Research Article
BibTex RIS Cite

The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement

Year 2022, Volume: 33 Issue: 4, 12143 - 12162, 01.07.2022
https://doi.org/10.18400/tekderg.761208

Abstract

The current study focuses on the effect of Acrylate-styrene-acrylonitrile (ASA)/Nanosilica (Si) modified binders on the complex modulus (G*) and rutting resistance parameters (G*/ sinδ) of Asphalt Cement (AC). Four different blends including the base binder and the polymer nanocomposites which were formed by blending 5% ASA to base binder with the addition of nanosilica at 3, 5 and 7% by the weight were the subject of investigations. Conventional and Dynamic Shear Rheometer (DSR) testing procedures were conducted as well as morphology analysis using Fourier Transform Infrared Spectroscopy (FT-IR). The rheological characteristics of AC were analysed by master curves, isochronal plots and rutting resistance parameter plots. Test results revealed that G* and G*/ sinδ of all modified samples were significantly enhanced compared to the base binder. Multiple Stress Creep Recovery Test (MSCRT) conducted at 100 Pa and 3200 Pa showed that, non-recoverable compliance was reduced and elastic recovery of modified binders were improved. Optimum concentration was found to be 5% ASA/Si composite, as further addition of polymer nanocomposite resulted in lower enhancement in the rheological properties of modified AC due to the occurrence of agglomeration between the composite and the base binder.

