Research Article
BibTex RIS Cite

Deposition of CdO Semiconductors on yarns by Dip Coating Method and Gas Sensor Applications

Year 2024, , 117 - 126, 30.06.2024
https://doi.org/10.32710/tekstilvekonfeksiyon.1178133

Abstract

Thin films produced by deposition of metal oxides on different surfaces show semi-conductor properties that are sensitive to the surrounding atmosphere components. With their optical, electrical, and structural properties, CdO metal oxides are used in a variety of fields ranging from optoelectronic materials to gas sensors. CdO thin films can be produced by different methods such as spray pyrolysis, SILAR, sol-gel spin coating and dip coating technique. The sol-gel dip coating technique, which is simple, accessible, adjustable, and repeatable based on desired parameters, is widely used in the production of CdO thin films. In this study, CdO metal oxide thin films were coated on polyamide, acrylic and cotton yarns by sol-gel dipping method in three different molarities of 0.1 M, 0.3 M and 0.5 M starting solutions. Structural properties of CdO thin film coated yarn samples were investigated using SEM and EDX analyzes were performed. The sensor tests of the yarn samples for LPG gas were carried out in the specially designed gas sensor measurement system and in the gas chamber. The 0.5 M CdO thin film coated cotton yarn samples showed better semiconductor properties and gas response than the other samples.

