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HİPERDALLANMIŞ POLİMER İLE MODİFİYE EDİLMİŞ POLİPROPİLEN LİFLERİNİN DOĞAL BOYALARLA BOYANABİLİRLİĞİNİN İNCELENMESİ

Year 2015, Volume: 25 Issue: 1, 73 - 79, 01.06.2015

Abstract

Hiperdallanmış polimer (HBP) eriyik halde lif çekimi esnasında ilave edilerek doğal boyalarla boyanabilen polipropilen (PP) lifi üretilmiştir. Ceviz kabuğu (Juglans regia L), palamut (Quercus Infectoria), papatya (Anthemis tinctoria), ada çayı (Salvia officinalis L) ve cehri (Rhamnus petiolaris) doğal boya kaynakları olarak seçilmiştir. Doğal boyalarla boyanmış PP liflerinin K/S değerlerine HBP konsantrasyonunun etkisi incelenmiştir. Yıkama haslıkları ve Fourier Dönüşümlü Infrared spektrometresi (FTIR) analizleri yapılmıştır. Ayrıca Diferansiyel Taramalı Kalorimetre (DSC) ile liflerin yüzde kristaliniteleri ve Taramalı Elektron Mikroskobu (SEM) ile morfolojik analizleri yapılmıştır. HBP ilavesinin; PP lifinin ceviz kabuğu, palamut ve cehri ile boyanabilirliğini papatya ve ada çayına göre daha çok artırdığı tespit edilmiştir. PP liflerinin doğal boyalarla boyanabilirliği HBP ilavesi ile arttığı görülmüştür

References

  • 1. Toshnival, L., Fan, Q., Ugbolue. S.C., 2007, “Dyeable polypropylene fibers via nanotechnology”. Journal of Applied Polymer Science, 106, pp: 706-711.
  • 2. Burkinshaw, S.M., 1995, Chemical Principle of Synthetic Fibre Dyeing, London, Chapman&Hall, 223.
  • 3. Needles, H.L., 1986, Textile Fibers, Dyes, Finishes and Processes, New Jersey, Noyes Publications, 227.
  • 4. Mirjalili, F., Moradian, S., Ameri, F., 2013, “ Enhancing the dyeability of polypropylene fibers by melt blending with polyethylene terephthalate”, Scientific World Journal, Article ID: 46854.
  • 5. Ataeefard, M., Moradian, S., 2012, “Preparing dyeable PP fiber nanocomposites using the special cubic mixture experimental design”. Journal of the Textile Institute, 103, p:1169-1182.
  • 6. Effenberger, F., Schweizer, M., and Mohamed, W.S., 2010, “Effect of montmorillonite clay nanoparticles on the properties of polypropylene fibres”, PolymerPlastics Technology and Engineering, 49, pp: 525-530.
  • 7. Arkman, J., Prikryl, J., 1996, “Dyeing behavior of polypropylene blend fiber. I. Kinetic and thermodynamic parameters of the dyeing system”, Journal of Applied Polymer Science, 62, pp: 235-245.
  • 8. Li, G., Wang, L.,, Ni, H., Pittman, C.U., 2001, “ Poly oligomeric silsesquioxane (POSS) polymers and copolymers: a review”, . Journal of Inorganic and Organometallic Polymers, 11, pp: 123-154.
  • 9. Joshi, M., Bhattacharyya, A., 2011, “Nanotechnology – a new route to high-performance functional textiles”, . Textile Progress, 43, pp: 155-233.
  • 10. Butola, B.S., Joshi, M., Kumar, S.,2010, “ Hybrid organic-inorganic POSS (polyhedral oligomeric silsesquioxane)/polypropylene nanocomposite filaments”, Fibers and Polymers, 11, pp: 1137-1145.
  • 11. Zeng, J., Kumar, S., Iyer, S., Schiraldi, D.A., Gonzalez, R.I., 2005, “Reinforcement of poly(ethylene terephthalate) fibers with polyhedral oligomeric silsesquioxanes (POSS)” Advances in Polymer Science, 17, pp: 403-424.
  • 12. Rabiei, N., Haghighat, K., Amirshahi, S.H., Radjabian, M., 2012, “The kinetic and thermodynamic parameters of dyeing of polypropylene/clay composite fibers using disperse dye”, Dyes and Pigments, 94, pp: 386-392.
  • 13. Ataeefard, M., Moradian, S., “Investigation the effect of various loads of organically modified montmorillonite on dyeing properties of polypropylene nanocomposites”, Journal of Applied Polymer Science, 125: pp:214-223.
  • 14. Gao, C.,Yan, D., 2004, “Hyperbranched polymers: from synthesis to applications”, Progress in Polymer Science, 29, pp: 183-275.
  • 15. Kim, Y.H., 1998, “Hyperbranched polymers 10 years after”, Journal of Polymer Science 1998; 36: 1685-1698.
  • 16. Kim, Y.H., Beckerbauer, R., 1994, “Role of end-groups on the glass-transition of hyperbranched polyphenylene and triphenylbenzene derivatives”, Macromolecules, 27, pp: 1968-1971.
  • 17. Uhrich, K.E., Hawker, C., Fre´chet ,J.M.J.,Turner, S.R., 1992, “One-pot synthesis of hyperbranched polyethers”, Macromolecules, 25, pp: 4583–4587.
  • 18. Wooley, K.L., Fre´chet, J.M.J.,Hawker, C.J., 1994, “Influence of shape on the reactivity and properties of dendritic, hyperbranched and linear aromatic polyesters”, Polymer, 23, p: 4489–4595.
  • 19. Burkinshaw, S.M., Froehling, P.E., Mignanelli, M., 2002, “The effect of hyperbranched polymers on the dyeing of polypropylene fibres” Dyes and Pigments, 53, pp: 229–235.
  • 20. Gao, C., Tang, W., Yan, D.Y., 2002, “ Synthesis and characterization of water-soluble hyperbranched poly(ester amine)s from diacrylates and diamines”, Journal of Applied Polymer Science: Part A: Polymer Chemistry, 40, pp: 2340–2349.
  • 21. Ishida, Y., Sun, A.C.F., Jikei, M., Kakimoto, M., 2000, “ Synthesis of hyperbranched aromatic polyamides starting from dendrons as ABx monomers: effect of monomer multiplicity on the degree of branching”, Macromolecules, 33, pp: 2832–2838.
  • 22. Bolton, D.H., Wooley, K.L., 1997, “Synthesis and characterization of hyperbranched polycarbonates”, Macromolecules, 30, pp: 1890–1896.
  • 23. Yoon, K., Son, D.Y., 1999, “Synthesis of hyperbranched poly(carbosilarylenes)”, Macromolecules, 32, pp: 5210–5216.
  • 24. Razafimahefa, L., Chlebicki, S., Vroman, I., Devaux ,E., 2008, “Effect of nanoclays on the dyeability of polypropylene nanocomposite fibres”, Coloration Technology, 124, pp: 86-91.

