Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study

Shahin Ahmadı; Chinenye Adaobi Igwegbe

Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study

Abstract

Environmental pollution caused by colored effluents is threatening to the world. The aim of this study is to evaluate the applicability of Zinc oxide nanoparticles (ZnO-NPs) for the removal of methylene blue (MB) from aqueous solution and also to study the applicability of the nonlinear and linear adsorption isotherm and kinetic models on the process. The effects of various operating parameters such as pH (3 - 11), ZnO-NPs dosage (0.1 – 0.4 g/L), contact time (30 - 120 min), initial MB concentration (20 – 80 mg/L) on the removal of MB were studied. The adsorption kinetic and isotherm models were examined using the linear and nonlinear regression analyses methods. The results revealed that under optimal conditions of pH 7, ZnO-NPs dosage of 0.2 g/L and contact time of 60 min at concentration of 40 mg/L, the maximum adsorption capacity (qm) of MB adsorption on ZnO NPs was 9.6. mg/g and maximum removal was 96.25 %. The MB adsorption data was found to follow the Langmuir isotherm model than the Freundlich model using the linear regression analysis method. But the values of the error functions (RMSE, SD, RSS, 𝑅𝑎𝑑𝑗2, and 𝑋𝑟𝑒𝑑2) estimated revealed that the Freundlich isotherm was more suitable for describing the adsorption process. The process of MB adsorption on ZnO-NPs was found to be governed by the pseudo-second-order model using both the linear and nonlinear adsorption models. The rate-determining step is chemisorption. In general, the results indicated that the nonlinear fitting method of the experimental data with the models provided better results. The adsorption of MB on ZnO-NPs was favorable since the intensity of adsorption (n = 9.62) lies within the range of 1-10. The monolayer adsorption capacity (qm) for ZnO-NPs with MB was 12.78 mg/g. It could be concluded from the study that ZnO-NPs can be useful for the removal of MB from its aqueous solution.

Keywords

References

[1] Kumar P.S., Fernando P.S.A., Ahmed R.T., Srinath R., Priyadharshini M., Vignesh A.M., Thanjiappan A., (2014) Effect of temperature on the adsorption of methylene blue dye onto sulfuric acid–treated orange peel, Chemical Engineering Communication 11, 1526- 1547.
[2] Royer B., Cardoso N.F., Lima E.C., Macedo T.R., Airoldi C., (2010) A useful organ functionalized layered silicate for textile dye removal, Journal of Hazardous Materials 181, 366-374.
[3] Srivastava S.N., (2008) Effects of process variables on kinetics of methylene blue sorption onto untreated guava (Psidium guajava) leaf powder: Statistical analysis, Chemical Engineering Journal 140, 609-621.
[4] Rafatullah M., Sulaiman O., Hashim R., Ahmad A., (2010) Adsorption of methylene blue on low-cost adsorbents: A review, Journal of Hazardous Materials 177, 70-78.
[5] Mulugeta M., Belisti L., (2014) Removal of methylene blue (MB) dye from aqueous solution by bioadsorption onto untreated Parthenium hystrophorous weed, Modern Chemistry Applications 2, 1-5.
[6] Qingdong Q., Sun T., Yin W., Xu Y., (2017) Rapid and efficient removal of methylene blue by freshly prepared manganese dioxide, Cogent Engineering 1, 1-10.
[7] Ahmadi S., Kord Mostafapour F., (2017) Adsorptive removal of aniline from aqueous solutions by Pistacia atlantica (Baneh) shells: isotherm and kinetic studies, Journal of Science, Technology and Environment Informatics 5, 327–335.
[8] Igwegbe C.A., Onyechi P.C., Onukwuli O.D., Nwokedi I.C., (2016) Adsorptive treatment of textile wastewater using activated carbon produced from Mucuna pruriens seed shells, World Journal of Engineering and Technology 4, 21-37.

