FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES

Benan Yazıcı Karabulut; Ayşe Dilek Atasoy; Mehmet İrfan Yeşilnacar

FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES

Abstract

Endemic fluorosis cases were detected in primary school students in Sarım and Karataş villages situated in the north-west of Sanliurfa. Fluorosis is resulted from high concentrations of fluoride in groundwater and observed in some regions of Turkey having volcanic rocks and geothermal fields. Results of fluoride analyses indicated that the concentrations in groundwater samples were above the admissible limit values for potable water (>1.5 mg L-1). Hence, fluoride concentration in groundwater must be decreased to an optimum level that was recommended in national and international groundwater regulations. Objectives of this work are; to study the high fluoride in groundwater of arid-semiarid region and its health effects on children and to examine its removal efficiency from groundwater by electrocoagulation (EC) and adsorption processes. Adsorption processes were performed by batch method with clay minerals. The fluoride adsorption values concorded well with both Langmuir and Freundlich equations. Low value for Kf (0.14) showed low F adsorption which can be accounted by negatively charged sites on the clay mineral. EC process including the electrodes, reactor and the power source successfully removed the fluoride from groundwater sample. F removal rate was found as 99% at the end of 4.5 h. EC method on the removal of F was more successful than F adsorption on the clay.

Keywords

References

[1] Irigoyen-Camacho M.E., García Pérez A., Mejía González A., Huizar Alvarez R. (2016) Nutritional Status and Dental Fluorosis Among School Children in communities with Different Drinking Water Fluoride Concentrations in a Central Region in Mexico, Science of the Total Environment 541, 512-519.
[2] Bhatnagar A., Sillanpää M., (2011) A Review of Emerging Adsorbents for Nitrate Removal from Water, Chemical Engineering Journal 168, 493-504.
[3] World Health Organisation, (1994) Fluorides and Oral Health, Technical Report Series No: 846, World Health Organisation, Geneva.
[4] Atasoy A.D., Yesilnacar M.I., (2017) The Hydrogeochemical Occurrence of Fluoride in Groundwater and Its Effect on Human Health: A Case Study from Sanliurfa, Turkey, Environment and Ecology Research 5(2): 167-172.
[5] Atasoy A.D., Yesilnacar M.İ., Özdemir-Şahin M., (2013) Removal of Fluoride from Contaminated Groundwater Using Raw and Modified Bauxite, Bulletin of Environmental Contamination and Toxicology 91, 595-599.
[6] World Health Organisation (2006) Fluorides in Drinking-Water, WHO Drinking-Water Quality Series, London, UK: IWA Publishing.
[7] Do L.G., Spencer A., (2007) Oral Health Related Quality of Life of Children by Dental Caries and Fluorosis Experience, Journal of Public Health Dentistry 67, 132 139.
[8] Chuah C.J., Lye H.R., Ziegler A.D., Wood S.H., Kongpun C., Rajchagool S., (2016) Fluoride: A Naturally-Occurring Health Hazard in Drinking-Waterresources of Northern Thailand, Science of the Total Environment 545-546, 266-279.

