Abstract
Bu çalışmada, Maleik
Anhidrit (MA) ve vinil Pivalat (VP)’ın birbirleri ile reaksiyona girebilme
yeteneğinin ve kopolimer yapısındaki dizilimlerinin belirlenebilmesi için
VP-ko-MA kopolimeri farklı besleme oranlarında çalışılarak sentezlenmiştir.
Sentezlenen VP-ko-MA kopolimer yapısının aydınlatılabilmesi için kızılötesi
(FT-IR) ve nükleer manyetik rezonans spektroskopilerinden (1H-NMR)
ve jel geçirgenlik kromotografisinden yararlanılmıştır. Ayrıca sentezlemiş olan
VP-ko-MA kopolimerinin volumetrik olarak asit sayıları, titrimetrik yöntemle
Kohezif Enerji Yoğunluğu (KEY) değerleri bulunmuştur. Kopolimer bileşimindeki
monomerlerin mol fraksiyonlarının FT-IR ve 1H-NMR spektroskopisi
yardımıyla tayini yapılmış olup Fineman-Ross ve Kelen-Tüdos metotları
yardımıyla da VP-ko-MA kopolimerinin reaktivite oranları belirlenmiştir.
References
- Boztuğ A, Zengin HB, Basan S (2004). Thermomechanical and Thermogravimetric Analysis of Blends of poly (Vinyl Chloride) (PVC) with Maleic Anhydride–Allyl Propionate Copolymer. Journal of Molecular Structure 697: 61–64.Bunck DN, Sorenson GP, Mahanthappa MK (2011). Cobalt-Mediated Radical Polymerization Routes to Poly(vinyl ester) Block Copolymers. Journal of Polymer Science: Part A: Polymer Chemistry 49: 242–249.Ciardelli F, Carlini C, Pertici P, Valentini G (1989). Polymer effect on catalyses by macromolecules transition metal complexes. Journal of Macromoleculer Science-Chemistry 26 (2-3): 327-347.Ekberov OH, Basan S, (1995). Polimer Kimyası Laboratuvarı (1.Baskı). Cumhuriyet Üniversitesi Yayınları No: 58, SivasGöksel C, Hacıoğlu B, Akbulut U (1997). Spontaneous Copolymerization of Maleic Anhydride and N-Vinylimidazole in 1,4-Dioxane. I. Charge Transfer Complexation and Kinetics of the Copolymerization. Journal of Polymer Science 35: 3735–3743.Guang WL, Jiang-nan, S, Huan-lin C, Cong-jie G, (2006). CO2 Facilitated Transport Through an Acrylamide and Maleic Anhydride Copolymer Membrane. Desalination 193: 313–320.Lyoo WS, Han SS, Kim JH, Yoon WS, Lee CJ, Kwon IC, Lee J, Ji BC, Han MH, (1999). Bulk polymerization of vinyl pivalate using low-temperature azoinitiator and saponification for the preparation of poly(vinyl alcohol) microfibrils. Die Angewandte Makromolekulare Chemie 271: 46–52.Ezio M, Pellegrino M, Giuseppe R, Gennaro S (1996). A polymer Network of unsaturate polyester and bismaleimide resin: 1.kineticks, mechanism and molecular structure. Polymer 37 (18): 4025-4032.Okudan A. (1998). Blok Polistirenin Katyonik Katalizörler Ortamında Maleik Anhidritle Kimyasal Modifikasyonun ve Kullanım Alanlarının İncelenmesi. Doktora Tezi, S.Ü. Fen Bilimleri Enstitüsü, Konya. Okudan A, Karasakal A (2013) The effect of H-bonding on radical copolymerization of Maleic anhydride with N-tert-Butylacrylamide and its characterization. International Journal of Polymer Science 2013: 1-9.Rzaev ZMO, Dincer S, Koseli V, Kesim H, Piskin E (2002). Radical copolymerization of N-isopropylacrylamide with anhydrides of maleic and citraconic acids. European Polymer Journal 38: 2143–2152.Rzaev ZMO, Kahraman G, Beşkardeş O, Pişkin E (2004). Bioengineering polyfunctional copolymers. VII. Synthesis and characterization of copolymers of p-vinylphenyl boronic acid with maleic and citraconic anhydrides and their self-assembled macrobranched supramolecular architectures. Science Direct Polymer 45: 5813-5828.Sebe G, Jebrane M (2008). A new process for the esterification of wood by reaction with vinyl esters. Carbohydrate Polymers 72: 657–663Scott MH, El Sayed MEH, Pirie CM, Hoffman AS, Stayton PS (2006). pH-Responsive Poly(styrene-alt-maleic anhydride) Alkylamide Copolymers for Intracellular Drug Delivery. Biomacromolecules 7: 2407-2414,Tanıhara M, Suzukı Y, Nıshımura Y, Suzukı K, Kakımaru Y. and Fukunushı Y (1999). A Novel Microbial Infection-Responsive Drug Release System. Journal of Pharmaceutical Sciences 88 (5): 510-514.Turner C, Ovaskainena L, Irene RM, Birkin NA, Howdle SM, Geddea U, LarsWågberg (2013). Towards superhydrophobic coatings made by non-fluorinated polymers sprayed from a supercritical solution. The Journal of Supercritical Fluids 77: 134–141.