INVESTIGATION THE DYEABILITY OF HYPERBRANCHED POLYMER MODIFİED POLYPROPYLENE FIBERS WITH NATURAL DYES

Year 2015, Volume: 25 Issue: 1, 73 - 79, 01.06.2015

Abstract

Polypropylene (PP) fiber dyeable with natural dyes was produced with the inclusion of hyperbranched polymer (HBP) via melt spinning technique. Walnut shell (Juglans regia L), oak gall (Quercus infectoria), dyer’s camomile (Anthemis tinctoria), sage tea (Salvia officinalis L) and cehri (Rhamnus petiolaris) are selected as natural dye sources. The effect of HBP concentration on K/S values of natural dyed PP fibers was investigated. The wash fastness and Fourier Transform Infrared (FTIR) spectroscopy results of fiber samples were also studied. Furthermore, the percent crystallinity of fiber samples was determined by differential scanning calorimeter (DSC) and the morphological analyses were performed with scanning electron microscopy (SEM). It was observed that the addition of HBP enhanced the dyeability of PP fiber with walnut shell, oak gall and cehri significantly compared to dyer’s camomile and sage dyed ones. The chemical structure of dyes has a great importance in the interaction with HBP. The inclusion of HBP enhanced the dyeability of PP fibers with natural dyes