[9] Carvalho C.A.P., Nicodemo C.A.Z., Mercadante D.C.F., Carvalho F.S., Buzalaf M.A.R., Carvalho Sales-Peres, S.H., (2013) Dental Fluorosis in The Primary Dentition and Intake of Manufactured Soy-Based Foods with Fluoride, Clinical Nutrition 32, 432-437.
[10] Sandoval M.A., Fuentes R., Nava J.L., Rodríguez I., (2014) Fluoride Removal from Drinking Water by Electrocoagulation in a Continuous Filter Press Reactor Coupled to a Flocculator and Clarifier, Separation and Purification Technology 134, 163-170.
[11] Sandoval M.A., Fuentes R., Nava J.L., Coreño O., Li Y., Hernández J.H., (2019) Simultaneous Removal of Fluoride and Arsenic from Groundwater by Electrocoagulation Using a Filter-Press Flow Reactor with a Three-Cell Stack, Separation and Purification Technology 208, 208-216.
[12] Oruç N., (1977) Preliminary Study on The Effect of Water-borne Fluoride on The Fluoride Content of Soils and Plants: in Seminar on Problems of High Fuoride Waters, CENTO Scientific Problems, Report No: 28, Atatürk University, Erzurum, Turkey.
[13] Oruç N., (2001) Türkiye’de Yüksek Düzeyde Florür İçeren Kaynak Suları ve Önemi, 1. Türkiye Su Kongresi, 8-10 Ocak 2001, 629-638, İstanbul, Turkey.
[14] Oruç N., (2008) Occurrence and Problems of High Fluoride Waters in Turkey: an Overview, Environmental Geochemistry and Health 30, 315-323.
[15] Sendil C., Baysu N., (1973) İnsan ve Hayvanlarda Ağrı İli Muradiye İlçesi Köylerinde Saptamamızla İlgili İlk Tebliğ, Ankara Üniversitesi Veteriner Fakültesi Dergisi 20, 4.
[16] Atasoy A.D., Yeşilnacar M.İ., Yazıcı-Karabulut B., Özdemir-Şahin M., (2016) Fluoride in Groundwater and Its Effects on Dental Health, World Journal of Environmental Research 6(2): 51-57.
[17] Yeşilnacar M.İ., (2010) Karataş ve Sarım Köylerinin İçme ve Kullanma Suyunda Yüksek Florür Şüphesiyle Çocukların Dişlerinde Oluşan Sorunun İncelenmesi, Ön Araştırma Raporu 2010, Şanlıurfa İl Sağlık Müdürlüğü, Şanlıurfa,Türkiye, pp. 9.
[18] Yeşilnacar M.İ, Demir-Yetiş A., Dülgergil Ç.T., Kumral M., Atasoy A.D., Rastgeldi-Doğan T., Tekiner S.İ., Bayhan İ., Aydoğdu M., (2016) Geomedical Assessment of an Area Having High-Fluoride Groundwater in Southeastern Turkey, Environmental Earth Sciences 75, 162.
[19] Richards L.A., Vuachere M., Schafer A.I., (2010) Impact of pH on The Removal of Fluoride, Nitrate and Boron by Nanofiltration/Reverse Osmosis, Desalination 261, 331-337.
[20] Arahman N., Mulyati S., Lubis M.R., Takagi R., Matsuyama H., (2016) The Removal of Fluoride from Water Based on Applied Current and Membrane Types in Electrodialysis, Journal of Fluorine Chemistry 191, 97-102.
[21] Gong We.X. Qu J.H., Liu R.P., Lan H.C., (2012) Adsorption of Fluoride onto Different Types of Aluminas, Chemical Engineering Journal 189-190, 126-133.
[22] Chubar N., (2011) New Inorganic (an)Ion Exchangers Based on Mg–Al Hydrous Oxides: (Alkoxide-Free) Sol–Gel Synthesis and Characterization, Journal of Colloid and Interface Science 357, 198-209.
[23] Behbahani M., Alavi Moghaddam M.R., Arami M. (2011) Techno-Economical Evaluation of Fluoride Removal by Electrocoagulation Process: Optimization Through Response Surface Methodology, Desalination 271, 209-218.
[24] Thakur L.S., Mondal P., (2017) Simultaneous Arsenic and Fluoride Removal from Synthetic and Real Groundwater by Electrocoagulation Process: Parametric and Cost Evaluation, Journal of Environmental Management 190, 102-112.
[25] Holt P.K., Barton G.W., Mitchell C.A., (2005) The Future for Electrocoagulation as a Localized Water Treatment Technology, Chemosphere 59(3): 355-367.
[26] Hashim K.S., Shaw A., Khaddar R.A., Pedrola M.O., Phipps D., (2017) Energy Efficient Electrocoagulation Using a New Flow Column Reactor to Remove Nitrate from Drinking Water Experimental, Statistical, and Economic Approach, Journal of Environmental Management 196, 224-233.
[27] Gülşen H., Çiftçi C., (2017) Güneydoğu Anadolu Bölgesi’nin Yenilenebilir Enerji Kaynakları Bakımından Potansiyelinin Araştırılması, Academia Journal of Engineering and Applied Sciences 1(3): 48-56.
[28] Valero D., Ortiz J.M., Expo´sito E., Montiel V., Aldaz A., (2008) Electrocoagulation of a Synthetic Textile Effluent Powered by Photovoltaic Energy Without Batteries: Direct Connection Behaviour, Solar Energy Materials & Solar Cells 92, 291-297.
[29] Prakash S., Srivastava S., (2013) Solar Energy and Its Future Role in Indian Economy, International Journal of Environmental Science Development and Monitoring 4(3): 81-88.
[30] Pavón-Silva T.B., Romero-Tehuitzil H., Munguia del Río G. and Huacuz-Villamar J., (2018) Photovoltaic Energy-Assisted Electrocoagulation of a Synthetic Textile Effluent, International Journal of Photoenergy pp. 9.
[31] Nawarkar C.J., Salkar V.D., (2019) Solar Powered Electrocoagulation System for Municipal Wastewater Treatment, Fuel 237, 222-226.
[32] Atasoy A.D., Yesilnacar M.İ., Çelik A.Z., (2013) High Fluoride Level in Groundwater and Fluoride Adsorption on Activated Carbon, International Conference on Environmental Science and Technology, ICOEST2013, 18-21 June 2013, Cappadocia, Turkey.
[33] Agarwal M., Rai K., Shrivastas R., Dass S., (2003) Defluoridation of Water Using Amended Clay, Journal of Cleaner Production 11, 439-444.
[34] Shahrokhian S., Ghalkhani M., Adeli M., Amini M.K., (2009) Multi-Walled Carbon Nanotubes with Immobilised Cobalt Nanoparticle for Modification of Glassy Carbon Electrode: Application to Sensitive Voltammetric Determination of Thioridazine, Biosensors and Bioelectronics 24, 3235-3241.