References

  • [1] Bulakhe, R. N., and Lokhande, C. D. “Chemically Deposited Cubic Structured CdO Thin Films: Use in Liquefied Petroleum Gas Sensor.” Sensors and Actuators B: Chemical, Vol. 200, 2014, pp. 245–250. https://doi.org/10.1016/J.SNB.2014.04.061.
  • [2] Joshi, G., Rajput, J. K., and Purohit, L. P. “Improved Stability of Gas Sensor by Inclusion of Sb in Nanostructured SnO2 Thin Films Grown on Sodalime.” Journal of Alloys and Compounds, Vol. 830, 2020, p. 154659. https://doi.org/10.1016/J.JALLCOM.2020.154659.
  • [3] Jiang, L., Xue, K., Chen, Z., Cui, Q., and Xu, S. “High Performance of Gas Sensor Based on Bi-Doped ZnSnO3/CuO Nanocomposites for Acetone.” Microporous and Mesoporous Materials, Vol. 329, 2022, p. 111532. https://doi.org/10.1016/J.MICROMESO.2021.111532.
  • [4] Shewale, P. S., and Yun, K. S. “Synthesis and Characterization of Cu-Doped ZnO/RGO Nanocomposites for Room-Temperature H2S Gas Sensor.” Journal of Alloys and Compounds, Vol. 837, 2020, p. 155527. https://doi.org/10.1016/J.JALLCOM.2020.155527.
  • [5] Zhao, Z., Morel, D. L., and Ferekides, C. S. “Electrical and Optical Properties of Tin-Doped CdO Films Deposited by Atmospheric Metalorganic Chemical Vapor Deposition.” Thin Solid Films, Vol. 413, Nos. 1–2, 2002, pp. 203–211. https://doi.org/10.1016/S0040-6090(02)00344-9.
  • [6] Velusamy, P., Xing, R., Babu, R. R., Elangovan, E., Viegas, J., Liu, S., and Sridharan, M. “A Study on Formaldehyde Gas Sensing and Optoelectronic Properties of Bi-Doped CdO Thin Films Deposited by an Economic Solution Process.” Sensors and Actuators B: Chemical, Vol. 297, 2019, p. 126718. https://doi.org/10.1016/J.SNB.2019.126718.
  • [7] Salunkhe, R. R., and Lokhande, C. D. “Effect of Film Thickness on Liquefied Petroleum Gas (LPG) Sensing Properties of SILAR Deposited CdO Thin Films.” Sensors and Actuators B: Chemical, Vol. 129, No. 1, 2008, pp. 345–351. https://doi.org/10.1016/J.SNB.2007.08.035.
  • [8] Salunkhe, R. R., Dhawale, D. S., Dubal, D. P., and Lokhande, C. D. “Sprayed CdO Thin Films for Liquefied Petroleum Gas (LPG) Detection.” Sensors and Actuators B: Chemical, Vol. 140, No. 1, 2009, pp. 86–91. https://doi.org/10.1016/J.SNB.2009.04.046.
  • [9] Rajput, J. K., Pathak, T. K., Kumar, V., Kumar, M., and Purohit, L. P. “Annealing Temperature Dependent Investigations on Nano-Cauliflower like Structure of CdO Thin Film Grown by Sol–Gel Method.” Surfaces and Interfaces, Vol. 6, 2017, pp. 11–17. https://doi.org/10.1016/J.SURFIN.2016.11.005.
  • [10] Saha, B., Thapa, R., and Chattopadhyay, K. K. “Bandgap Widening in Highly Conducting CdO Thin Film by Ti Incorporation through Radio Frequency Magnetron Sputtering Technique.” Solid State Communications, Vol. 145, Nos. 1–2, 2008, pp. 33–37. https://doi.org/10.1016/J.SSC.2007.10.001.
  • [11] Suhail, M. H., Ibrahim, I. M., and Rao, G. M. “Characterization and Gas Sensitivity of Cadmium Oxide Thin Films Prepared by Thermal Evaporation Technique.” Journal of Electron Devices, Vol. 13, 2011, pp. 965–974.
  • [12] Aydemir, S., Köse, S., Selami Kilickaya, M., and Özkan, V. “Influence of Al-Doping on Microstructure and Optical Properties of Sol-Gel Derived CdO Thin Films.” 2014. https://doi.org/10.1016/j.spmi.2014.03.010.
