Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method

A. Çiğdem Adıgüzel; Burak Korkmaz; Fatih Çakar; Özlem Cankurtaran; B. Filiz Şenkal

Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method

Abstract

In the present work, vinyl benzyl chloride (VBC) was polymerized by using free radical polymerization. The obtained PVBC was reacted with dibutyl amine to obtain tertiary amine modified polystyrene based polymer (PVBC-Dibutyl amine). The inverse gas chromatography (IGC) method was used to examine the thermodynamic properties of the polymer. Firstly, the retention diagrams of some polar and non-polar solvents on PVBC-Dibutyl amine were obtained over a temperature range from 135 to 160° C. Then, the thermodynamic parameters, including Flory–Huggins interaction parameter, weight fraction activity coefficient, partial molar heat of sorption, and partial molar heat of mixing were determined via interactions between the polymer and selected solvents at infinite dilution. The results reveal that the alkanes are poor solvents for the polymer whereas n-butyl acetate, i-butyl acetate, ethyl acetate, n-propylbenzene, i-propylbenzene, and ethylbenzene are moderately solvents in the studied temperature range.

Keywords

References

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Details

Primary Language

English

Subjects

Industrial Biotechnology

Journal Section

Research Article

Authors

A. Çiğdem Adıgüzel This is me
0000-0003-4765-1102
Türkiye

Burak Korkmaz This is me
0000-0002-2530-1761
Türkiye

Fatih Çakar This is me
0000-0001-6192-1370
Türkiye

Özlem Cankurtaran ^* This is me
0000-0002-8383-1170
Türkiye

B. Filiz Şenkal This is me
0000-0002-1616-6828
Türkiye

Publication Date

November 17, 2021

Submission Date

October 24, 2020

Acceptance Date

January 12, 2021

Published in Issue

Year 2021 Volume: 39 Number: 4

IZ

https://izlik.org/JA68BB67AW

Cite

RIS / Bibtex

APA

Adıgüzel, A. Ç., Korkmaz, B., Çakar, F., Cankurtaran, Ö., & Şenkal, B. F. (2021). Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method. Sigma Journal of Engineering and Natural Sciences, 39(4), 414-421. https://izlik.org/JA68BB67AW

AMA

1.Adıgüzel AÇ, Korkmaz B, Çakar F, Cankurtaran Ö, Şenkal BF. Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method. SIGMA. 2021;39(4):414-421. https://izlik.org/JA68BB67AW

Chicago

Adıgüzel, A. Çiğdem, Burak Korkmaz, Fatih Çakar, Özlem Cankurtaran, and B. Filiz Şenkal. 2021. “Thermodynamic Studies on Tert-Amine Modified Polystyrene Based Polymer Solvent Systems by Inverse Gas Chromatography Method”. Sigma Journal of Engineering and Natural Sciences 39 (4): 414-21. https://izlik.org/JA68BB67AW.

EndNote

Adıgüzel AÇ, Korkmaz B, Çakar F, Cankurtaran Ö, Şenkal BF (November 1, 2021) Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method. Sigma Journal of Engineering and Natural Sciences 39 4 414–421.

IEEE

[1]A. Ç. Adıgüzel, B. Korkmaz, F. Çakar, Ö. Cankurtaran, and B. F. Şenkal, “Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method”, SIGMA, vol. 39, no. 4, pp. 414–421, Nov. 2021, [Online]. Available: https://izlik.org/JA68BB67AW

ISNAD

Adıgüzel, A. Çiğdem - Korkmaz, Burak - Çakar, Fatih - Cankurtaran, Özlem - Şenkal, B. Filiz. “Thermodynamic Studies on Tert-Amine Modified Polystyrene Based Polymer Solvent Systems by Inverse Gas Chromatography Method”. Sigma Journal of Engineering and Natural Sciences 39/4 (November 1, 2021): 414-421. https://izlik.org/JA68BB67AW.

JAMA

1.Adıgüzel AÇ, Korkmaz B, Çakar F, Cankurtaran Ö, Şenkal BF. Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method. SIGMA. 2021;39:414–421.

MLA

Adıgüzel, A. Çiğdem, et al. “Thermodynamic Studies on Tert-Amine Modified Polystyrene Based Polymer Solvent Systems by Inverse Gas Chromatography Method”. Sigma Journal of Engineering and Natural Sciences, vol. 39, no. 4, Nov. 2021, pp. 414-21, https://izlik.org/JA68BB67AW.

Vancouver

1.A. Çiğdem Adıgüzel, Burak Korkmaz, Fatih Çakar, Özlem Cankurtaran, B. Filiz Şenkal. Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method. SIGMA [Internet]. 2021 Nov. 1;39(4):414-21. Available from: https://izlik.org/JA68BB67AW