Theoretical Investigation of Temperature Effect on the Formation of Sulphuric Acid Rain

Year 2017, Volume: 1 Issue: 1, 11 - 16, 15.06.2017

Koray Sayın Duran Karakaş

Abstract

The
acid rain is a major problem for life and environment. Mainly, acid rain
consists from sulfuric acid and nitric acid. There are five successive reaction
for the formation of sulfuric acid. All reactions have been investigated
experimentally but some properties of them have not been defined clearly. In this
study, mechanisms of each reaction were predicted. The temperature effect on activation
energy, equilibrium constant and rate constant were investigated for each
reaction. The effect of global warming on the formation of sulphuric acid rain
was discussed.

Keywords

Acid rain, Sulfuric acid, Atmospheric reactions, Theoretical study, Global Warming

References

• A. A. N. Patrinos, M. J. Leach, R. M. Brown, Journal of Applied Meteorology 28 (1989) 948-968.
• C. Anatolaki, R. Tsitouridou, Atmospheric Research 92 (2009) 100-113.
• X. Zhang, H. Jiang, J. Jin, X. Xu, Q. Zhang, Atmospheric Environment 46 (2012) 590-596.
• J. C. Nam, S. N. Oh, J. C. Choi, J. Kim, Y. Chun, Water, Air and Soil Pollution 130 (2001) 433-438.
• C. C. Lin, X. M. Lin, Y. Zou,L. Zhang, Journal of Tropical Meteorology 21 (2005) 330-336.
• A. K. Singh, G. C. Mondal, S. Kumar, K. K. Singh, K. P. Kamal, A. Sinha, Environmental Monitoring and Assessment 125 (2007) 99-110.
• T. A. Hill, A. Jones, T. W. Choularton, Quarterly Journal of the Royal Meteorological Society 113 (1987) 1217-1236.
• T. W. Choularton, M. J. Gay, A. Jones, D. Fowler, J. N. Cape, I. D. Leith, Atmospheric Environment 22 (1988) 1363-1371.
• G. Sumner, Precipitation Process and Analysis. John Wiley, 1988 New York.
• J. W. Grimm, J. A. Lynch, Environmental Monitoring and Assessment 90 (2004) 243-268.
• S. V. Ollinger, J. D. Aber, G. M. Lovett, S. E. Millham, R. G. Lathrop, J. M. Ellis, Ecological Applications 3 (1993) 459-472.
• M. Ito, M. J. Mitchell, C. T. Driscoll, Atmospheric Environment 36 (2002) 1051-1062.
• J. P. Hutton, G. E. Halkos, Energy Economics 17 (1995) 259-275.
• L. Hordijk, C. Kroeze, Eur. J. Oper. Res. 102 (1997) 405-417.
• J. W. Park, S. Y. Cho, Atmospheric Environment 32 (1998) 2745-2756.
• B. He, X. Zheng, Y. Wen, H. Tong, M. Chen, C. Chen, J. Energy. Convers. Manage. 44 (2003) 2175-2188.
• V. Eyring, I. S. A. Isaksen, T. Berntsen, W. J. Collins, J. J. Corbett, O. Endresen, R. G. Grainger, J. Moldanova, H. Schlager,D. S. Stevenson, Atmospheric Environment 44 (2010) 4735-4771.
• R. Atkinson, D. L. Baulch, R. A. Cox, R. F. Hampson, J. A. Kerr, M. J. Rossi, J. Troe, J. Phys. Chem. Ref. Data 26 (1997) 521-1011.
• R. W. Fair, B. A. Thrush, Trans. Faraday Soc. 65 (1969) 1557-1570.
• R. W. Fair, A. V. Roodselaar, O. P. Strausz, Can. J. Chem. 49 (1971) 1659-1664.
• D. D. Davis, R. B. Klemm, M. J. Pilling, Int. J. Chem. Kinet. 4 (1972) 367-382.
• R. J. Donovan, D. J. Little, Chem. Phys. Lett. 13 (1972) 488-490.
• M. A. A. Clyne, P. D. Whitefield, J. Chem. Soc. Faraday Trans. 275 (1979) 1327-1340.
• G. Black, R. T. Shrapless, T. G. Slanger, Chem. Phys. Lett. 90 (1982) 55-58.
• G. Black, R. T. Shrapless, T. G. Slanger, Chem. Phys. Lett. 90 (1982) 598-602.
• Y. Y. Lee, W. C. Kao, Y. P. Lee, J. Phys. Chem. 94 (1990) 4535-4540.
• J. J. Margitan, J. Phys. Chem. 88 (1984) 3314-3318.
• D. Martin, J. L. Jourdain, G. Le Bras, J. Phys. Chem. 90 (1986) 4143-4147.
• J. F. Gleason, A. Sinha, C. J. Howard, J. Phys. Chem. 91 (1987) 719-724.
• J. F. Gleason, C. J. Howard, J. Phys. Chem. 92 (1988) 3414-3417.
• Dennington II R.D., Keith T.A., Millam J.M., 2009. Gaussview 5.0, Wallingford, CT, USA.
• Gaussian 09, Revision D.01, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, Ö. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, and D. J. Fox, Gaussian, Inc., Wallingford CT, 2009.
• J. Baker, J. Comp. Chem. 7 (1986) 385-389.
• C. Doubleday, J. Mclver, M. Page, T. Zielinski, 1985. J. American Chem. Society 107 (1985) 5800-5801.
• R. H. Petrucci, W. S. Harwood, F. G. Herring, edt: T. Uyar, S. Aksoy, Genel Kimya 2. Palme Yayıncılık, 2005 ANKARA.