[35] Yang T., Zhou N., Zhang Y., Zhang W., Jiao K., Li G., Synergistically Improved Sensitivity for The Detection of Specific DNA Sequences Using Polyaniline Nanofibers and Multi-Walled Carbon Nanotubes Composites, Biosensors and Bioelectronics 24, 2165-2170.
[36] Sanghavi B.J., Srivastava A.K., (2011) Adsorptive Stripping Differential Pulse Voltammetric Determination of Venlafaxine and Desvenlafaxine Employing Nafion–Carbon Nanotube Composite Glassy Carbon Electrode, Electrochimica Acta 56, 4188-4196.
[37] Jagtap S., Yenkie M.K.N., Labhsetwar N., Rayalu S., (2011) Defluoridation of Drinking Water Using Chitosan Based Mesoporous Alumina, Microporous Mesoporous Materials 142, 454-463.
[38] Mullick A., Sudarsan N., (2019) Ultrasound Assisted Synthesis of Mg-Mn-Zr Impregnated Activated Carbon for Effective Fluoride Adsorption from Water, Ultrasonics Sonochemistry 50, 126-137.
[39] Zhu J., Zhao H., Ni J., (2007) Fluoride distribution in electrocoagulation defluoridation process, Seperation and Purification Technology 56 ,184-191.
[40] Liu H., Deng S., Li Z., Yu G., Huang J., (2010) Preparation of Al–Ce Hybrid Adsorbent and Its Application for Defluoridation of Drinking Water, Journal of Hazardous Materials 179, 424-430.
[41] Sparks D.L., (1995) Environmental Soil Chemistry. Academic Press, San Diego. CA.
[42] Derin P., Yeşilnacar M.İ., Bayhan İ., Çalışır M., Kirmit A., (2018) Investigation of Drinking Water Quality in terms of High Fluoride Level in a Rural Area: The Case of Sarım and Karataş Village (Şanlıurfa), First Findings, 71st Geological Congress of Turkey, 23-27 April 2018, Ankara, Turkey.
[43] Shen F., Chen X., Gao P., Chen G., (2003) Electrochemical Removal of Fluoride Ions from Industrial Wastewater, Chemical Engineering Science 58, 987-993.
[44] Aoudj S., Khelifa A., Drouiche N., (2017) Removal of Fluoride, SDS, Ammonia and Turbidity from Semiconductor Wastewater by Combined Electrocoagulation-Electroflotation, Chemosphere 180, 379-387.
[45] Ghosh D., Medhi C.R., Purkait M.K., (2008) Treatment of Fluoride Containing Drinking Water by Electrocoagulation Using Monopolar and Bipolar Electrode Connections, Chemosphere, 73, 1393-1400.
[46] Zuo Q., Chen X., Li W., Chen G., (2008) Combined Electrocoagulation and Electroflotation for Removal of Fluoride from Drinking Water, Journal of Hazardous Materials 159, 452-457.
[47] Hakiziman J.N., Gourich B., Chafi M., Stiriba Y., Vial C., Drogui P., Naja J., (2017) Electrocoagulation Process in Water Treatment: a Review of Electrocoagulation Modeling Approaches, Desalination 404, 1-21.
[48] Bensadok K., Benammar S., Lapicque F., Nezzal G., (2008) Electrocoagulation of Cutting Oil Emulsions Using Aluminum Plate Electrodes, Journal of Hazardous Materials 152, 423-430.
[49] Un U.T., Koparal A.S., Ogutveren U.B., (2013) Fluoride Removal from Water and Wastewater with a Batch Ccylindrical Electrode Using Electrocoagulation, Chemical Engineering Journal 223, 110-115.
[50] Aoudj S., Khelifa A., Drouiche N., Belkada R., Miroud D., (2015) Simultaneous removal of chromium (VI) and fluoride by electrocoagulation–electroflotation: Application of a hybrid Fe-Al anode, Chemical Engineering Journal 267, 153-167.
[51] Silva F.A., Graça N.S., Ribeiro A.M., Rodrigues A.E., (2018) Electrocoagulation process for the removal of co-existent fluoride, arsenic and iron from contaminated drinking water, Separation and Purification Technology 197, 237-243.
[52] Rozales M., Oscar C., Nava J.L., (2018) Removal of hydrated silica, fluoride and arsenic from groundwater by electrocoagulation using a continuous reactor with a twelve-cell stack, Chemosphere 211, 149-155.
[53] López-Guzmán M., Alarcón-Herrera M.T., Irigoyen-Campuzano J.R., Torres-Castañón L.A., Reynoso-Cuevas L., (2019) Simultaneous removal of fluoride and arsenic from well water by electrocoagulation, Science of the Total Environment 678, 181-187.
[54] Alcacio R., Nava J.L., Carreno G., Elorza E., Martinez F., (2014) Removal of arsenic from deep well by electrocoagulation in a continuous filter press reactor, Water Science and Technology: Water Supply 14, 189-195.
[55) Can B.Z., Boncukcuoglu R., Yilmaz A.E., Fil B.A., (2014) Effect of some operational parameters on the arsenic removal by electrocoagulation using iron electrodes, Journal of Environmental Health Science & Engineering 12, 2-10.
[56] Uzun H.I., Debik E., (2019) Economical approach to nitrate removal via membrane capacitive deionization, Separation and Purification Technology 209, 776-781.
[57] Xu L., Cao G., Xu X., Liu S., Duan Z., He C., Wang Y., Huang Q., (2017) Simultaneous removal of cadmium, zinc and manganese using electrocoagulation: Influence of operating parameters and electrolyte nature, Journal of Environmental Management 204, 394-403.
[58] Mandal S., Mayadevi S., (2009) Defluoridation of Water Using As‐Synthesized Zn/Al/Cl Anionic Clay Adsorbent: Equilibrium and Regeneration Studies, Journal of Hazardous Materials 167, 873-878.
[59] Sundaram C.S., Viswanathan N., Meenakshi S., (2009) Defluoridation of Water Using Magnesia/Chitosan Composite, Journal of Hazardous Materials 163, 618-624.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Benan Yazıcı Karabulut This is me
Türkiye