[9] Kapdan I.K., Kargi F., (2002) Simultaneous biodegradation, and adsorption of textile dye stuff in an activated sludge unit, Process Biochemistry 37, 973-98.
[10] Ahmadi Sh., Kord Mostafapoor F., (2017) Adsorptive removal of bisphenol A from aqueous solutions by Pistacia atlantica: isotherm and kinetic studies, Pharmaceutical and Chemical Journal 4, 1–8.
[11] Igwegbe C.A., Mohmmadi L., Ahmadi S., Rahdar A., Khadkhodaiy D., Dehghani R., Rahdar S., (2019) Modeling of adsorption of Methylene blue dye on Ho-CaWO4 nanoparticles using Response surface methodology (RSM) and Artiﬁcial neural network (ANN) techniques, MethodsX 6, 1779-1797.
[12] Igwegbe C.A., Banach A.M., Ahmadi S., (2018) Adsorption of Reactive Blue 19 from aqueous environment on magnesium oxide nanoparticles: kinetic, isotherm and thermodynamic studies, Pharmaceutical and Chemical Journal 5, 111-121.
[13] Igwegbe C.A., Onyechi P.C., Onukwuli O.D., (2015) Kinetic, isotherm and thermodynamic modelling on the adsorptive removal of malachite green on Dacryodes edulis seeds, Journal of Scientific and Engineering Research 2, 23-39.
[14] Ahmadi S., Rahdar A., Rahdar S., Igwegbe C.A., (2019) Removal of Remazol Black B from aqueous solution using P-γ-Fe2O3 nanoparticles: synthesis, physical characterization, isotherm, kinetic and thermodynamic studies, Desalination and Water Treatment 152, 401–410.
[15] Ahmadi S, Mohammadi L, Igwegbe C.A., Rahdar S., Banach A.M., (2018) Application of response surface methodology in the degradation of Reactive Blue 19 using H2O2/MgO nanoparticles advanced oxidation process, International Journal of Industrial Chemistry 9(3), 241-253.
[16] Ahmadi S., Igwegbe C.A., Rahdar S., (2019) The application of thermally activated persulfate for degradation of Acid Blue 92 in aqueous solution, International Journal of Industrial Chemistry 10(3), 249–260.
[17] Han Y., Quan X., Chen S., Zhao H., Cui C., Zhao Y., (2006) Electrochemically enhanced adsorption of aniline on activated carbon fibers, Separation and Purification Technology 50, 365–372.
[18] Sarvani R., Damani E., Ahmadi Sh., (2018) Adsorption isotherm and kinetics Study: Removal of phenol using adsorption onto modified Pistacia mutica shells, Iranian Journal of Health Sciences 6, 33-42.
[19] Samadi M.T., Kashitarash E.Z., Ahangari F., Ahmadi Sh., Jafari J., (2013) Nickel removal from aqueous environments using carbon nanotubes, Water and Wastewater 24, 38–44.
[20] Karine S.C., (2001) Adsorption kinetics of dyes and yellowing inhibitors on pulp fibers, 0885-0885.
[21] Rahdar S., Igwegbe C.A., Rahdar A., Ahmadi S., (2018) Efficiency of sono-nano-catalytic process of magnesium oxide nanoparticle in removal of penicillin G from aqueous solution, Desalination and Water Treatment 106, 330–335.
[22] Hong R., Pan T., Qian J., Li H., (2006) Synthesis and surface modification of ZnO nanoparticles, Chemical Engineering Journal 119, 71-81.
[23] Ahmadi Sh, Kord Mostafapour F., Bazrafshan E., (2017) Removal of aniline and from aqueous solutions by coagulation/flocculation flotation, Chemical Science International Journal 18, 1–10.
[24] Ahmadi Sh., Kord Mostafapour F., (2017) Survey of efficiency of dissolved air flotation in removal penicillin G potassium from aqueous solutions, British Journal of Pharmaceutical and Medical Research 15, 1–11.
[25] Bazrafshan E, Ahmadi Sh., (2017) Removal COD of landfill leachate using coagulation and activated tea waste (ZnCl2) adsorption, International Journal of Innovative Science Engineering and Technology 4, 339-347.
[26] Rahdar S., Samani S., Ahmadi Sh., (2018) Efficiency of Arachis hypogaea ash in aniline adsorption from aqueous solution: a thermodynamic and kinetic study, Journal of Health Research in Community 4, 21-32.
[27] Elnasri, N.A., Elsheik, M.A., & Eltayeb M.B. (2013). Physico-chemical characterization and Freundlich isotherm studies of adsorption of Fe(II), from aqueous solution by using activated carbon prepared from Doumfruit waste. Archives of Applied Science Research, 5, 149-158.
[28] Okeola O.F., Odebunmi E.O., Ameen O.M., (2012) Comparison of sorption capacity and surface area of activated carbon prepared from Jatropha curcas fruit pericarp and seed coat, Bulletin of the Chemical Society of Ethiopia 2, 171-180.
[29] Coates J., (2010) Interpretation of Infrared Spectra. A Practical Approach. Encyclopedia of Analytical Chemistry. R.A. Meyers (ed.): John Wiley & Sons Ltd, Chichester, 10815–10837, 2010.
[30] Bonetto L.R., Ferrarini F., De Marco C., Crespo J.S., Guégan R., Giovanela M., (2015) Removal of methyl violet 2B dye from aqueous solution using a magnetic composite as an adsorbent, Journal of Water Process Engineering 6, 11-20.
