Research Article
BibTex RIS Cite

ELECTROCHEMICAL STUDIES OF ZINC DEPOSITION CONDITIONS

Year 2019, Volume: 37 Issue: 4, 1262 - 1273, 01.12.2019

Abstract

Zinc films are deposited on steel from sulphate bath using electrodeposition process. Cyclic voltammetry and chronoamperometry are used to study the effect of pH on zinc electrodeposition process and nucleation model respectively. Furthermore, potentiodynamic polarisation and electrochemical impedance spectroscopyare used to study corrosion behaviour of zinc films.The pH of the bath was controlled at 4, for decreasinghydrogen evolution reaction,and increasing current efficiency of the Zn deposition. The study of the influence of deposition potential on corrosion behaviour in 3.5% NaCl, solution indicated that Zn film obtained at -1.26V presented less corrosion current and bestcorrosion resistance.

References

  • [1] Abbott A.P, Barron J.C, Frisch G, Ryder K.S, Silva A.F, (2011)The effect of additives on zinc electrodeposition from deep eutectic solvents, ElectrochimActa56, 5272-5279.
  • [2] Abbott A.P, Barron J.C, Frisch G, Gurman S, Ryder K.S, Silva A.F., (2011) Double layer effects on metal nucleation in deep eutectic solvents, PhysChem 13, 10224-10231.
  • [3] Boiadjieva T, Monev M, Tomandl A, Kronberger H, Fafilekal G., (2009) Electrochemical studies on Zn deposition and dissolution in sulphate electrolyte, J Solid State Electrochem 13, 671-677.
  • [4] Bockris J. O’M, Khan S. U. M, W., (1993) Surface Electrochemistry, a Molecular Level Approach, Surface Electrochemistry, Plenum Press, New York.
  • [5] Cantwell P.A, Chung P.P, Jiang H, Wilcox G.D, Critchlow G.W (2009)Corrosion from the Nanoscaleto the Plant, Proceedings of Eurocorr, Nice, France, September.
  • [6] Cachet C., Wiart R., (1990) Zinc deposition and passivated hydrogen evolution in highly acidic sulphate electrolytes: Depassivation by nickel impurities, J Appl Electrochem20, 1009-1014.
  • [7] Cachet C., Wiart R., (1994) Zinc Electrowinning in Acidic Sulfate Electrolytes: Impedance Analysis and Modeling of the Influence on Nickel Impurities, J Electrochem Soc 141, 131-140.
  • [8] Epelboin I, Ksouri M, Wiart R., (1975) On a Model for the Electrocrystallization of Zinc Involving an Autocatalytic Step, ElectrochemSoc122, 1206-2014.
  • [9] Epelboin I., Ksouri M., Lejay E., Wiart R., (1975) A study of the elementary steps of electron-transfer during the electrocrystállization of zinc, ElectrochimActa20, 603-605.
  • [10] Elkhatabi F., Barcelo G., Sarret M., Muller C., (1996) Electrochemical oxidation of zinc + nickel alloys in ammonium baths, J ElectroanalChem 419, 71-76.
  • [11] Gomes A., Pereira M.I.S., (2006) Zn electrodeposition in the presence of surfactants: Part I. Voltammetric and structural studies, ElectrochimActa52, 863-871.
  • [12] Gunawardena G., Hills G., Montenegro I., Scharifker B., (1982)Electrochemical nucleation: Part I. General considerations, J. of ElectroanChem and Inter Electrochem 138, 225-239.
  • [13] Ibrahim S., Bakkar A., Ahmed E., Selim A., (2016) Effect of additives and current mode on zinc electrodeposition from deep eutectic ionic liquids, ElectrochimActa 191, 724–732.
  • [14] Ichino R., Cachet C., Wiart R., (1996) Mechanism of zinc electrodeposition in acidic sulfate electrolytes containing Pb2+ ions,ElectrochimActa41, 1031-1039.
  • [15] Krishnan R.M., Natarajan S.R., Muralidharan V.S., Singh G., (1992) Characteristics of a Non-Cyanide Alkaline Zinc Plating Bath, Plat. Surf. Finish. 79, 67.
  • [16] Liu Z., Zein El Abedin S., Endres F., (2013) Electrodeposition of zinc films from ionic liquids and ionic liquid/water mixtures,ElectrochimActa89, 635-643.
  • [17] Marcos F., de Carvalho, Ivani A., Carlos (2013) Zinc electrodeposition from alkaline solution containing trisodiumnitrilotriacetic added, ElectrochimicaActa 113, 229– 239.
  • [18] Nitin P., WasekarA.,Jyothirmayi, NehaHebalkar G., Sundararajan (2015)Influence of pulsed current on the aqueous corrosion resistance of electrodeposited zinc, Surf Coat Technol272, 373–379.
  • [19] Otani T., Nagata M., Fukunaka Y., Homma T.,(2016)Morphological evolution of mossy structures during theelectrodeposition of zinc from an alkaline zincate solution,ElectrochimicaActa 206, 366–373.
  • [20] Ramesh Bapu G.N.K., Devaraj G., Ayyapparaj J., (1998) Studies on non-cyanide alkaline zinc electrolytes, J Solid State Electrochem 3, 48-51.
  • [21] Salles R. C.M, G. C.G. de Oliveira, Díaz S. L., Barcia O. E., Mattos O.R., (2011) Electrodeposition of Zn in acid sulphate solutions: PH effects, ElectrochimicaActa 56, 7931–7939.
  • [22] Scharifker B., Hills G., (1983)Theoretical and experimental studies of multiple nucleation, ElectrochimActa 28, 879-889.
  • [23] Song Y., Hu J., Gu W., Tang J., Fu Y., Ji X., (2017)The dynamic interfacial understanding of zinc electrodeposition in ammoniacal media through synchrotron radiation techniques, J ElectrochemSoc 164, 230.
  • [24] Song Y., Liu S., Tang J., Chang G., Fu Y., Jin W., Ji X., Hu J., (2018) Effective inhibition of zinc dendrites during electrodeposition using thiourea derivatives as additives, j. Mater.Sci. 54, 3536–3546.
  • [25] Xu. M., D. G. Ivey, W. Qu., and XieZ.,(2015)Study of the mechanism for electrodeposition of dendrite-free zinc in an alkaline electrolyte modified with 1-ethyl-3-methylimidazolium dicyanamide,J. Power Sources 274, 1249-1253.
There are 25 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Hayette Faıd This is me 0000-0002-7750-5491

Publication Date December 1, 2019
Submission Date May 20, 2019
Published in Issue Year 2019 Volume: 37 Issue: 4

Cite

Vancouver Faıd H. ELECTROCHEMICAL STUDIES OF ZINC DEPOSITION CONDITIONS. SIGMA. 2019;37(4):1262-73.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/