EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID

Ali Yaraş; Hasan Arslanoğlu

EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID

Abstract

In present study, paper mill sludge (PMS) in cellulosic structure carbonized with sulfuric acid was utilized for adsorption of cationic basic yellow 51 (BY 51) dye from synthetic solution. The parameters affecting on removal of BY 51 dye following; initial pH (2-11), amount of carbonized paper mill sludge (CPMS) (0.25-1.5 g/l), initial concentration (0.5-2 mM), time (0-360 min.) and temperature (25-55°C) were studied in the batch adsorption experiments. The physical and chemical properties of prepared CPMS were determined using elemental analyzes, scanning electron microscopy (SEM) and BET techniques. Optimum initial pH was measured to be 7 for the removal of BY 51 dye. The obtained equilibrium data in various initial concentrations of BY 51 dye solution varied from 0.5 to 2.5 mM for three temperatures (25°C, 40°C and 55°C) were applied to Langmuir and Freundlich isotherms. The calculated maximum adsorption capacity (qmax) from Langmuir equation was achieved 1089.45 mg/g depending on increasing temperature from 25oC to 55oC. The experimental results for all temperatures were applied to pseudo-first order kinetic model, pseudo-second order kinetic model and intra-particle diffusion model. Consequently, it was good agreement with the second-order kinetic model and the activation energy (Ea) is calculated as 11.642 kJ/mol. Thermodynamic parameters such as enthalpy (∆H°, +19.32 kJ/mol), free energy (∆G°, -23.02 kJ/mol) and entropy (∆S°, 0.142 kJ/molK) were also calculated. The results showed that the adsorption phenomena of cationic BY 51 dye is of endothermic and spontaneous nature. The findings presented that CPMS could be utilized as adsorbent in the treatment of industrial wastewater.

Keywords

References

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Ali Yaraş This is me
0000-0003-1725-7788
Türkiye

Hasan Arslanoğlu This is me
0000-0002-3132-4468
Türkiye

Publication Date

September 1, 2018

Submission Date

April 6, 2018

Acceptance Date

June 25, 2018

Published in Issue

Year 2018 Volume: 36 Number: 3

IZ

https://izlik.org/JA58WC67PA

Cite

RIS / Bibtex

APA

Yaraş, A., & Arslanoğlu, H. (2018). EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID. Sigma Journal of Engineering and Natural Sciences, 36(3), 803-818. https://izlik.org/JA58WC67PA

AMA

1.Yaraş A, Arslanoğlu H. EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID. SIGMA. 2018;36(3):803-818. https://izlik.org/JA58WC67PA

Chicago

Yaraş, Ali, and Hasan Arslanoğlu. 2018. “EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID”. Sigma Journal of Engineering and Natural Sciences 36 (3): 803-18. https://izlik.org/JA58WC67PA.

EndNote

Yaraş A, Arslanoğlu H (September 1, 2018) EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID. Sigma Journal of Engineering and Natural Sciences 36 3 803–818.

IEEE

[1]A. Yaraş and H. Arslanoğlu, “EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID”, SIGMA, vol. 36, no. 3, pp. 803–818, Sept. 2018, [Online]. Available: https://izlik.org/JA58WC67PA

ISNAD

Yaraş, Ali - Arslanoğlu, Hasan. “EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID”. Sigma Journal of Engineering and Natural Sciences 36/3 (September 1, 2018): 803-818. https://izlik.org/JA58WC67PA.

JAMA

1.Yaraş A, Arslanoğlu H. EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID. SIGMA. 2018;36:803–818.

MLA

Yaraş, Ali, and Hasan Arslanoğlu. “EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID”. Sigma Journal of Engineering and Natural Sciences, vol. 36, no. 3, Sept. 2018, pp. 803-18, https://izlik.org/JA58WC67PA.

Vancouver

1.Ali Yaraş, Hasan Arslanoğlu. EFFICIENT REMOVAL OF BASIC YELLOW 51 DYE VIA CARBONIZED PAPER MILL SLUDGE USING SULFURIC ACID. SIGMA [Internet]. 2018 Sep. 1;36(3):803-18. Available from: https://izlik.org/JA58WC67PA