References

  • 1. Toshnival, L., Fan, Q., Ugbolue. S.C., 2007, “Dyeable polypropylene fibers via nanotechnology”. Journal of Applied Polymer Science, 106, pp: 706-711.
  • 2. Burkinshaw, S.M., 1995, Chemical Principle of Synthetic Fibre Dyeing, London, Chapman&Hall, 223.
  • 3. Needles, H.L., 1986, Textile Fibers, Dyes, Finishes and Processes, New Jersey, Noyes Publications, 227.
  • 4. Mirjalili, F., Moradian, S., Ameri, F., 2013, “ Enhancing the dyeability of polypropylene fibers by melt blending with polyethylene terephthalate”, Scientific World Journal, Article ID: 46854.
  • 5. Ataeefard, M., Moradian, S., 2012, “Preparing dyeable PP fiber nanocomposites using the special cubic mixture experimental design”. Journal of the Textile Institute, 103, p:1169-1182.
  • 6. Effenberger, F., Schweizer, M., and Mohamed, W.S., 2010, “Effect of montmorillonite clay nanoparticles on the properties of polypropylene fibres”, PolymerPlastics Technology and Engineering, 49, pp: 525-530.
  • 7. Arkman, J., Prikryl, J., 1996, “Dyeing behavior of polypropylene blend fiber. I. Kinetic and thermodynamic parameters of the dyeing system”, Journal of Applied Polymer Science, 62, pp: 235-245.
  • 8. Li, G., Wang, L.,, Ni, H., Pittman, C.U., 2001, “ Poly oligomeric silsesquioxane (POSS) polymers and copolymers: a review”, . Journal of Inorganic and Organometallic Polymers, 11, pp: 123-154.
  • 9. Joshi, M., Bhattacharyya, A., 2011, “Nanotechnology – a new route to high-performance functional textiles”, . Textile Progress, 43, pp: 155-233.
  • 10. Butola, B.S., Joshi, M., Kumar, S.,2010, “ Hybrid organic-inorganic POSS (polyhedral oligomeric silsesquioxane)/polypropylene nanocomposite filaments”, Fibers and Polymers, 11, pp: 1137-1145.
  • 11. Zeng, J., Kumar, S., Iyer, S., Schiraldi, D.A., Gonzalez, R.I., 2005, “Reinforcement of poly(ethylene terephthalate) fibers with polyhedral oligomeric silsesquioxanes (POSS)” Advances in Polymer Science, 17, pp: 403-424.
  • 12. Rabiei, N., Haghighat, K., Amirshahi, S.H., Radjabian, M., 2012, “The kinetic and thermodynamic parameters of dyeing of polypropylene/clay composite fibers using disperse dye”, Dyes and Pigments, 94, pp: 386-392.
  • 13. Ataeefard, M., Moradian, S., “Investigation the effect of various loads of organically modified montmorillonite on dyeing properties of polypropylene nanocomposites”, Journal of Applied Polymer Science, 125: pp:214-223.
  • 14. Gao, C.,Yan, D., 2004, “Hyperbranched polymers: from synthesis to applications”, Progress in Polymer Science, 29, pp: 183-275.
  • 15. Kim, Y.H., 1998, “Hyperbranched polymers 10 years after”, Journal of Polymer Science 1998; 36: 1685-1698.
  • 16. Kim, Y.H., Beckerbauer, R., 1994, “Role of end-groups on the glass-transition of hyperbranched polyphenylene and triphenylbenzene derivatives”, Macromolecules, 27, pp: 1968-1971.
  • 17. Uhrich, K.E., Hawker, C., Fre´chet ,J.M.J.,Turner, S.R., 1992, “One-pot synthesis of hyperbranched polyethers”, Macromolecules, 25, pp: 4583–4587.
  • 18. Wooley, K.L., Fre´chet, J.M.J.,Hawker, C.J., 1994, “Influence of shape on the reactivity and properties of dendritic, hyperbranched and linear aromatic polyesters”, Polymer, 23, p: 4489–4595.
  • 19. Burkinshaw, S.M., Froehling, P.E., Mignanelli, M., 2002, “The effect of hyperbranched polymers on the dyeing of polypropylene fibres” Dyes and Pigments, 53, pp: 229–235.
  • 20. Gao, C., Tang, W., Yan, D.Y., 2002, “ Synthesis and characterization of water-soluble hyperbranched poly(ester amine)s from diacrylates and diamines”, Journal of Applied Polymer Science: Part A: Polymer Chemistry, 40, pp: 2340–2349.
  • 21. Ishida, Y., Sun, A.C.F., Jikei, M., Kakimoto, M., 2000, “ Synthesis of hyperbranched aromatic polyamides starting from dendrons as ABx monomers: effect of monomer multiplicity on the degree of branching”, Macromolecules, 33, pp: 2832–2838.
  • 22. Bolton, D.H., Wooley, K.L., 1997, “Synthesis and characterization of hyperbranched polycarbonates”, Macromolecules, 30, pp: 1890–1896.
  • 23. Yoon, K., Son, D.Y., 1999, “Synthesis of hyperbranched poly(carbosilarylenes)”, Macromolecules, 32, pp: 5210–5216.
  • 24. Razafimahefa, L., Chlebicki, S., Vroman, I., Devaux ,E., 2008, “Effect of nanoclays on the dyeability of polypropylene nanocomposite fibres”, Coloration Technology, 124, pp: 86-91.
There are 24 citations in total.

Details

Other ID JA89AU72GF
Journal Section Articles
Authors

Asım Davulcu This is me

Publication Date June 1, 2015
Submission Date June 1, 2015
Published in Issue Year 2015 Volume: 25 Issue: 1

Cite

APA Davulcu, A. (2015). INVESTIGATION THE DYEABILITY OF HYPERBRANCHED POLYMER MODIFİED POLYPROPYLENE FIBERS WITH NATURAL DYES. Textile and Apparel, 25(1), 73-79.

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