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Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation

Year 2021, Volume 11, Issue 1, 53 - 63, 30.06.2021

Abstract

Facile synthesis of Pt@PTH catalyst on pencil graphite electrode for electrooxidation of methanol was described. Influence of experimental conditions on the performance of the catalyst system was studied by recording cyclic voltammograms of methanol solution containing H2SO4 as the supporting electrolyte. The catalyst prepared under optimum conditions was physically characterized using Scanning Electron Microscopy, Energy Dispersive X-Ray Dispersion and Elemental Mapping methods. Electrochemical characterization was performed by cyclic voltammetry in H2SO4 solution.

References

  • Ferreira V, Tenreiro A & Abrantes L M (2006). Electrochemical, microgravimetric and AFM studies of polythionine films Application as new support for the immobilisation of nucleotides. Sensors and Actuators B 119: 632–641
  • Li X & Faghri A (2013). Review and advances of direct methanol fuel cells (DMFCs) part I: Design, fabrication, and testing with high concentration methanol solutions. J. Power Sources 226: 223–240
  • Lin M, Hu X, Ma Z & Chen L (2012) Functionalized polypyrrole nanotube arrays as electrochemical biosensor for the determination of copper ions. Analytica Chimica Acta 746: 63-69
  • Liu H, Wang G, Chen D, Zhang W, Li C & Fang B (2008). Fabrication of polythionine/NPAu/MWNTs modified electrode for simultaneous determination of adenine and guanine in DNA. Sensors and Actuators B 128: 414-421
  • Liu C, Huang J & Wang L (2018). Electrochemical synthesis of a nanocomposite consisting of carboxy-modified multi-walled carbon nanotubes, polythionine and platinum nanoparticles for simultaneous voltammetric determination of myricetin and rutin. Microchimica Acta 185: 414
  • Mondal S & Malik S (2016). Easy synthesis approach of Pt-nanoparticles on polyaniline surface: an efficient electro-catalyst for methanol oxidation reaction. Journal of Power Sources 328: 271-279
  • Ong B C, Kamarudin S K & Basri S (2017). Direct liquid fuel cells: A review. Int. J. Hydrogen Energy 42: 10142–10157
  • Selvaraj V & Alagar M (2007). Pt and Pt–Ru nanoparticles decorated polypyrrole/multiwalled carbon nanotubes and their catalytic activity towards methanol oxidation. Electrochem. Commun 9: 1145-1153
  • Sönmez Çelebi M, Pekmez K, Özyörük H & Yıldız A (2008). Preparation and physical/electrochemical characterization of Pt/poly(vinylferrocenium) electrocatalyst for methanol oxidation. J. Power Sources 183: 8–13
  • Sönmez Çelebi M (2016) Energy Applications: Fuel Cells, In Advanced Electrode Materials, Edited by A. Tiwari, F. Kuralay, and L. Uzun, Wiley-VCH, Weinheim, pp. 397–434
  • Sönmez Çelebi M & Pekmez K (2017). Electrooxidation of Formic Acid Using Pt Nanoparticles Supported on Conducting Poly(Vinylferrocene) Polymer Support. Hacettepe J. Biol. & Chem. 45: 351–358
  • Sönmez Çelebi M, Öztürk K & Dumangöz M (2021). Electrochemical Synthesis of Cauliflower-Like PtPd@PVF Nanocatalyst for Electrooxidation of Methanol. Hacettepe J. Biol. & Chem 49(1): 79-91
  • Yang R, Ruan C, Dai W, Deng J & Kong J (1999). Electropolymerization of thionine in neutral aqueous media and H2O2 biosensor based on poly(thionine). Electrochimica Acta 44: 1585-1596
  • Zhou W, Du Y, Ren F, Wang C, Xu J & Yang P (2010). High efficient electrocatalytic oxidation of methanol on Pt/polyindoles composite catalysts. Int. J. Hydrogen Energy 35: 3270-3279

İletken poli(tiyonin) filminin Pt partikülleri için destek malzemesi olarak kullanılması: Metanol yükseltgenmesine karşı elektrokatalitik aktivite

Year 2021, Volume 11, Issue 1, 53 - 63, 30.06.2021

Abstract

Bu çalışmada kalem grafit elektrot üzerinde Pt@PTH katalizör sisteminin sentezi ve metanolün elektroyükseltgenmesi için kullanımı anlatılmaktadır. Deneysel koşulların katalizör sisteminin performansı üzerine olan etkisi, destek elektrolit olarak H2SO4 içeren metanol çözeltisinin dönüşümlü voltamogramları kaydedilerek saptanmıştır. Optimum koşullarda hazırlanan katalizörün fiziksel karakterizasyonu Taramalı Elektron Mikroskobu, Enerji Dağılımlı X-Işınları Spektroskopisi ve Elementel Haritalama ile gerçekleştirilmiştir. Elektrokimyasal karakterizasyon için ise H2SO4 çözeltisinde dönüşümlü voltametri yöntemi kullanılmıştır.