  • [13] Rajput, J. K., Pathak, T. K., Kumar, V., Swart, H. C., and Purohit, L. P. “Tailoring and Optimization of Optical Properties of CdO Thin Films for Gas Sensing Applications.” Physica B: Condensed Matter, Vol. 535, 2018, pp. 314–318. https://doi.org/10.1016/J.PHYSB.2017.08.014.
  • [14] Manickam, K., Muthusamy, V., Manickam, S., Senthil, T. S., Periyasamy, G., and Shanmugam, S. “Effect of Annealing Temperature on Structural, Morphological and Optical Properties of Nanocrystalline TiO2 Thin Films Synthesized by Sol-Gel Dip Coating Method.” Materials Today: Proceedings, Vol. 23, 2019, pp. 68–72. https://doi.org/10.1016/J.MATPR.2019.06.651.
  • [15] Rajput, J. K., Pathak, T. K., Kumar, V., and Purohit, L. P. “Influence of Sol Concentration on CdO Nanostructure with Gas Sensing Application.” Applied Surface Science, Vol. 409, 2017, pp. 8–16. https://doi.org/10.1016/J.APSUSC.2017.03.019.
  • [16] Sankarasubramanian, K., Babu, K. J., Soundarrajan, P., Logu, T., Gnanakumar, G., Ramamurthi, K., Sethuraman, K., and Senthil Kumar, S. M. “A New Catalyst Ti Doped CdO Thin Film for Non-Enzymatic Hydrogen Peroxide Sensor Application.” Sensors and Actuators B: Chemical, Vol. 285, 2019, pp. 164–172. https://doi.org/10.1016/J.SNB.2018.12.161.
  • [17] Deokate, R. J., and Lokhande, C. D. “Liquefied Petroleum Gas Sensing Properties of Sprayed Nanocrystalline Ga-Doped CdO Thin Films.” Sensors and Actuators B: Chemical, Vol. 193, 2014, pp. 89–94. https://doi.org/10.1016/J.SNB.2013.11.060.
  • [18] Nakate, U. T., Patil, P., Ghule, B., Nakate, Y. T., Ekar, S., Ambare, R. C., and Mane, R. S. “Room Temperature LPG Sensing Properties Using Spray Pyrolysis Deposited Nano-Crystalline CdO Thin Films.” Surfaces and Interfaces, Vol. 17, 2019, p. 100339. https://doi.org/10.1016/J.SURFIN.2019.100339.
  • [19] Ziabari, A. A., and Ghodsi, F. E. “Optical and Structural Studies of Sol-Gel Deposited Nanostructured CdO Thin Films: Annealing Effect.” Acta Physica Polonica A, Vol. 120, 2011, pp. 536–540.
  • [20] Choudhary, K., Saini, R., Upadhyay, G. K., and Purohit, L. P. “Sustainable Behavior of Cauliflower like Morphology of Y-Doped ZnO:CdO Nanocomposite Thin Films for CO2 Gas Sensing Application at Low Operating Temperature.” Journal of Alloys and Compounds, Vol. 879, 2021, p. 160479. https://doi.org/10.1016/J.JALLCOM.2021.160479.
  • [21] Prabavathi, A., Balu, A. R., Nagarethinam, V. S., Raja, N., Suganya, M., Usharani, K., Balamurugan, S., Karthika, M., and Kayathiri, C. “Cauliflower Shaped CdO:Mo Nanostructures with Enhanced Photocatalytic Activity against the Degradation of Metanil Yellow Dye.” Nano-Structures & Nano-Objects, Vol. 22, 2020, p. 100458. https://doi.org/10.1016/J.NANOSO.2020.100458.
  • [22] Shanmugavel, G., Balu, A. R., Baskaran, R., and Nagarethinam, V. S. “Realization of Improved Hackee’s Quality Factor and Photo Degradation Efficiency of Cauliflower Shape Nanostructured CdO Thin Films through Cs Doping.” Photonics and Nanostructures - Fundamentals and Applications, Vol. 40, 2020, p. 100784. https://doi.org/10.1016/J.PHOTONICS.2020.100784.
  • [23] Miller, D. R., Akbar, S. A., and Morris, P. A. “Nanoscale Metal Oxide-Based Heterojunctions for Gas Sensing: A Review.” Sensors and Actuators B: Chemical, Vol. 204, 2014, pp. 250–272. https://doi.org/10.1016/J.SNB.2014.07.074.
Year 2024, , 117 - 126, 30.06.2024
https://doi.org/10.32710/tekstilvekonfeksiyon.1178133

