Year 2020,
Volume: 11 Issue: 2, 185 - 191, 01.06.2020
Asena Damla Büyüküstün
Emir Erişir
,
Esat Gümüşkaya
References
- [1] Braihi, A.J., Salih, S.J., Hasham, F.A., Ahmed, J.K., (2014) Prepared crosslinking model for carboxynethyl cellulose/starch superabsorbent polyners blend, International of Material Science and Applications, 3(6), 363-369.
- [2] Mischnick P., Momcilovic D., (2010) Chemical structure analysis of starch and cellulose derivatives. Adv Carbohydr Chem Biochem 64:117–210.
- [3] Fekete, T., Borsa, J., Takacs, E., (2014) Synthesis of cellulose derivatives based superabsorbent hydrogels by radiation induced crosslinking, Cellulose J., 21, 4157-4165.
- [4] İbrahim, S.M., Salmawi, K.M., Zahran, A.H., (2007) Synthesis of crosslinked superabsorbent carboxymethul cellulose/Acrylamide hydrogel Through Electron Beam irradiation, Journal of Applied Polymer Scişence, 104, 2003-2008.
- [5] Bahram, M.; Mohseni, N.; Moghtader, M, (2016) Emerging Concepts in Analysis and Applications of Hydrogels; InTech: London, UK, 2016; ISBN 978-953-51-2510-5.
- [6] Laftah W.A. and Hashim,S., (2013) Preparation and possible agricultural applications of polymer hydrogel composite as soil conditioner, Adv. Mater Res., 626, 6–10.
- [7] Wang, D., Song, Z., Sheng, S.B., (2008) Characterization and biodegradability of amphoteric superabsorbent polymers, J. Appl. Polym. Sci., 107(6), 4116-4120.
- [8] Chang, C., Duan, B., Cai, L. & Zhang, L., (2010) Superaborbent hydrogels based on cellulose fors smart swelling and controllable delivery. European Polymer Journal, 46, 92-100.
- [9] Bao, Y., Ma, J. & Li, N., (2011) Synthesis and swelling behaviours of carboxymethylcellulose-g-poly (AA-co-AM-co-MPS)/MMT superabsorbent hydrogel. Carbohydrate Polymers, 84, 76-82.
- [10] Hubbe, M., Aguola, A., Daystar, J.S., Venditti, R.A., Pawlok, J.J., (2013) Enhanced absorbed products incorprating cellulose and its derivaties: A review. BioResources, 8(4), 6556-6629.
- [11] Wüstenberg, T., (2015) Cellulose and cellulose derivatives in the food industry. Singapore, Wiley VCH Verlag GMBH&Co. KGaA,
Germany.
- [12] Sannino, A., Demitri, C. & Madaghiele, M., (2009) Biodegradable cellulose-based hydrogel. Design and Apllications Materials, 2(2), 363-373.
- [13] Çelik, A.D., Gümüşkaya, E., Kırcı, H., Erişir, E., (2019) The Oxidative Pretreatments of Cellulose for Cellulosic Superabsorbents, Journal of Anatolian Environmental and Animal Sciences, 4(4), 657-661.
- [14] Kono, H., (2014) Characterization and properties of carboxymethyl cellulose hydrogels crosslinking by ethylene glycols, Carbohydrate Polymers, 16, 86-93.
- [15] Alam, N., Islam,S., Christopher, L.P., (2019) Sustainable Production of Cellulose-Based Hydrogels with Superb Absorbing Potential in Physiological Saline, ACS Omega, 4, 9419−9426.
