Elektrokimyasal yöntemle Visinal trans-1,2-Dibromür bileşiklerinden Alken sentezi

Latif Kelebekli; Yunus Kara

Research Article

Synthesis of Alkenes from Vicinal trans-1,2-Dibromide compounds by electrochemical methods

Year 2017, Volume: 6 Issue: 2, 7 - 10, 16.12.2017

Latif Kelebekli , Yunus Kara

Abstract

In this work, alkene
synthesis was carried out by electrochemical reduction of compounds having a
bicyclic ring system. The required starting compounds were prepared the
endoperoxide and trans-7,8-dibromo-cis-2,5-dihydroxybicyclo [4.2.0]
octa-3-ene using synthetic methods. Electrochemical reduction method was
applied to these compounds and obtained the cis-2,5-diacetoxy-bicyclo
[4.2.0] octa-3,7-diene and bicyclo [4.2.0] octa-3,7-diene. The structures of
all compounds obtained were determined using spectroscopic techniques (FT-IR, ¹H-¹³C-NMR).

Keywords

Electrochemical reduction, cathodic reduction

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