Abstract

References

  • [1] Bulakhe, R. N., and Lokhande, C. D. “Chemically Deposited Cubic Structured CdO Thin Films: Use in Liquefied Petroleum Gas Sensor.” Sensors and Actuators B: Chemical, Vol. 200, 2014, pp. 245–250. https://doi.org/10.1016/J.SNB.2014.04.061.
  • [2] Joshi, G., Rajput, J. K., and Purohit, L. P. “Improved Stability of Gas Sensor by Inclusion of Sb in Nanostructured SnO2 Thin Films Grown on Sodalime.” Journal of Alloys and Compounds, Vol. 830, 2020, p. 154659. https://doi.org/10.1016/J.JALLCOM.2020.154659.
  • [3] Jiang, L., Xue, K., Chen, Z., Cui, Q., and Xu, S. “High Performance of Gas Sensor Based on Bi-Doped ZnSnO3/CuO Nanocomposites for Acetone.” Microporous and Mesoporous Materials, Vol. 329, 2022, p. 111532. https://doi.org/10.1016/J.MICROMESO.2021.111532.
  • [4] Shewale, P. S., and Yun, K. S. “Synthesis and Characterization of Cu-Doped ZnO/RGO Nanocomposites for Room-Temperature H2S Gas Sensor.” Journal of Alloys and Compounds, Vol. 837, 2020, p. 155527. https://doi.org/10.1016/J.JALLCOM.2020.155527.
  • [5] Zhao, Z., Morel, D. L., and Ferekides, C. S. “Electrical and Optical Properties of Tin-Doped CdO Films Deposited by Atmospheric Metalorganic Chemical Vapor Deposition.” Thin Solid Films, Vol. 413, Nos. 1–2, 2002, pp. 203–211. https://doi.org/10.1016/S0040-6090(02)00344-9.
  • [6] Velusamy, P., Xing, R., Babu, R. R., Elangovan, E., Viegas, J., Liu, S., and Sridharan, M. “A Study on Formaldehyde Gas Sensing and Optoelectronic Properties of Bi-Doped CdO Thin Films Deposited by an Economic Solution Process.” Sensors and Actuators B: Chemical, Vol. 297, 2019, p. 126718. https://doi.org/10.1016/J.SNB.2019.126718.
  • [7] Salunkhe, R. R., and Lokhande, C. D. “Effect of Film Thickness on Liquefied Petroleum Gas (LPG) Sensing Properties of SILAR Deposited CdO Thin Films.” Sensors and Actuators B: Chemical, Vol. 129, No. 1, 2008, pp. 345–351. https://doi.org/10.1016/J.SNB.2007.08.035.
  • [8] Salunkhe, R. R., Dhawale, D. S., Dubal, D. P., and Lokhande, C. D. “Sprayed CdO Thin Films for Liquefied Petroleum Gas (LPG) Detection.” Sensors and Actuators B: Chemical, Vol. 140, No. 1, 2009, pp. 86–91. https://doi.org/10.1016/J.SNB.2009.04.046.
  • [9] Rajput, J. K., Pathak, T. K., Kumar, V., Kumar, M., and Purohit, L. P. “Annealing Temperature Dependent Investigations on Nano-Cauliflower like Structure of CdO Thin Film Grown by Sol–Gel Method.” Surfaces and Interfaces, Vol. 6, 2017, pp. 11–17. https://doi.org/10.1016/J.SURFIN.2016.11.005.
  • [10] Saha, B., Thapa, R., and Chattopadhyay, K. K. “Bandgap Widening in Highly Conducting CdO Thin Film by Ti Incorporation through Radio Frequency Magnetron Sputtering Technique.” Solid State Communications, Vol. 145, Nos. 1–2, 2008, pp. 33–37. https://doi.org/10.1016/J.SSC.2007.10.001.
  • [11] Suhail, M. H., Ibrahim, I. M., and Rao, G. M. “Characterization and Gas Sensitivity of Cadmium Oxide Thin Films Prepared by Thermal Evaporation Technique.” Journal of Electron Devices, Vol. 13, 2011, pp. 965–974.
  • [12] Aydemir, S., Köse, S., Selami Kilickaya, M., and Özkan, V. “Influence of Al-Doping on Microstructure and Optical Properties of Sol-Gel Derived CdO Thin Films.” 2014. https://doi.org/10.1016/j.spmi.2014.03.010.
  • [13] Rajput, J. K., Pathak, T. K., Kumar, V., Swart, H. C., and Purohit, L. P. “Tailoring and Optimization of Optical Properties of CdO Thin Films for Gas Sensing Applications.” Physica B: Condensed Matter, Vol. 535, 2018, pp. 314–318. https://doi.org/10.1016/J.PHYSB.2017.08.014.
  • [14] Manickam, K., Muthusamy, V., Manickam, S., Senthil, T. S., Periyasamy, G., and Shanmugam, S. “Effect of Annealing Temperature on Structural, Morphological and Optical Properties of Nanocrystalline TiO2 Thin Films Synthesized by Sol-Gel Dip Coating Method.” Materials Today: Proceedings, Vol. 23, 2019, pp. 68–72. https://doi.org/10.1016/J.MATPR.2019.06.651.