CELLULOSIC SUPERABSORBENT PRODUCTION WITH CITRIC ACID CROSS-LINKING METHOD
Year 2020,
Volume: 11 Issue: 2, 185 - 191, 01.06.2020
Asena Damla Büyüküstün
Emir Erişir
,
Esat Gümüşkaya
Abstract
In this study, it was aimed to determine water and liquid salt solution absorption capacity of cellulosic superabsorbents that were produced by using citric acid crosslinking method. Cellulosic superabsorbents were prepared with mixing cellulose and carboxymethylcellulose at different ratio. The highest water absorption capacity in water was determined 2616% at pH:7 for cellulosic superabsorbent which was produced with cellulose (10%) and carboxymethylcelulose (90%). Absorption capacity of cellulosic superaborbent in salt solution was calculated 984% for NH4Cl2 liquid salt solution. It was concluded that carboxymethylcellulose had an affirmative effect on water absorption capacity of cellulosic superabsorbents.
References
- [1] Braihi, A.J., Salih, S.J., Hasham, F.A., Ahmed, J.K., (2014) Prepared crosslinking model for carboxynethyl cellulose/starch superabsorbent polyners blend, International of Material Science and Applications, 3(6), 363-369.
- [2] Mischnick P., Momcilovic D., (2010) Chemical structure analysis of starch and cellulose derivatives. Adv Carbohydr Chem Biochem 64:117–210.
- [3] Fekete, T., Borsa, J., Takacs, E., (2014) Synthesis of cellulose derivatives based superabsorbent hydrogels by radiation induced crosslinking, Cellulose J., 21, 4157-4165.
- [4] İbrahim, S.M., Salmawi, K.M., Zahran, A.H., (2007) Synthesis of crosslinked superabsorbent carboxymethul cellulose/Acrylamide hydrogel Through Electron Beam irradiation, Journal of Applied Polymer Scişence, 104, 2003-2008.
- [5] Bahram, M.; Mohseni, N.; Moghtader, M, (2016) Emerging Concepts in Analysis and Applications of Hydrogels; InTech: London, UK, 2016; ISBN 978-953-51-2510-5.
- [6] Laftah W.A. and Hashim,S., (2013) Preparation and possible agricultural applications of polymer hydrogel composite as soil conditioner, Adv. Mater Res., 626, 6–10.
- [7] Wang, D., Song, Z., Sheng, S.B., (2008) Characterization and biodegradability of amphoteric superabsorbent polymers, J. Appl. Polym. Sci., 107(6), 4116-4120.
- [8] Chang, C., Duan, B., Cai, L. & Zhang, L., (2010) Superaborbent hydrogels based on cellulose fors smart swelling and controllable delivery. European Polymer Journal, 46, 92-100.
- [9] Bao, Y., Ma, J. & Li, N., (2011) Synthesis and swelling behaviours of carboxymethylcellulose-g-poly (AA-co-AM-co-MPS)/MMT superabsorbent hydrogel. Carbohydrate Polymers, 84, 76-82.
- [10] Hubbe, M., Aguola, A., Daystar, J.S., Venditti, R.A., Pawlok, J.J., (2013) Enhanced absorbed products incorprating cellulose and its derivaties: A review. BioResources, 8(4), 6556-6629.
- [11] Wüstenberg, T., (2015) Cellulose and cellulose derivatives in the food industry. Singapore, Wiley VCH Verlag GMBH&Co. KGaA,
Germany.
- [12] Sannino, A., Demitri, C. & Madaghiele, M., (2009) Biodegradable cellulose-based hydrogel. Design and Apllications Materials, 2(2), 363-373.
- [13] Çelik, A.D., Gümüşkaya, E., Kırcı, H., Erişir, E., (2019) The Oxidative Pretreatments of Cellulose for Cellulosic Superabsorbents, Journal of Anatolian Environmental and Animal Sciences, 4(4), 657-661.
- [14] Kono, H., (2014) Characterization and properties of carboxymethyl cellulose hydrogels crosslinking by ethylene glycols, Carbohydrate Polymers, 16, 86-93.
- [15] Alam, N., Islam,S., Christopher, L.P., (2019) Sustainable Production of Cellulose-Based Hydrogels with Superb Absorbing Potential in Physiological Saline, ACS Omega, 4, 9419−9426.