Supporting Institution

-

Project Number

-

Thanks

-

References

  • [1] Ahmed AW, Said SF, Lu X, Carlsson H. Pavement performance follow-up and evaluation of polymer-modified test sections. International Journal of Pavement Engineering. 2019;20(12):1474-87.
  • [2] Al-Mansob RA, Ismail A, Yusoff NIM, Albrka SI, Azhari CH, Karim MR. Rheological characteristics of unaged and aged epoxidised natural rubber modified asphalt. Construction and Building Materials. 2016;102:190-9.
  • [3] Mahali I, Sahoo UC. Rheological characterization of Nanocomposite modified asphalt binder. International Journal of Pavement Research and Technology. 2019;12(6):589-94.
  • [4] Crucho J, Picado-Santos L, Neves J, Capitão S. A Review of Nanomaterials’ Effect on Mechanical Performance and Aging of Asphalt Mixtures. Applied Sciences. 2019;9(18):3657.
  • [5] Ponniah J, Kennepohl G. Polymer-modified asphalt pavements in Ontario: Performance and cost-effectiveness. Transportation research record. 1996;1545(1):151-60.
  • [6] Porto M, Caputo P, Loise V, Eskandarsefat S, Teltayev B, Oliviero Rossi C. Bitumen and bitumen modification: A review on latest advances. Applied Sciences. 2019;9(4):742.
  • [7] Ameri M, Mansourian A, Sheikhmotevali AH. Investigating effects of ethylene vinyl acetate and gilsonite modifiers upon performance of base bitumen using Superpave tests methodology. Construction and Building Materials. 2012;36:1001-7.
  • [8] Brovelli C, Hilliou L, Hemar Y, Pais J, Pereira P, Crispino M. Rheological characteristics of EVA modified bitumen and their correlations with bitumen concrete properties. Construction and Building Materials. 2013;48:1202-8.
  • [9] Garcia-Morales M, Partal P, Navarro F, Gallegos C. Effect of waste polymer addition on the rheology of modified bitumen. Fuel. 2006;85(7-8):936-43.
  • [10] Garcı́a-Morales M, Partal P, Navarro F, Martı́nez-Boza F, Gallegos C, González N, et al. Viscous properties and microstructure of recycled eva modified bitumen. Fuel. 2004;83(1):31-8.
  • [11] Yuanita E, Hendrasetyawan B, Firdaus D, Chalid M, editors. Improvement of polypropylene (PP)-modified bitumen through lignin addition. IOP Conf Ser Mater Sci Eng; 2017.
  • [12] Bala N, Napiah M, Kamaruddin I, Danlami N. Rheological properties investigation of bitumen modified with nanosilica and polyethylene polymer. International Journal of Advanced and Applied Sciences. 2017;4(10):165-74.
  • [13] Brasileiro L, Moreno-Navarro F, Tauste-Martínez R, Matos J, Rubio-Gámez MdC. Reclaimed polymers as asphalt binder modifiers for more sustainable roads: A review. Sustainability. 2019;11(3):646.
  • [14] Kok BV, Yilmaz M, Sengoz B, Sengur A, Avci E. Investigation of complex modulus of base and SBS modified bitumen with artificial neural networks. Expert Systems with Applications. 2010;37(12):7775-80.
  • [15] Zorn S, Mehta Y, Dahm K, Batten E, Nolan A, Dusseau R. Rheological properties of the polymer modified bitumen with emphasis on SBS polymer and its microstructure. Road Materials and New Innovations in Pavement Engineering2011. p. 41-8.
  • [16] Pyshyev S, Gunka V, Grytsenko Y, Bratychak M. Polymer modified bitumen. Chemistry & Chemical Technology. 2016(10,№ 4 (s)):631-6.
  • [17] Ali SIA, Ismail A, Yusoff NIM, Karim MR, Al-Mansob RA, Alhamali DI. Physical and rheological properties of acrylate–styrene–acrylonitrile modified asphalt cement. Construction and Building Materials. 2015;93:326-34.
  • [18] Airey GD. Rheological properties of styrene butadiene styrene polymer modified road bitumens☆. Fuel. 2003;82(14):1709-19.
  • [19] Fernandes MRS, Forte MMC, Leite LFM. Rheological evaluation of polymer-modified asphalt binders. Materials research. 2008;11(3):381-6.
  • [20] Rossi CO, Spadafora A, Teltayev B, Izmailova G, Amerbayev Y, Bortolotti V. Polymer modified bitumen: Rheological properties and structural characterization. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2015;480:390-7.
  • [21] Galooyak SS, Dabir B, Nazarbeygi AE, Moeini A. Rheological properties and storage stability of bitumen/SBS/montmorillonite composites. Construction and Building Materials. 2010;24(3):300-7.
  • [22] Polacco G, Filippi S, Merusi F, Stastna G. A review of the fundamentals of polymer-modified asphalts: Asphalt/polymer interactions and principles of compatibility. Advances in colloid and interface science. 2015;224:72-112.