References

  • Ferreira V, Tenreiro A & Abrantes L M (2006). Electrochemical, microgravimetric and AFM studies of polythionine films Application as new support for the immobilisation of nucleotides. Sensors and Actuators B 119: 632–641
  • Li X & Faghri A (2013). Review and advances of direct methanol fuel cells (DMFCs) part I: Design, fabrication, and testing with high concentration methanol solutions. J. Power Sources 226: 223–240
  • Lin M, Hu X, Ma Z & Chen L (2012) Functionalized polypyrrole nanotube arrays as electrochemical biosensor for the determination of copper ions. Analytica Chimica Acta 746: 63-69
  • Liu H, Wang G, Chen D, Zhang W, Li C & Fang B (2008). Fabrication of polythionine/NPAu/MWNTs modified electrode for simultaneous determination of adenine and guanine in DNA. Sensors and Actuators B 128: 414-421
  • Liu C, Huang J & Wang L (2018). Electrochemical synthesis of a nanocomposite consisting of carboxy-modified multi-walled carbon nanotubes, polythionine and platinum nanoparticles for simultaneous voltammetric determination of myricetin and rutin. Microchimica Acta 185: 414
  • Mondal S & Malik S (2016). Easy synthesis approach of Pt-nanoparticles on polyaniline surface: an efficient electro-catalyst for methanol oxidation reaction. Journal of Power Sources 328: 271-279
  • Ong B C, Kamarudin S K & Basri S (2017). Direct liquid fuel cells: A review. Int. J. Hydrogen Energy 42: 10142–10157
  • Selvaraj V & Alagar M (2007). Pt and Pt–Ru nanoparticles decorated polypyrrole/multiwalled carbon nanotubes and their catalytic activity towards methanol oxidation. Electrochem. Commun 9: 1145-1153
  • Sönmez Çelebi M, Pekmez K, Özyörük H & Yıldız A (2008). Preparation and physical/electrochemical characterization of Pt/poly(vinylferrocenium) electrocatalyst for methanol oxidation. J. Power Sources 183: 8–13
  • Sönmez Çelebi M (2016) Energy Applications: Fuel Cells, In Advanced Electrode Materials, Edited by A. Tiwari, F. Kuralay, and L. Uzun, Wiley-VCH, Weinheim, pp. 397–434
  • Sönmez Çelebi M & Pekmez K (2017). Electrooxidation of Formic Acid Using Pt Nanoparticles Supported on Conducting Poly(Vinylferrocene) Polymer Support. Hacettepe J. Biol. & Chem. 45: 351–358
  • Sönmez Çelebi M, Öztürk K & Dumangöz M (2021). Electrochemical Synthesis of Cauliflower-Like PtPd@PVF Nanocatalyst for Electrooxidation of Methanol. Hacettepe J. Biol. & Chem 49(1): 79-91
  • Yang R, Ruan C, Dai W, Deng J & Kong J (1999). Electropolymerization of thionine in neutral aqueous media and H2O2 biosensor based on poly(thionine). Electrochimica Acta 44: 1585-1596
  • Zhou W, Du Y, Ren F, Wang C, Xu J & Yang P (2010). High efficient electrocatalytic oxidation of methanol on Pt/polyindoles composite catalysts. Int. J. Hydrogen Energy 35: 3270-3279

Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Nesrin ÇOSKUN KURT
ORDU ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ, ANALİTİK KİMYA ANABİLİM DALI
0000-0003-4889-3920
Türkiye


Mutlu SÖNMEZ ÇELEBİ (Primary Author)
ORDU ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ, ANALİTİK KİMYA ANABİLİM DALI
0000-0002-8816-6763
Türkiye

Supporting Institution Scientific Research Projects Coordination Department of Ordu University (ODÜBAP)
Project Number TF-1615
Publication Date June 30, 2021
Published in Issue Year 2021, Volume 11, Issue 1

