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SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)2RuCl2]

Year 2018, Volume: 36 Issue: 2, 487 - 499, 01.06.2018

Abstract

In this study, (ethylsulfanyl) porphyrazines have been modified with one peripheral ruthenium bipyridine groups. These compounds possess (bpy)2RuII moieties directly attached to the β position in the (ethylsulfanyl) porphyrazines through thioether chelation. The new compounds have been characterized by elemental analysis, FT-IR, 1H-NMR spectroscopy and mass spectra. The spectral properties such as electronic spectra, aggregation and fluorescence of compounds have been studied in THF. Insertion of (bpy)2RuII moiety on the porphyrazines structure have been investigated photophysical properties of the complexes.

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There are 43 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Fatma Aytan Kılıçarslan This is me 0000-0002-4623-3067

Ali Erdoğmuş This is me 0000-0001-9282-7651

Sabiha Manav Yalçın This is me

Ahmet Gül This is me

Publication Date June 1, 2018
Submission Date November 14, 2017
Published in Issue Year 2018 Volume: 36 Issue: 2

Cite

Vancouver Kılıçarslan FA, Erdoğmuş A, Manav Yalçın S, Gül A. SYNTHESIS, CHARACTERIZATION, SPECTRAL, AGGREGATION AND FLUORESCENCE AND IMPROVED PHOTOPHYSICAL PROPERTIES OF (ethylsulfanyl) PORPHYRAZINES CONTAINING β-THIOETHER APPENDED [(bpy)2RuCl2]. SIGMA. 2018;36(2):487-99.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK https://eds.yildiz.edu.tr/sigma/