Abstract
In this study, VP-ko-MA
copolymer was synthesized by studying at different feed ratios to determine the
order of the copolymer structure and the ability to react with Vinyl Pivalate
(VP) of maleic anhydride (MA). The structures of the synthesized VP-co-MA
copolymers were elucidate by FT-IR and 1H-NMR spectroscopy and gel
permeation chromatography. In addition, Cohesive Energy Density (KEY) values
with titrimetric method and acid numbers as volumetric of the synthesized
VP-co-MA copolymers were determined. The mole fractions of the monomers in the
copolymer composition were determined by FT-IR and 1H-NMR
spectroscopy and the reactivity ratios of VP-co-MA copolymer were determined by
Fineman-Ross and Kelen-Tudos methods.
References
- Boztuğ A, Zengin HB, Basan S (2004). Thermomechanical and Thermogravimetric Analysis of Blends of poly (Vinyl Chloride) (PVC) with Maleic Anhydride–Allyl Propionate Copolymer. Journal of Molecular Structure 697: 61–64.Bunck DN, Sorenson GP, Mahanthappa MK (2011). Cobalt-Mediated Radical Polymerization Routes to Poly(vinyl ester) Block Copolymers. Journal of Polymer Science: Part A: Polymer Chemistry 49: 242–249.Ciardelli F, Carlini C, Pertici P, Valentini G (1989). Polymer effect on catalyses by macromolecules transition metal complexes. Journal of Macromoleculer Science-Chemistry 26 (2-3): 327-347.Ekberov OH, Basan S, (1995). Polimer Kimyası Laboratuvarı (1.Baskı). Cumhuriyet Üniversitesi Yayınları No: 58, SivasGöksel C, Hacıoğlu B, Akbulut U (1997). Spontaneous Copolymerization of Maleic Anhydride and N-Vinylimidazole in 1,4-Dioxane. I. Charge Transfer Complexation and Kinetics of the Copolymerization. Journal of Polymer Science 35: 3735–3743.Guang WL, Jiang-nan, S, Huan-lin C, Cong-jie G, (2006). CO2 Facilitated Transport Through an Acrylamide and Maleic Anhydride Copolymer Membrane. Desalination 193: 313–320.Lyoo WS, Han SS, Kim JH, Yoon WS, Lee CJ, Kwon IC, Lee J, Ji BC, Han MH, (1999). Bulk polymerization of vinyl pivalate using low-temperature azoinitiator and saponification for the preparation of poly(vinyl alcohol) microfibrils. Die Angewandte Makromolekulare Chemie 271: 46–52.Ezio M, Pellegrino M, Giuseppe R, Gennaro S (1996). A polymer Network of unsaturate polyester and bismaleimide resin: 1.kineticks, mechanism and molecular structure. Polymer 37 (18): 4025-4032.Okudan A. (1998). Blok Polistirenin Katyonik Katalizörler Ortamında Maleik Anhidritle Kimyasal Modifikasyonun ve Kullanım Alanlarının İncelenmesi. Doktora Tezi, S.Ü. Fen Bilimleri Enstitüsü, Konya. Okudan A, Karasakal A (2013) The effect of H-bonding on radical copolymerization of Maleic anhydride with N-tert-Butylacrylamide and its characterization. International Journal of Polymer Science 2013: 1-9.Rzaev ZMO, Dincer S, Koseli V, Kesim H, Piskin E (2002). Radical copolymerization of N-isopropylacrylamide with anhydrides of maleic and citraconic acids. European Polymer Journal 38: 2143–2152.Rzaev ZMO, Kahraman G, Beşkardeş O, Pişkin E (2004). Bioengineering polyfunctional copolymers. VII. Synthesis and characterization of copolymers of p-vinylphenyl boronic acid with maleic and citraconic anhydrides and their self-assembled macrobranched supramolecular architectures. Science Direct Polymer 45: 5813-5828.Sebe G, Jebrane M (2008). A new process for the esterification of wood by reaction with vinyl esters. Carbohydrate Polymers 72: 657–663Scott MH, El Sayed MEH, Pirie CM, Hoffman AS, Stayton PS (2006). pH-Responsive Poly(styrene-alt-maleic anhydride) Alkylamide Copolymers for Intracellular Drug Delivery. Biomacromolecules 7: 2407-2414,Tanıhara M, Suzukı Y, Nıshımura Y, Suzukı K, Kakımaru Y. and Fukunushı Y (1999). A Novel Microbial Infection-Responsive Drug Release System. Journal of Pharmaceutical Sciences 88 (5): 510-514.Turner C, Ovaskainena L, Irene RM, Birkin NA, Howdle SM, Geddea U, LarsWågberg (2013). Towards superhydrophobic coatings made by non-fluorinated polymers sprayed from a supercritical solution. The Journal of Supercritical Fluids 77: 134–141.
Details
| Primary Language | Turkish |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | April 30, 2019 |
| Submission Date | August 13, 2018 |
| Published in Issue | Year 2019 Volume: 45 Issue: 1 |
Cite
Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Hüseyin YILMAZ
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.
It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" since 2009.
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