  • [23] Yildirim Y. Polymer modified asphalt binders. Construction and Building Materials. 2007;21(1):66-72.
  • [24] Al-Mansob RA, Ismail A, Rahmat RAO, Borhan MN, Alsharef JM, Albrka SI, et al. The performance of epoxidised natural rubber modified asphalt using nano-alumina as additive. Construction and Building Materials. 2017;155:680-7.
  • [25] Lu X, Isacsson U, Ekblad J. Phase separation of SBS polymer modified bitumens. Journal of Materials in Civil Engineering. 1999;11(1):51-7.
  • [26] Bhargava S, Raghuwanshi AK, Gupta P. Nanomaterial Compatibility and Effect on Properties of Base Bitumen Binder and Polymer Modified Bitumen. IJISET-International Journal of Innovative Science, Engineering & Technology. 2016;3(6):276-82.
  • [27] de Mello Donegá C. The Nanoscience Paradigm:“Size Matters!”. Nanoparticles: Springer; 2014. p. 1-12.
  • [28] Yang J, Tighe S. A review of advances of nanotechnology in asphalt mixtures. Procedia-Social and Behavioral Sciences. 2013;96:1269-76.
  • [29] Ziari H, Farahani H, Goli A, Akbari T. The effect of carbon nano-tube on the fatigue life of asphalt mixtures. International Journal of Transportation Engineering. 2014;2(1):81-96.
  • [30] Sadeghpour Galooyak S, Palassi M, Goli A, Zanjirani Farahani H. Performance evaluation of nano-silica modified bitumen. International Journal of Transportation Engineering. 2015;3(1):55-66.
  • [31] Jahromi SG, Khodaii A. Effects of nanoclay on rheological properties of bitumen binder. Construction and building materials. 2009;23(8):2894-904.
  • [32] Arabani M, Faramarzi M. Characterization of CNTs-modified HMA’s mechanical properties. Construction and Building Materials. 2015;83:207-15.
  • [33] Ziari H, Amini A, Goli A, Mirzaiyan D. Predicting rutting performance of carbon nano tube (CNT) asphalt binders using regression models and neural networks. Construction and Building Materials. 2018;160:415-26.
  • [34] You Z, Mills-Beale J, Foley JM, Roy S, Odegard GM, Dai Q, et al. Nanoclay-modified asphalt materials: Preparation and characterization. Construction and Building Materials. 2011;25(2):1072-8.
  • [35] Yao H, You Z, Li L, Lee CH, Wingard D, Yap YK, et al. Rheological properties and chemical bonding of asphalt modified with nanosilica. Journal of Materials in Civil Engineering. 2013;25(11):1619-30.
  • [36] Arabani M, Haghi A, Tanzadeh R, editors. Laboratory study on the effect of Nano-SiO2 on improvement fatigue performance of aged asphalt pavement. 4th International Conference on Nanostructures, Kish Island, IR Iran; 2012.
  • [37] Bala N, Napiah M, Kamaruddin I. Effect of nanosilica particles on polypropylene polymer modified asphalt mixture performance. Case studies in construction materials. 2018;8:447-54.
  • [38] Bala N, Kamaruddin I, Napiah M, Danlami N, editors. Rheological and rutting evaluation of composite nanosilica/polyethylene modified bitumen. Proceedings of the 7th International Conference on Key Engineering Materials (ICKEM 2017) held between 11th to 13th March; 2017.
  • [39] Rezaei S, Ziari H, Nowbakht S. Low temperature functional analysis of bitumen modified with composite of nano-SiO2 and styrene butadiene styrene polymer. Petroleum Science and Technology. 2016;34(5):415-21.
  • [40] Ehinola OA, Falode OA, Jonathan G. Softening point and Penetration Index of bitumen from parts of Southwestern Nigeria. Nafta. 2012;63(9-10):319-23.
  • [41] Yan C, Huang W, Tang N. Evaluation of the temperature effect on Rolling Thin Film Oven aging for polymer modified asphalt. Construction and Building Materials. 2017;137:485-93.
  • [42] Yin F, Moraes PR. Storage Stability Testing of Asphalt Binders Containing Recycled Polyethylene Materials. Phase II-A Study Report, Prepared for the Plastics Industry Association; 2018.
  • [43] Abutalib N, Fini EH, Aflaki S, Abu-Lebdeh TM. Investigating effects of application of silica fume to reduce asphalt oxidative aging. American Journal of Engineering and Applied Sciences. 2015;8(1):176-84.
  • [44] Yusoff NIM, Alhamali DI, Ibrahim ANH, Rosyidi SAP, Hassan NA. Engineering characteristics of nanosilica/polymer-modified bitumen and predicting their rheological properties using multilayer perceptron neural network model. Construction and Building Materials. 2019;204:781-99.

