ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS

Özgen Ömür Pekel

ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS

Abstract

Inorganic and organometallic boron compounds are being extremely used in organic synthesis Sodium perborate NaBO3, is a cheap and commonly used oxidation reagent; sodium borohydride, NaBH4 and diborane, B2H6 are reduction reagents used for hydride transfer. Organoboranes, R3B which are easily prepared by addition of B2H6, to alkenes and alkynes (hydroboration) are an important class of organoboron compounds and Prof. H. Brown has received 1979 Nobel laurate due to his research on this subject. Organoboron compounds and especially organoboranes have importance and a wide range of application in organic synthesis and especially in synthesis of pharmaceuticals and due to their easy preparation, stability in water and air, toleration toward functional reagents, high stereoselectivity of their reactions and nontoxic boric acid as a side product. Pd catalyzed C-C coupling, which is one of the most important reactions of organoboron compunds, is known as Suzuki-Miyaura reaction and Prof. A.Suzuki has received 2010 Nobel laurate due to his research in this subject. In last ten years, there has been a great increase in the reseach on the reactions of organoboron compounds and their industrial applications. In this account, preparation methods and use of organaboron compounds in organic synthesis have been summarized and the importance and applicability of Suzuki-Miyaura Reaction has been reviewed .

Keywords

References

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Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Review

Authors

Özgen Ömür Pekel This is me
Türkiye

Publication Date

December 1, 2013

Submission Date

January 14, 2013

Acceptance Date

April 10, 2013

Published in Issue

Year 2013 Volume: 31 Number: 4

IZ

https://izlik.org/JA36KM69XF

Cite

RIS / Bibtex

APA

Ömür Pekel, Ö. (2013). ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS. Sigma Journal of Engineering and Natural Sciences, 31(4), 477-494. https://izlik.org/JA36KM69XF

AMA

1.Ömür Pekel Ö. ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS. SIGMA. 2013;31(4):477-494. https://izlik.org/JA36KM69XF

Chicago

Ömür Pekel, Özgen. 2013. “ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS”. Sigma Journal of Engineering and Natural Sciences 31 (4): 477-94. https://izlik.org/JA36KM69XF.

EndNote

Ömür Pekel Ö (December 1, 2013) ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS. Sigma Journal of Engineering and Natural Sciences 31 4 477–494.

IEEE

[1]Ö. Ömür Pekel, “ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS”, SIGMA, vol. 31, no. 4, pp. 477–494, Dec. 2013, [Online]. Available: https://izlik.org/JA36KM69XF

ISNAD

Ömür Pekel, Özgen. “ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS”. Sigma Journal of Engineering and Natural Sciences 31/4 (December 1, 2013): 477-494. https://izlik.org/JA36KM69XF.

JAMA

1.Ömür Pekel Ö. ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS. SIGMA. 2013;31:477–494.

MLA

Ömür Pekel, Özgen. “ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS”. Sigma Journal of Engineering and Natural Sciences, vol. 31, no. 4, Dec. 2013, pp. 477-94, https://izlik.org/JA36KM69XF.

Vancouver

1.Özgen Ömür Pekel. ORGANOBORON COMPOUNDS AND THEIR USES IN ORGANIC SYNTHESIS. SIGMA [Internet]. 2013 Dec. 1;31(4):477-94. Available from: https://izlik.org/JA36KM69XF