Ayşe Dilek Atasoy This is me
0000-0002-8689-7300
Türkiye

Mehmet İrfan Yeşilnacar This is me
0000-0001-9724-8683
Türkiye

Publication Date

December 1, 2019

Submission Date

April 10, 2019

Acceptance Date

August 27, 2019

Published in Issue

Year 2019 Volume: 37 Number: 4

IZ

https://izlik.org/JA47WR43KX

Cite

RIS / Bibtex

APA

Yazıcı Karabulut, B., Atasoy, A. D., & Yeşilnacar, M. İ. (2019). FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES. Sigma Journal of Engineering and Natural Sciences, 37(4), 1250-1262. https://izlik.org/JA47WR43KX

AMA

1.Yazıcı Karabulut B, Atasoy AD, Yeşilnacar Mİ. FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES. SIGMA. 2019;37(4):1250-1262. https://izlik.org/JA47WR43KX

Chicago

Yazıcı Karabulut, Benan, Ayşe Dilek Atasoy, and Mehmet İrfan Yeşilnacar. 2019. “FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES”. Sigma Journal of Engineering and Natural Sciences 37 (4): 1250-62. https://izlik.org/JA47WR43KX.

EndNote

Yazıcı Karabulut B, Atasoy AD, Yeşilnacar Mİ (December 1, 2019) FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES. Sigma Journal of Engineering and Natural Sciences 37 4 1250–1262.

IEEE

[1]B. Yazıcı Karabulut, A. D. Atasoy, and M. İ. Yeşilnacar, “FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES”, SIGMA, vol. 37, no. 4, pp. 1250–1262, Dec. 2019, [Online]. Available: https://izlik.org/JA47WR43KX

ISNAD

Yazıcı Karabulut, Benan - Atasoy, Ayşe Dilek - Yeşilnacar, Mehmet İrfan. “FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES”. Sigma Journal of Engineering and Natural Sciences 37/4 (December 1, 2019): 1250-1262. https://izlik.org/JA47WR43KX.

JAMA

1.Yazıcı Karabulut B, Atasoy AD, Yeşilnacar Mİ. FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES. SIGMA. 2019;37:1250–1262.

MLA

Yazıcı Karabulut, Benan, et al. “FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES”. Sigma Journal of Engineering and Natural Sciences, vol. 37, no. 4, Dec. 2019, pp. 1250-62, https://izlik.org/JA47WR43KX.

Vancouver

1.Benan Yazıcı Karabulut, Ayşe Dilek Atasoy, Mehmet İrfan Yeşilnacar. FLUORIDE CONTAMINATION IN GROUNDWATER AND ITS REMOVAL BY ADSORPTION AND ELECTROCOAGULATION PROCESSES. SIGMA [Internet]. 2019 Dec. 1;37(4):1250-62. Available from: https://izlik.org/JA47WR43KX