The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement

Year 2022, Volume: 33 Issue: 4, 12143 - 12162, 01.07.2022
https://doi.org/10.18400/tekderg.761208

Abstract

The current study focuses on the effect of Acrylate-styrene-acrylonitrile (ASA)/Nanosilica (Si) modified binders on the complex modulus (G*) and rutting resistance parameters (G*/ sinδ) of Asphalt Cement (AC). Four different blends including the base binder and the polymer nanocomposites which were formed by blending 5% ASA to base binder with the addition of nanosilica at 3, 5 and 7% by the weight were the subject of investigations. Conventional and Dynamic Shear Rheometer (DSR) testing procedures were conducted as well as morphology analysis using Fourier Transform Infrared Spectroscopy (FT-IR). The rheological characteristics of AC were analysed by master curves, isochronal plots and rutting resistance parameter plots. Test results revealed that G* and G*/ sinδ of all modified samples were significantly enhanced compared to the base binder. Multiple Stress Creep Recovery Test (MSCRT) conducted at 100 Pa and 3200 Pa showed that, non-recoverable compliance was reduced and elastic recovery of modified binders were improved. Optimum concentration was found to be 5% ASA/Si composite, as further addition of polymer nanocomposite resulted in lower enhancement in the rheological properties of modified AC due to the occurrence of agglomeration between the composite and the base binder.

