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Electrocatalytic oxidation of formic acid using Pt nanocatalyst supported on PVF-PANI composite

Year 2020, Volume: 10 Issue: 1, 1 - 10, 30.06.2020

Abstract

Facile synthesis of Pt@PVF-PANI catalyst for electrooxidation of formic acid was described. Influence of experimental conditions on the performance of the catalyst system was studied via cyclic voltammetry of formic acid solution in acidic medium. The catalyst prepared under optimum conditions was physically characterized using Scanning Electron Microscopy and elemental mapping. Electrochemical characterization was performed by electrochemical impedance spectroscopy.

Supporting Institution

Scientific Research Projects Coordination Department of Ordu University (ODUBAP)

Project Number

AP-1701

References

  • Akgül E, Gülce A & Gülce H (2012). Electrocatalytic oxidation of methanol on poly(vinylferrocene) modified Pt electrode. Journal of Electroanalytical Chemistry 668: 73–82. Çelebi M S & Yılmaz A N (2018). PVF - PPy Composite as Support Material for Facile Synthesis of Pt @ PVF - PPy Catalyst and Its Electrocatalytic Activity Towards Formic Acid Oxidation. Journal of New Materials for Electrochemical Systems 162: 157–162. Çelebi M S, Pekmez K, Özyörük H & Yıldız A (2008). Electrochemical synthesis of Pd particles on poly(vinylferrocenium). Catalysis Communications 9(13): 2175–2178. Çelebi M S (2016) in Advanced Electrode Materials, Edited by A. Tiwari, F. Kuralay, and L. Uzun, Wiley-VCH, Weinheim, pp. 397–434. Çelebi M S, Pekmez K, Özyörük H & Yıldız A (2008). Preparation and physical/electrochemical characterization of Pt/poly(vinylferrocenium) electrocatalyst for methanol oxidation. Journal of Power Sources 183(1): 8–13. Hsieh C T, Hsiao H T, Tzou D Y, Yu P Y, Chen P Y & Jang B S (2015). Electro-oxidation of methanol and formic acid on platinum nanoparticles with different oxidation levels. Materials Chemistry and Physics, 149: 359–367. Kavanoz M & Pekmez N Ö (2012). Poly(vinylferrocenium) perchlorate-polyaniline composite film-coated electrode for amperometric determination of hydroquinone. Journal of Solid State Electrochemistry 16(3): 1175–1186. Kuralay F, Erdem A, Abacı S & Özyörük H (2013). Electrochemical characterization of redox polymer modified electrode developed for monitoring of adenine. Colloids and Surfaces B: Biointerfaces, 105: 1–6. Lemos H G, Santos S F & Venancio E C (2015). Polyaniline-Pt and polypyrrole-Pt nanocomposites: Effect of supporting type and morphology on the nanoparticles size and distribution. Synthetic Metals, 203: 22–30. Lin H, Yang J, Liu J, Huang Y, Xiao J & Zhang X (2013). Properties of Pd nanoparticles-embedded polyaniline multilayer film and its electrocatalytic activity for hydrazine oxidation. Electrochimica Acta, 90: 382–392. Nagashree K L & Ahmed M F (2008). Electrocatalytic oxidation of methanol on Pt modified polyaniline in alkaline medium. Synthetic Metals, 158(15): 610–616. Ong B C, Kamarudin S K & Basri S (2017). Direct liquid fuel cells: A review. International Journal of Hydrogen Energy 42(15): 10142–10157. Pekmez K & Sönmez Çelebi M (2017). Electrooxidation of Formic Acid Using Pt Nanoparticles Supported on Conducting Poly(Vinylferrocene) Polymer Support. Hacettepe Journal of Biology and Chemistry, 3(45): 351–358. Ramírez M R A, del Valle M A, Armijo F, Díaz F R, Angélica Pardo M & Ortega E. (2017). Enhancement of electrodes modified by electrodeposited PEDOT-nanowires with dispersed Pt nanoparticles for formic acid electro-oxidation. Journal of Applied Polymer Science 134(16): 1–7. Sharma S & Pollet B G (2012). Support materials for PEMFC and DMFC electrocatalysts - A review. Journal of Power Sources, 208: 96–119. Tian W, Mao X, Brown P, Rutledge G C & Hatton T A (2015). Electrochemically Nanostructured Polyvinylferrocene/Polypyrrole Hybrids with Synergy for Energy Storage. Advanced Functional Materials, 25(30): 4803–4813. Zhu Z Z, Wang Z & Li H L (2008). Functional multi-walled carbon nanotube/polyaniline composite films as supports of platinum for formic acid electrooxidation. Applied Surface Science 254(10): 2934–2940.