[31] Ertas M., Acemioglu B., Alma M.H., Usta M., (2010). Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust, Chemical Engineering Journal 183, 421-427.
[32] Ahmadi Sh., Banach A., Kord Mostafapour F., Balarak D., (2017) Study survey of cupric oxide nanoparticles in removal efficiency of ciprofloxacin antibiotic from aqueous solution: adsorption isotherm study, Desalination and Water Treatment 89, 297–303.
[33] Nsami J.N, Mbadcam J.K., (2013) The adsorption efficiency of chemically prepared activated carbon from cola nut shells by ZnCl2 on methylene blue, Journal of Chemistry, 1-7.
[34] Das B, Mondal N.K., (2011) Calcareous soil as a new adsorbent to remove lead from aqueous solution: equilibrium, kinetic and thermodynamic study, Universal Journal of Environmental Research and Technology 4, 515–530.
[35] Chakravarty P., Sarma N.S., Sharma H.P., (2010) Removal of Pb (II) from aqueous solution using heartwood of Areca catechu powder, Desalination 256, 16-21.
[36] Ata S., Din M.I., Rasool A., Qasim I., Ul Mohsin I., (2012) Equilibrium, thermodynamics, and kinetic sorption studies for the removal of coomassie brilliant blue on wheat bran as a low cost adsorbent, Journal of Analytical Methods in Chemistry, 1-8.
[37] Calvete T., Lima E.C., Cardoso N.F., Silvio L.D., Pavan F.A., (2009) Application of carbon adsorbents prepared from the Brazilian-pine fruit shell for removal of procion red MX 3B from aqueous solution-kinetic, equilibrium and thermodynamic studies, Chemical Engineering Journal 155, 627–636.
[38] Rahdar S., Ahmadi Sh., (2016) Removal of phenol and aniline from aqueous solutions by using adsorption onto Pistacia terebinthus: study of adsorption isotherm and kinetics, Journal of Health Research in Community 2, 35–45.
[39] Igwegbe C.A., Al-Rawajfeh A.E., Al-Itawi H.I., Al-Qazaqi S., Hashish E.A., Al-Qatatsheh M., Sharadqah S., Sillanpaa M., (2019) Utilization of calcined gypsum in water and wastewater treatment: removal of phenol, Journal of Ecological Engineering 20(7), 1–10.
[40] Ahmadi S., Igwegbe C.A., Rahdar S., Asadi Z., (2019) The survey of application of the linear and nonlinear kinetic models for the adsorption of nickel (II) by modified multi-walled carbon nanotubes, Appl. Water Sci. 9, 98.
[41] Ahmadi S., Igwegbe C.A., (2018) Adsorptive removal of phenol and aniline by modified bentonite: adsorption isotherm and kinetics study, Applied Water Science 8:170.
[42] Carneiro P.A., Umbuzeiro G.A., Oliveira D.P., Zanoni M.V.B., (2010) Assessment of water contamination caused by a mutagenic textile effluent/dyehouse effluent bearing disperse dyes, Journal of Hazardous Materials 174, 694-699.
[43] Khoshnamvand N., Ahmadi Sh., Kord Mostafapour F., (2017) Kinetic and isotherm studies on Ciprofloxacin an adsorption using magnesium oxide nanoparticles, Journal of Applied Pharmaceutical Science 7, 079-083.
[44] Jokiniemi J., Naushad M., Bhatnagar A., (2017) Optimization of fluoride removal from aqueous solution by Al2O3 nanoparticles, Journal of Molecular Liquids 238, 254–262.
[45] Igwegbe C.A., Onukwuli O.D., Nwabanne J.T., (2016) Adsorptive removal of vat yellow 4 on activated Mucuna pruriens (velvet bean) seed shells carbon, Asian Journal of Chemical Sciences 1, 1-16.
[46] Jawad A., Al-Heetim D., Abd Rashid R., (2019). Biochar from orange (Citrus sinensis) peels by acid activation for methylene blue adsorption, Iranian Journal of Chemistry and Chemical Engineering 38(2), 91-105.
[47] Rahdar S., Rahdar A., Igwegbe C.A., Moghaddam F., Ahmadi S., (2019) Synthesis and physical characterization of nickel oxide nanoparticles and its application study in the removal of ciprofloxacin from contaminated water by adsorption: Equilibrium and kinetic studies, Desalination and Water Treatment 141, 386–393.
[48] Kaya N., Yıldız Z. ve Ceylan S., (2018) Preparation and characterisation of biochar from hazelnut shell and its adsorption properties for methylene blue dye, Politeknik Dergisi 21(4), 765-776.
[49] Abbasi H., Asgari H., (2018) Removal of methylene blue from aqueous solutions using Luffa adsorbent modified with sodium dodecyl sulfate anionic surfactant, Global NEST Journal 20(3), 582-588.
[50] Nayeri D., Mousavi S.A., Fatahi M., Almasi A., Khodadoost F., (2019) Dataset on adsorption of methylene blue from aqueous solution onto activated carbon obtained from low cost wastes by chemical-thermal activation e modelling using response surface methodology, Data in Brief 25, 104036.
[51] Derakhshan Z., Baghapour M.A., Ranjbar M., Faramarzian M, (2013) Adsorption of methylene blue dye from aqueous solutions by modified pumice stone: kinetics and equilibrium studies, Health Scope 2(3), 136-144.
[52] Moeinian K., Mehdinia S.M., (2019) Removing Methylene Blue from aqueous solutions using rice husk silica adsorbent, Pol. J. Environ. Stud. 28(4):2281–2287.

Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Shahin Ahmadı This is me
0000-0003-2831-2148
Iran

Chinenye Adaobi Igwegbe This is me
0000-0002-5766-7047
Nigeria

Publication Date

March 27, 2020

Submission Date

November 6, 2019

Acceptance Date

January 8, 2020

Published in Issue

Year 2020 Volume: 38 Number: 1

IZ

https://izlik.org/JA23MW68PP

Cite

RIS / Bibtex

APA

Ahmadı, S., & Igwegbe, C. A. (2020). Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study. Sigma Journal of Engineering and Natural Sciences, 38(1), 289-303. https://izlik.org/JA23MW68PP

AMA

1.Ahmadı S, Igwegbe CA. Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study. SIGMA. 2020;38(1):289-303. https://izlik.org/JA23MW68PP

Chicago

Ahmadı, Shahin, and Chinenye Adaobi Igwegbe. 2020. “Removal of Methylene Blue on Zinc Oxide Nanoparticles: Nonlinear and Linear Adsorption Isotherms and Kinetics Study”. Sigma Journal of Engineering and Natural Sciences 38 (1): 289-303. https://izlik.org/JA23MW68PP.

EndNote

Ahmadı S, Igwegbe CA (March 1, 2020) Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study. Sigma Journal of Engineering and Natural Sciences 38 1 289–303.

IEEE

[1]S. Ahmadı and C. A. Igwegbe, “Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study”, SIGMA, vol. 38, no. 1, pp. 289–303, Mar. 2020, [Online]. Available: https://izlik.org/JA23MW68PP

ISNAD

Ahmadı, Shahin - Igwegbe, Chinenye Adaobi. “Removal of Methylene Blue on Zinc Oxide Nanoparticles: Nonlinear and Linear Adsorption Isotherms and Kinetics Study”. Sigma Journal of Engineering and Natural Sciences 38/1 (March 1, 2020): 289-303. https://izlik.org/JA23MW68PP.

JAMA

1.Ahmadı S, Igwegbe CA. Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study. SIGMA. 2020;38:289–303.

MLA

Ahmadı, Shahin, and Chinenye Adaobi Igwegbe. “Removal of Methylene Blue on Zinc Oxide Nanoparticles: Nonlinear and Linear Adsorption Isotherms and Kinetics Study”. Sigma Journal of Engineering and Natural Sciences, vol. 38, no. 1, Mar. 2020, pp. 289-03, https://izlik.org/JA23MW68PP.

Vancouver

1.Shahin Ahmadı, Chinenye Adaobi Igwegbe. Removal of methylene blue on zinc oxide nanoparticles: nonlinear and linear adsorption isotherms and kinetics study. SIGMA [Internet]. 2020 Mar. 1;38(1):289-303. Available from: https://izlik.org/JA23MW68PP