Project Number

-

References

  • [1] Ahmed AW, Said SF, Lu X, Carlsson H. Pavement performance follow-up and evaluation of polymer-modified test sections. International Journal of Pavement Engineering. 2019;20(12):1474-87.
  • [2] Al-Mansob RA, Ismail A, Yusoff NIM, Albrka SI, Azhari CH, Karim MR. Rheological characteristics of unaged and aged epoxidised natural rubber modified asphalt. Construction and Building Materials. 2016;102:190-9.
  • [3] Mahali I, Sahoo UC. Rheological characterization of Nanocomposite modified asphalt binder. International Journal of Pavement Research and Technology. 2019;12(6):589-94.
  • [4] Crucho J, Picado-Santos L, Neves J, Capitão S. A Review of Nanomaterials’ Effect on Mechanical Performance and Aging of Asphalt Mixtures. Applied Sciences. 2019;9(18):3657.
  • [5] Ponniah J, Kennepohl G. Polymer-modified asphalt pavements in Ontario: Performance and cost-effectiveness. Transportation research record. 1996;1545(1):151-60.
  • [6] Porto M, Caputo P, Loise V, Eskandarsefat S, Teltayev B, Oliviero Rossi C. Bitumen and bitumen modification: A review on latest advances. Applied Sciences. 2019;9(4):742.
  • [7] Ameri M, Mansourian A, Sheikhmotevali AH. Investigating effects of ethylene vinyl acetate and gilsonite modifiers upon performance of base bitumen using Superpave tests methodology. Construction and Building Materials. 2012;36:1001-7.
  • [8] Brovelli C, Hilliou L, Hemar Y, Pais J, Pereira P, Crispino M. Rheological characteristics of EVA modified bitumen and their correlations with bitumen concrete properties. Construction and Building Materials. 2013;48:1202-8.
  • [9] Garcia-Morales M, Partal P, Navarro F, Gallegos C. Effect of waste polymer addition on the rheology of modified bitumen. Fuel. 2006;85(7-8):936-43.
  • [10] Garcı́a-Morales M, Partal P, Navarro F, Martı́nez-Boza F, Gallegos C, González N, et al. Viscous properties and microstructure of recycled eva modified bitumen. Fuel. 2004;83(1):31-8.
  • [11] Yuanita E, Hendrasetyawan B, Firdaus D, Chalid M, editors. Improvement of polypropylene (PP)-modified bitumen through lignin addition. IOP Conf Ser Mater Sci Eng; 2017.
  • [12] Bala N, Napiah M, Kamaruddin I, Danlami N. Rheological properties investigation of bitumen modified with nanosilica and polyethylene polymer. International Journal of Advanced and Applied Sciences. 2017;4(10):165-74.
  • [13] Brasileiro L, Moreno-Navarro F, Tauste-Martínez R, Matos J, Rubio-Gámez MdC. Reclaimed polymers as asphalt binder modifiers for more sustainable roads: A review. Sustainability. 2019;11(3):646.
  • [14] Kok BV, Yilmaz M, Sengoz B, Sengur A, Avci E. Investigation of complex modulus of base and SBS modified bitumen with artificial neural networks. Expert Systems with Applications. 2010;37(12):7775-80.
  • [15] Zorn S, Mehta Y, Dahm K, Batten E, Nolan A, Dusseau R. Rheological properties of the polymer modified bitumen with emphasis on SBS polymer and its microstructure. Road Materials and New Innovations in Pavement Engineering2011. p. 41-8.
  • [16] Pyshyev S, Gunka V, Grytsenko Y, Bratychak M. Polymer modified bitumen. Chemistry & Chemical Technology. 2016(10,№ 4 (s)):631-6.
  • [17] Ali SIA, Ismail A, Yusoff NIM, Karim MR, Al-Mansob RA, Alhamali DI. Physical and rheological properties of acrylate–styrene–acrylonitrile modified asphalt cement. Construction and Building Materials. 2015;93:326-34.
  • [18] Airey GD. Rheological properties of styrene butadiene styrene polymer modified road bitumens☆. Fuel. 2003;82(14):1709-19.
  • [19] Fernandes MRS, Forte MMC, Leite LFM. Rheological evaluation of polymer-modified asphalt binders. Materials research. 2008;11(3):381-6.
  • [20] Rossi CO, Spadafora A, Teltayev B, Izmailova G, Amerbayev Y, Bortolotti V. Polymer modified bitumen: Rheological properties and structural characterization. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2015;480:390-7.
  • [21] Galooyak SS, Dabir B, Nazarbeygi AE, Moeini A. Rheological properties and storage stability of bitumen/SBS/montmorillonite composites. Construction and Building Materials. 2010;24(3):300-7.
  • [22] Polacco G, Filippi S, Merusi F, Stastna G. A review of the fundamentals of polymer-modified asphalts: Asphalt/polymer interactions and principles of compatibility. Advances in colloid and interface science. 2015;224:72-112.
  • [23] Yildirim Y. Polymer modified asphalt binders. Construction and Building Materials. 2007;21(1):66-72.
  • [24] Al-Mansob RA, Ismail A, Rahmat RAO, Borhan MN, Alsharef JM, Albrka SI, et al. The performance of epoxidised natural rubber modified asphalt using nano-alumina as additive. Construction and Building Materials. 2017;155:680-7.
  • [25] Lu X, Isacsson U, Ekblad J. Phase separation of SBS polymer modified bitumens. Journal of Materials in Civil Engineering. 1999;11(1):51-7.
  • [26] Bhargava S, Raghuwanshi AK, Gupta P. Nanomaterial Compatibility and Effect on Properties of Base Bitumen Binder and Polymer Modified Bitumen. IJISET-International Journal of Innovative Science, Engineering & Technology. 2016;3(6):276-82.
  • [27] de Mello Donegá C. The Nanoscience Paradigm:“Size Matters!”. Nanoparticles: Springer; 2014. p. 1-12.
  • [28] Yang J, Tighe S. A review of advances of nanotechnology in asphalt mixtures. Procedia-Social and Behavioral Sciences. 2013;96:1269-76.
  • [29] Ziari H, Farahani H, Goli A, Akbari T. The effect of carbon nano-tube on the fatigue life of asphalt mixtures. International Journal of Transportation Engineering. 2014;2(1):81-96.
  • [30] Sadeghpour Galooyak S, Palassi M, Goli A, Zanjirani Farahani H. Performance evaluation of nano-silica modified bitumen. International Journal of Transportation Engineering. 2015;3(1):55-66.
  • [31] Jahromi SG, Khodaii A. Effects of nanoclay on rheological properties of bitumen binder. Construction and building materials. 2009;23(8):2894-904.
  • [32] Arabani M, Faramarzi M. Characterization of CNTs-modified HMA’s mechanical properties. Construction and Building Materials. 2015;83:207-15.
  • [33] Ziari H, Amini A, Goli A, Mirzaiyan D. Predicting rutting performance of carbon nano tube (CNT) asphalt binders using regression models and neural networks. Construction and Building Materials. 2018;160:415-26.
  • [34] You Z, Mills-Beale J, Foley JM, Roy S, Odegard GM, Dai Q, et al. Nanoclay-modified asphalt materials: Preparation and characterization. Construction and Building Materials. 2011;25(2):1072-8.
  • [35] Yao H, You Z, Li L, Lee CH, Wingard D, Yap YK, et al. Rheological properties and chemical bonding of asphalt modified with nanosilica. Journal of Materials in Civil Engineering. 2013;25(11):1619-30.
  • [36] Arabani M, Haghi A, Tanzadeh R, editors. Laboratory study on the effect of Nano-SiO2 on improvement fatigue performance of aged asphalt pavement. 4th International Conference on Nanostructures, Kish Island, IR Iran; 2012.
  • [37] Bala N, Napiah M, Kamaruddin I. Effect of nanosilica particles on polypropylene polymer modified asphalt mixture performance. Case studies in construction materials. 2018;8:447-54.
  • [38] Bala N, Kamaruddin I, Napiah M, Danlami N, editors. Rheological and rutting evaluation of composite nanosilica/polyethylene modified bitumen. Proceedings of the 7th International Conference on Key Engineering Materials (ICKEM 2017) held between 11th to 13th March; 2017.
  • [39] Rezaei S, Ziari H, Nowbakht S. Low temperature functional analysis of bitumen modified with composite of nano-SiO2 and styrene butadiene styrene polymer. Petroleum Science and Technology. 2016;34(5):415-21.
  • [40] Ehinola OA, Falode OA, Jonathan G. Softening point and Penetration Index of bitumen from parts of Southwestern Nigeria. Nafta. 2012;63(9-10):319-23.
  • [41] Yan C, Huang W, Tang N. Evaluation of the temperature effect on Rolling Thin Film Oven aging for polymer modified asphalt. Construction and Building Materials. 2017;137:485-93.
  • [42] Yin F, Moraes PR. Storage Stability Testing of Asphalt Binders Containing Recycled Polyethylene Materials. Phase II-A Study Report, Prepared for the Plastics Industry Association; 2018.
  • [43] Abutalib N, Fini EH, Aflaki S, Abu-Lebdeh TM. Investigating effects of application of silica fume to reduce asphalt oxidative aging. American Journal of Engineering and Applied Sciences. 2015;8(1):176-84.
  • [44] Yusoff NIM, Alhamali DI, Ibrahim ANH, Rosyidi SAP, Hassan NA. Engineering characteristics of nanosilica/polymer-modified bitumen and predicting their rheological properties using multilayer perceptron neural network model. Construction and Building Materials. 2019;204:781-99.
There are 44 citations in total.

