Crystals, vol. 41, no. 12, pp. 1889–1896, 2014, doi: 10.1080/02678292.2014.959571.
  • V. Kumar, A. Kumar, A. M. Biradar, G. B. Reddy, D. Sachdev, and R. Pasricha, “Enhancement of electro-optical response of ferroelectric liquid crystal: the role of graphene quantum dots,” Liquid Crystals, vol. 41, no. 12, pp. 1719–1725, 2014, doi: 10.1080/02678292.2014.949888.
  • A. Anczykowska, S. Bartkiewicz, M. Nyk, and J. Myśliwiec, “Enhanced photorefractive effect in liquid crystal structures co-doped with semiconductor quantum dots and metallic nanoparticles,” Applied Physics Letters, vol. 99, no. 19, pp. 1–4, 2011, doi: 10.1063/1.3659485.
  • L. J. Martínez-Miranda, K. M. Traister, I. Meĺndez-Rodríguez, and L. Salamanca-Riba, “Liquid crystal-ZnO nanoparticle photovoltaics: Role of nanoparticles in ordering the liquid crystal,” Applied Physics Letters, vol. 97, no. 22, 2010, doi: 10.1063/1.3511736.
  • T. Zhang, C. Zhong, and J. Xu, “CdS-Nanoparticle-doped liquid crystal displays showing low threshold voltage,” Japanese Journal of Applied Physics, vol. 48, no. 5, pp. 0550021–0550026, 2009, doi: 10.1143/JJAP.48.055002.
  • J. Tauc and A. Menth, “States in the gap,” Journal of Non-Crystalline Solids, vol. 8–10, no. C, pp. 569–585, 1972, doi: 10.1016/0022-3093(72)90194-9.
  • J. C. Tauc, “Semiconductor Amorphous and Liquid,” p. 195, 1974.
  • O. Baytar, O. Sahin, H. Kilicvuran, and S. Horoz, “Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 6, pp. 4564–4568, 2018, doi: 10.1007/s10854-017-8406-0.
  • S. Horoz et al., “CdSe quantum dots synthesized by laser ablation in water and their photovoltaic applications,” Applied Physics Letters, vol. 101, no. 22, pp. 1–5, 2012, doi: 10.1063/1.4768706.
  • O. Sahin and S. Horoz, “Synthesis of Ni:ZnS quantum dots and investigation of their properties,” Journal of Materials Science: Materials in Electronics, vol. 29, no. 19, pp. 16775–16781, 2018, doi: 10.1007/s10854-018-9771-z.
  • OriginPro19b (Version 9.5), OriginLab Corporation, Northampton, MA (USA), 2022.
  • SpectraGryph 1.2, Spectroscopy Software, https://www.effemm2.de/spectragryph/down.html.
  • Y. Li, L. Ma, X. Zhang, A. G. Joly, Z. Liu, and W. Chen, “Synthesis and optical properties of sulfide nanoparticles prepared in dimethylsulfoxide,” Journal of Nanoscience and Nanotechnology, vol. 8, no. 11, pp. 5646–5651, Nov. 2008, doi: 10.1166/JNN.2008.474.
  • F. Rodríguez‐mas, J. C. Ferrer, J. L. Alonso, S. F. de Ávila, and D. Valiente, “Reduced Graphene Oxide Inserted into PEDOT:PSS Layer to Enhance the Electrical Behaviour of Light-Emitting Diodes,” Nanomaterials 2021, Vol. 11, Page 645, vol. 11, no. 3, p. 645, Mar. 2021, doi: 10.3390/NANO11030645.
There are 25 citations in total.

Details

Primary Language English
Journal Section Research Article
Authors

Yunus Emre Kara 0000-0002-8412-6633

Yadigar Gülseven Sıdır 0000-0002-5329-2815

Sabit Horoz 0000-0002-3238-8789

Early Pub Date August 8, 2022
Publication Date June 30, 2023
Submission Date December 29, 2022
Published in Issue Year 2023 Volume: 8 Issue: 1

Cite

APA Kara, Y. E., Gülseven Sıdır, Y., & Horoz, S. (2023). The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. Open Journal of Nano, 8(1), 50-64. https://doi.org/10.56171/ojn.1225833
AMA Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. June 2023;8(1):50-64. doi:10.56171/ojn.1225833
Chicago Kara, Yunus Emre, Yadigar Gülseven Sıdır, and Sabit Horoz. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano 8, no. 1 (June 2023): 50-64. https://doi.org/10.56171/ojn.1225833.
EndNote Kara YE, Gülseven Sıdır Y, Horoz S (June 1, 2023) The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. Open Journal of Nano 8 1 50–64.
IEEE Y. E. Kara, Y. Gülseven Sıdır, and S. Horoz, “The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals”, OJN, vol. 8, no. 1, pp. 50–64, 2023, doi: 10.56171/ojn.1225833.
ISNAD Kara, Yunus Emre et al. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano 8/1 (June 2023), 50-64. https://doi.org/10.56171/ojn.1225833.
JAMA Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. 2023;8:50–64.
MLA Kara, Yunus Emre et al. “The Study on Determination Interactions Between Liquid Crystals and Nanoparticle: Fluorescence Spectra of Nanoparticle-Doped Liquid Crystals”. Open Journal of Nano, vol. 8, no. 1, 2023, pp. 50-64, doi:10.56171/ojn.1225833.
Vancouver Kara YE, Gülseven Sıdır Y, Horoz S. The study on determination interactions between liquid crystals and nanoparticle: Fluorescence spectra of nanoparticle-doped liquid crystals. OJN. 2023;8(1):50-64.

23830

The Open Journal of Nano(OJN) deals with information related to (but not limited to) physical, chemical and biological phenomena and processes ranging from molecular to microscale structures.

All publications in The Open Journal of Nano are licensed under the Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license.