  • [15] Rajput, J. K., Pathak, T. K., Kumar, V., and Purohit, L. P. “Influence of Sol Concentration on CdO Nanostructure with Gas Sensing Application.” Applied Surface Science, Vol. 409, 2017, pp. 8–16. https://doi.org/10.1016/J.APSUSC.2017.03.019.
  • [16] Sankarasubramanian, K., Babu, K. J., Soundarrajan, P., Logu, T., Gnanakumar, G., Ramamurthi, K., Sethuraman, K., and Senthil Kumar, S. M. “A New Catalyst Ti Doped CdO Thin Film for Non-Enzymatic Hydrogen Peroxide Sensor Application.” Sensors and Actuators B: Chemical, Vol. 285, 2019, pp. 164–172. https://doi.org/10.1016/J.SNB.2018.12.161.
  • [17] Deokate, R. J., and Lokhande, C. D. “Liquefied Petroleum Gas Sensing Properties of Sprayed Nanocrystalline Ga-Doped CdO Thin Films.” Sensors and Actuators B: Chemical, Vol. 193, 2014, pp. 89–94. https://doi.org/10.1016/J.SNB.2013.11.060.
  • [18] Nakate, U. T., Patil, P., Ghule, B., Nakate, Y. T., Ekar, S., Ambare, R. C., and Mane, R. S. “Room Temperature LPG Sensing Properties Using Spray Pyrolysis Deposited Nano-Crystalline CdO Thin Films.” Surfaces and Interfaces, Vol. 17, 2019, p. 100339. https://doi.org/10.1016/J.SURFIN.2019.100339.
  • [19] Ziabari, A. A., and Ghodsi, F. E. “Optical and Structural Studies of Sol-Gel Deposited Nanostructured CdO Thin Films: Annealing Effect.” Acta Physica Polonica A, Vol. 120, 2011, pp. 536–540.
  • [20] Choudhary, K., Saini, R., Upadhyay, G. K., and Purohit, L. P. “Sustainable Behavior of Cauliflower like Morphology of Y-Doped ZnO:CdO Nanocomposite Thin Films for CO2 Gas Sensing Application at Low Operating Temperature.” Journal of Alloys and Compounds, Vol. 879, 2021, p. 160479. https://doi.org/10.1016/J.JALLCOM.2021.160479.
  • [21] Prabavathi, A., Balu, A. R., Nagarethinam, V. S., Raja, N., Suganya, M., Usharani, K., Balamurugan, S., Karthika, M., and Kayathiri, C. “Cauliflower Shaped CdO:Mo Nanostructures with Enhanced Photocatalytic Activity against the Degradation of Metanil Yellow Dye.” Nano-Structures & Nano-Objects, Vol. 22, 2020, p. 100458. https://doi.org/10.1016/J.NANOSO.2020.100458.
  • [22] Shanmugavel, G., Balu, A. R., Baskaran, R., and Nagarethinam, V. S. “Realization of Improved Hackee’s Quality Factor and Photo Degradation Efficiency of Cauliflower Shape Nanostructured CdO Thin Films through Cs Doping.” Photonics and Nanostructures - Fundamentals and Applications, Vol. 40, 2020, p. 100784. https://doi.org/10.1016/J.PHOTONICS.2020.100784.
  • [23] Miller, D. R., Akbar, S. A., and Morris, P. A. “Nanoscale Metal Oxide-Based Heterojunctions for Gas Sensing: A Review.” Sensors and Actuators B: Chemical, Vol. 204, 2014, pp. 250–272. https://doi.org/10.1016/J.SNB.2014.07.074.
There are 23 citations in total.

Details

Primary Language English
Subjects Wearable Materials
Journal Section Articles
Authors

Enes Nayman 0000-0002-3656-3126

Mehmet Fatih Gözükızıl 0000-0003-1719-959X

İsmail Usta 0000-0002-0869-5439

Early Pub Date July 1, 2024
Publication Date June 30, 2024
Submission Date September 21, 2022
Acceptance Date March 31, 2023
Published in Issue Year 2024

Cite

APA Nayman, E., Gözükızıl, M. F., & Usta, İ. (2024). Deposition of CdO Semiconductors on yarns by Dip Coating Method and Gas Sensor Applications. Textile and Apparel, 34(2), 117-126. https://doi.org/10.32710/tekstilvekonfeksiyon.1178133

No part of this journal may be reproduced, stored, transmitted or disseminated in any forms or by any means without prior written permission of the Editorial Board. The views and opinions expressed here in the articles are those of the authors and are not the views of Tekstil ve Konfeksiyon and Textile and Apparel Research-Application Center.