Details

Primary Language English
Subjects Civil Engineering
Journal Section Articles
Authors

Mustafa Alas 0000-0002-8988-2008

Ali Albrka This is me 0000-0003-1938-9127

Hüseyin Gökçekuş 0000-0001-5793-4937

Project Number -
Publication Date July 1, 2022
Submission Date June 30, 2020
Published in Issue Year 2022 Volume: 33 Issue: 4

Cite

APA Alas, M., Albrka, A., & Gökçekuş, H. (2022). The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement. Teknik Dergi, 33(4), 12143-12162. https://doi.org/10.18400/tekderg.761208
AMA Alas M, Albrka A, Gökçekuş H. The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement. Teknik Dergi. July 2022;33(4):12143-12162. doi:10.18400/tekderg.761208
Chicago Alas, Mustafa, Ali Albrka, and Hüseyin Gökçekuş. “The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement”. Teknik Dergi 33, no. 4 (July 2022): 12143-62. https://doi.org/10.18400/tekderg.761208.
EndNote Alas M, Albrka A, Gökçekuş H (July 1, 2022) The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement. Teknik Dergi 33 4 12143–12162.
IEEE M. Alas, A. Albrka, and H. Gökçekuş, “The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement”, Teknik Dergi, vol. 33, no. 4, pp. 12143–12162, 2022, doi: 10.18400/tekderg.761208.
ISNAD Alas, Mustafa et al. “The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement”. Teknik Dergi 33/4 (July 2022), 12143-12162. https://doi.org/10.18400/tekderg.761208.
JAMA Alas M, Albrka A, Gökçekuş H. The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement. Teknik Dergi. 2022;33:12143–12162.
MLA Alas, Mustafa et al. “The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement”. Teknik Dergi, vol. 33, no. 4, 2022, pp. 12143-62, doi:10.18400/tekderg.761208.
Vancouver Alas M, Albrka A, Gökçekuş H. The High Temperature Performance Evaluation of Polymer/Nanocomposite Modified Asphalt Cement. Teknik Dergi. 2022;33(4):12143-62.