Cite

Bibtex @research article { ordubtd943466, journal = {Ordu Üniversitesi Bilim ve Teknoloji Dergisi}, issn = {2146-6440}, eissn = {2146-6459}, address = {}, publisher = {Ordu University}, year = {2021}, volume = {11}, pages = {53 - 63}, doi = {}, title = {Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation}, key = {cite}, author = {Çoskun Kurt, Nesrin and Sönmez Çelebi, Mutlu} }
APA Çoskun Kurt, N. & Sönmez Çelebi, M. (2021). Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation . Ordu Üniversitesi Bilim ve Teknoloji Dergisi , 11 (1) , 53-63 . Retrieved from https://dergipark.org.tr/en/pub/ordubtd/issue/63218/943466
MLA Çoskun Kurt, N. , Sönmez Çelebi, M. "Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation" . Ordu Üniversitesi Bilim ve Teknoloji Dergisi 11 (2021 ): 53-63 <https://dergipark.org.tr/en/pub/ordubtd/issue/63218/943466>
Chicago Çoskun Kurt, N. , Sönmez Çelebi, M. "Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation". Ordu Üniversitesi Bilim ve Teknoloji Dergisi 11 (2021 ): 53-63
RIS TY - JOUR T1 - Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation AU - Nesrin Çoskun Kurt , Mutlu Sönmez Çelebi Y1 - 2021 PY - 2021 N1 - DO - T2 - Ordu Üniversitesi Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 53 EP - 63 VL - 11 IS - 1 SN - 2146-6440-2146-6459 M3 - UR - Y2 - 2021 ER -
EndNote %0 Ordu University Journal of Science and Tecnology Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation %A Nesrin Çoskun Kurt , Mutlu Sönmez Çelebi %T Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation %D 2021 %J Ordu Üniversitesi Bilim ve Teknoloji Dergisi %P 2146-6440-2146-6459 %V 11 %N 1 %R %U
ISNAD Çoskun Kurt, Nesrin , Sönmez Çelebi, Mutlu . "Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation". Ordu Üniversitesi Bilim ve Teknoloji Dergisi 11 / 1 (June 2021): 53-63 .
AMA Çoskun Kurt N. , Sönmez Çelebi M. Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation. Ordu Üniversitesi Bilim ve Teknoloji Dergisi. 2021; 11(1): 53-63.
Vancouver Çoskun Kurt N. , Sönmez Çelebi M. Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation. Ordu Üniversitesi Bilim ve Teknoloji Dergisi. 2021; 11(1): 53-63.
IEEE N. Çoskun Kurt and M. Sönmez Çelebi , "Conducting poly(thionine) film as a support material for Pt particles: Electrocatalytic activity towards methanol oxidation", Ordu Üniversitesi Bilim ve Teknoloji Dergisi, vol. 11, no. 1, pp. 53-63, Jun. 2021