Electrocatalytic oxidation of formic acid using Pt nanocatalyst supported on PVF-PANI composite

Year 2020, Volume: 10 Issue: 1, 1 - 10, 30.06.2020

Abstract

Facile synthesis of Pt@PVF-PANI catalyst for electrooxidation of formic acid was described. Influence of experimental conditions on the performance of the catalyst system was studied via cyclic voltammetry of formic acid solution in acidic medium. The catalyst prepared under optimum conditions was physically characterized using Scanning Electron Microscopy and elemental mapping. Electrochemical characterization was performed by electrochemical impedance spectroscopy.

Project Number

AP-1701

References

  • Akgül E, Gülce A & Gülce H (2012). Electrocatalytic oxidation of methanol on poly(vinylferrocene) modified Pt electrode. Journal of Electroanalytical Chemistry 668: 73–82. Çelebi M S & Yılmaz A N (2018). PVF - PPy Composite as Support Material for Facile Synthesis of Pt @ PVF - PPy Catalyst and Its Electrocatalytic Activity Towards Formic Acid Oxidation. Journal of New Materials for Electrochemical Systems 162: 157–162. Çelebi M S, Pekmez K, Özyörük H & Yıldız A (2008). Electrochemical synthesis of Pd particles on poly(vinylferrocenium). Catalysis Communications 9(13): 2175–2178. Çelebi M S (2016) in Advanced Electrode Materials, Edited by A. Tiwari, F. Kuralay, and L. Uzun, Wiley-VCH, Weinheim, pp. 397–434. Çelebi M S, Pekmez K, Özyörük H & Yıldız A (2008). Preparation and physical/electrochemical characterization of Pt/poly(vinylferrocenium) electrocatalyst for methanol oxidation. Journal of Power Sources 183(1): 8–13. Hsieh C T, Hsiao H T, Tzou D Y, Yu P Y, Chen P Y & Jang B S (2015). Electro-oxidation of methanol and formic acid on platinum nanoparticles with different oxidation levels. Materials Chemistry and Physics, 149: 359–367. Kavanoz M & Pekmez N Ö (2012). Poly(vinylferrocenium) perchlorate-polyaniline composite film-coated electrode for amperometric determination of hydroquinone. Journal of Solid State Electrochemistry 16(3): 1175–1186. Kuralay F, Erdem A, Abacı S & Özyörük H (2013). Electrochemical characterization of redox polymer modified electrode developed for monitoring of adenine. Colloids and Surfaces B: Biointerfaces, 105: 1–6. Lemos H G, Santos S F & Venancio E C (2015). Polyaniline-Pt and polypyrrole-Pt nanocomposites: Effect of supporting type and morphology on the nanoparticles size and distribution. Synthetic Metals, 203: 22–30. Lin H, Yang J, Liu J, Huang Y, Xiao J & Zhang X (2013). Properties of Pd nanoparticles-embedded polyaniline multilayer film and its electrocatalytic activity for hydrazine oxidation. Electrochimica Acta, 90: 382–392. Nagashree K L & Ahmed M F (2008). Electrocatalytic oxidation of methanol on Pt modified polyaniline in alkaline medium. Synthetic Metals, 158(15): 610–616. Ong B C, Kamarudin S K & Basri S (2017). Direct liquid fuel cells: A review. International Journal of Hydrogen Energy 42(15): 10142–10157. Pekmez K & Sönmez Çelebi M (2017). Electrooxidation of Formic Acid Using Pt Nanoparticles Supported on Conducting Poly(Vinylferrocene) Polymer Support. Hacettepe Journal of Biology and Chemistry, 3(45): 351–358. Ramírez M R A, del Valle M A, Armijo F, Díaz F R, Angélica Pardo M & Ortega E. (2017). Enhancement of electrodes modified by electrodeposited PEDOT-nanowires with dispersed Pt nanoparticles for formic acid electro-oxidation. Journal of Applied Polymer Science 134(16): 1–7. Sharma S & Pollet B G (2012). Support materials for PEMFC and DMFC electrocatalysts - A review. Journal of Power Sources, 208: 96–119. Tian W, Mao X, Brown P, Rutledge G C & Hatton T A (2015). Electrochemically Nanostructured Polyvinylferrocene/Polypyrrole Hybrids with Synergy for Energy Storage. Advanced Functional Materials, 25(30): 4803–4813. Zhu Z Z, Wang Z & Li H L (2008). Functional multi-walled carbon nanotube/polyaniline composite films as supports of platinum for formic acid electrooxidation. Applied Surface Science 254(10): 2934–2940.
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Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Mutlu Sönmez Çelebi 0000-0002-8816-6763

Songül Kırlak Kara This is me 0000-0001-5432-1721

Nesrin Çoskun Kurt This is me 0000-0003-4889-3920

Project Number AP-1701
Publication Date June 30, 2020
Submission Date June 20, 2020
Published in Issue Year 2020 Volume: 10 Issue: 1

Cite

APA Sönmez Çelebi, M., Kırlak Kara, S., & Çoskun Kurt, N. (2020). Electrocatalytic oxidation of formic acid using Pt nanocatalyst supported on PVF-PANI composite. Ordu Üniversitesi Bilim Ve Teknoloji Dergisi, 10(1), 1-10.