DANIŞMA KURULU

Dr. Mushtaq Ahmed - University of Science & Technology- Bannu
Dr. Francesso CALABRESE - Dipartmento di Colture Arbaee, Universitate di Palermo
Dr. Hicham Zazou - University Ibn Zohr - Agadir/Morocco
Dr. Shunguan LII -  College of Horticulture South Chine Agricultural Univ.
Dr. Fouad GUENFOUD - Université de Tlemcen- Tlemcen/Algérie
Dr. Zehruni MESSAOUDI - Department arboniculture-Viticulture Ecole Nationale d Agriculture de Meknes
Dr. Khuram Ali Khan - University of Sargodha- Punjab
Dr. Zoubir DAHMANI - University of Mostaganem- Algeria
Dr. Osamu TERAI - Nagasaki Fruit Tree Experiment
Dr. Mohammed Wasim Siddiqui - Bihar Agricultural University, Sabour
Dr. Jose M. LEITAO - Universidade do Algarue
Prof. Dr. Borris KRISKA - Mendel University
Prof. Dr. Abdullah MENZEK - Atatürk Üniversitesi
Prof. Dr. Âdem ERSOY - Çukurova Üniversitesi
Prof. Dr. Adnan ERDAĞ - Adnan Menderes Üniversitesi
Prof. Dr. Ali İrfan İLBAŞ - Erciyes Üniversitesi
Prof. Dr. Aliye ALTUNDAŞ -  Gazi Üniversitesi
Prof. Dr. Ahmet CANSIZ - İstanbul Teknik Üniversitesi
Prof. Dr. Ahmet DURMUŞ - Karadeniz Teknik Üniversitesi
Prof. Dr. Ahmet KAZANKAYA - Yüzüncü Yıl Üniversitesi
Prof. Dr. Ayhan SARIOĞLUGİL - Ondokuz Mayıs Üniversitesi
Prof. Dr. Ahmet UYANIK - Ondokuz Mayıs Üniversitesi
Prof. Dr. Ahmet YARTAŞI - Çankırı Karatekin Üniversitesi
Prof. Dr. Burhan ARSLAN - Namık Kemal Üniversitesi
Prof. Dr. Celal TUNCER - Ondokuz Mayıs Üniversitesi
Prof. Dr. Cemil YAPAR - Ordu Üniversitesi
Prof. Dr. Cevdet COŞKUN - Giresun Üniversitesi
Prof. Dr. Cumhur ÇÖKMÜŞ - Ankara Üniversitesi
Prof. Dr. Dürdane KOLONKAYA - Hacettepe Üniversitesi
Prof. Dr. Ertunç GÜNDÜZ - Hacettepe Üniversitesi
Prof. Dr. Fahri YAVUZ - Atatürk Üniversitesi
Prof. Dr. Ferhan TÜMER - Atatürk Üniversitesi
Prof. Dr. Fikri BALTA - Ordu Üniversitesi
Prof.Dr.F. Ekmel TEKİNTAŞ - Adnan Menderes Üniversitesi
Prof. Dr. Gençağa PÜRÇEK - Karadeniz Teknik Üniversitesi
Prof. Dr. Halil KÜTÜK - Ondokuz Mayıs Üniversitesi
Prof. Dr. Halim ÖZDEMİR - Sakarya Üniversitesi
Prof. Dr. Halis AYGÜN - Kocaeli Üniversitesi
Prof. Dr. Hasan GÜMÜŞ - Ondokuz Mayıs Üniversitesi
Prof. Dr. Hasan SEÇEN - Atatürk Üniversitesi
Prof. Dr. İhsan ÜNVER - Karadeniz Teknik Üniversitesi
Doç. Dr. İlkay ŞİŞMAN - Sakarya Üniversitesi
Doç. Dr. İ. Yasin ERDOĞAN - Bingöl Üniversitesi
Prof. Dr. Lütfi ÖZYÜZER - İzmir Yüksek Teknolojileri Üniversitesi
Prof. Dr. Mehmet AKBAŞ - Karadeniz Teknik Üniversitesi
Prof.Dr. Mehmet Cengiz KAYACAN - Süleyman Demirel Üniversitesi
Prof. Dr. Mehmet ÇAKIROĞLU - Ondokuz Mayıs Üniversitesi
Prof. Dr. Mehmet GAVGALI - Atatürk Üniversitesi
Prof. Dr. Mehmet TÜMER - Kahramanmaraş Sütçü İmam Üniversitesi
Prof. Dr. Mehmet ÜLKER - Yüzüncü Yıl Üniversitesi
Prof. Dr. Metin HÜSEM - Karadeniz Teknik Üniversitesi
Prof. Dr. Mustafa BÜYÜKYILMAZ - Namık Kemal Üniversitesi
Prof. Dr. Mustafa ÇALIŞKAN - Gazi Üniversitesi
Prof. Dr. Ömer AKBULUT - Atatürk Üniversitesi
Prof. Dr. Ö. İrfan KÜFREVİOĞLU - Atatürk Üniversitesi
Prof. Dr. Refik KESKİN - Sakarya Üniversitesi
Prof. Dr. Rüştü HATİPOĞLU - Çukurova Üniversitesi
Prof.Dr. Sadri ŞEN - Atatürk Üniversitesi
Prof.Dr. S. Zeki BOSTAN - Ordu Üniversitesi
Prof. Dr. Sebahattin TÜZEMEN - Atatürk Üniversitesi
Prof. Dr. Sinan UYANIK - Harran Üniversitesi
Prof. Dr. Suat AKBULUT - Atatürk Üniversitesi
Prof. Dr. Şenol EREN - Ondokuz Mayıs Üniversitesi
Prof. Dr. Ş. Metin KARA - Ordu Üniversitesi
Prof. Dr. Tarık YARILGAÇ - Ordu Üniversitesi