OZONLAMA: OPTİK BEYAZLATILMIŞ KUMAŞLAR İÇİN YENİ BİR DESENLENDİRME YÖNTEMİ

Year 2016, Volume: 26 Issue: 1, 76 - 83, 01.06.2016

Seher Perincek

Abstract

Bu çalışmada, pamuklu kumaş üzerinden optik beyazlatıcıların uzaklaştırılmasında ozonun kullanılabilirliği incelenmiştir. Bu amaçla, üç farklı konsantrasyonda (%0.1-0.3-0.5) stilben esaslı direkt tip optik beyazlatıcı pamuklu kumaşa aktarılmış ve sonrasında optik beyazlatılmış numuneler 15, 30 ve 60 dakika süresince ozonlanmıştır. Elde edilen sonuçlar ozonlamanın optik beyazlatılmış numunelerin rengini gidermede başarılı bir şekilde kullanılabileceğini göstermektedir. İşlemin verimliliği ozonlama süresindeki artış ile birlikte artmaktadır, ancak kumaşların patlama mukavemet kayıplarındaki artıştan dolayı ideal işlem süresinin seçilmesine dikkat edilmelidir. Aynı zamanda bu çalışma ile optik beyazlatılmış pamuklu kumaşlar için yeni bir desenlendirme yöntemi geliştirilmiştir. Elde edilen sonuçlara bakılarak bu yeni yöntemin, optik beyazlatmada kullanılamayan batik boyama ile benzer sonuçları sağladığı söylenebilir

Keywords

Ozon, optik beyazlatma, renk giderimi, batik boyama, batik

OZONATION: A NEW PATTERNING METHOD FOR OPTICAL BLEACHED FABRICS

Abstract

In this paper, the usability of ozone to remove the optical brightener from cotton fabric is undertaken. For this aim, the direct type optical brightener based on stilbene, with three different concentration (0.1-0.3-0.5%), was applied to the cotton fabric and then optical bleached samples were ozonated for 15, 30, and 60 minutes. The achieved results clearly indicate that ozonation can be used efficiently to decolorize the optical bleached samples. The efficiency of the process increased with the rise in ozonation time, but it should be paid attention to choose the ideal process time because of the increase in bursting strength loss of fabric. Also, a new patterning method has been developed for optical bleached cotton fabric with this study. It can be said that this new process provides similar results with tiedyeing, which is not appropriate for optical bleaching, in the light of achieved results

Keywords

Ozone, optical brightening, color removal, tie-dyeing, batik

References

• 1. Boughton, A.J., Lewis, L.C., Bonning, B.C., 2001, “Potential of Agrotis ipsilon nucleopolyhedrovirus for suppression of the black cutworm (Lepidoptera: Noctuidae) and effect of an optical brightener on virus efficacy”, Journal of Economic Entomology, 94, 1045-1052.
• 2. Esteves, M.F., Noronha, A.C., Marinho, R.M., 2004, “Optical Brighteners Effect on White and Colored Textiles”, Autex World Textile Conference, 4, Roubaix, 1-6.
• 3. Millington, K.R., Maurdev, G., 2004, “The generation of superoxide and hydrogen peroxide by exposure of fluorescentwhitening agents to UVA radiation and its relevance to the rapid photoyellowing of whitened wool”, Journal of Photochemistry and Photobiology A: Chemistry, 165, 177–185.
• 4. Panda, H., Panda, R., 2006, “Fluorescent brighteners and optical whitening agents”, Science Tech Entrepreneur. 5. Karmakar, S.R., 1999, “Chemical technology in the pretreatment process of textiles”, Textile Science and Technology, 12, 320-327.
• 6. Sakamoto, T., 1988, “Method for preventing the brightening effect of optical brightening agents on textiles”, United States Patent, Patent No: 4,764,176.
• 7. Kramer, J.B., Canonica, S., Hoigne, J., 1996, “Degradation of fluorescent whitening agents in sunlit natural waters”, Environ. Science Technology, 30, 2227-2234.
• 8. Stana, K.K., Pohar, C., Ribitsch, V., 1995, “Adsorption of whitening agents on cellulose fibers-Monitored by streaming potential measurements, calorimetry and fluorescence”, Colloid & Polymer Science, 273, 1174-1178.
• 9. Baum, A.A., Sanders, P.A., 1955, “Fluorescent whitening agents”, United States Patent, Patent No: 2,700,043. 10. Eder, K.W., 1957, “Optical bleach”, United States Patent, Patent No: 2,806,054.
• 11. Tomasino, C., 1992, Handbook of Chemistry & technology of fabric preparation & finishing, Department of Textile Engineering, Chemistry & Science College of Textiles, North Carolina State University, Raleigh, North Carolina, 70-71.
• 12. Perincek, S., Bahtiyari, M.İ., Körlü, A.E., 2007, “Ozone bleaching of jute fabrics”, AATCC, 3, 34-39.
• 13. Konsowa, A.H., 2003, “Decolorization of wastewater containing direct dye by ozonation in a batch bubble column reactor“, Desalination, 158, 233-240.
• 14. Namboodri, C.G., Perkins, W.S., Walsh, W.K., 1994, “Decolorizing dyes with chlorine and ozone: Part II”, American Dyestuff Reporter, 17-26.
• 15. Perincek, S., Duran, K., Körlü, A.E., 2007, “An investigation in the use of ozone gas in the bleaching of cotton fabrics”, Ozone: Science and Engineering, http://www.informaworld.com/smpp/title~content=t713610645~db=all~tab=issueslist~branches=29 - v2929, 325-333.
• 16. Sevimli, M.F., Sarikaya, H.Z., 2002, “Ozone treatment of textile effluents and dyes: effect of applied ozone dose, pH and dye concentration”, Journal of Chemical Technology and Biotechnology, 77, 842-850.
• 17. Perincek, S., 2006, “An investigation on the applicability of ultrasound, ultraviolet, ozone and combination of these technologies as a pretreatment process”, MSc Thesis, Textile Engineering Department, Ege University, İzmir, Turkey.
• 18. Wu, J., Wang, T., 2001, “Ozonation of aqueous azo dye in a semi-batch reactor”, Water Research, 35, 1093-1099.
• 19. Sarayu, K., Swaminathan, K., Sandhya, S., 2007, “Assessment of degradation of eight commercial reactive azo dyes individually and in mixture in aqueous solution by ozonation”, Dyes and Pigments, 75, 362-368.
• 20. Marmagne, O., Coste, C., 1996, “Color removal from textile plant effluents”, American Dyestuff Reporter, 15-21.
• 21. Muthukumar, M., Sargunamani, D., Selvakumar, N., 2004, “Optimisation of ozone treatment for colour and COD removal of acid dye effluent using central composite design experiment”, Dyes and Pigments, 63, 127–134.
• 22. Perincek, S., Bahtiyari, M.İ., Körlü, A.E., 2008, “Ozone treatment of angora rabbit fiber”, Journal of Cleaner Production, 16, 1900-1906.
• 23. Kafka, F.J., 1973. Batik, Tie Dyeing, Stenciling, Silk Screen, Block Printing: The Hand Decoration of Fabrics, Dover Publications Inc, New York, 4-5.
• 24. Bilgin E., 2003, “Chemical Damages Occurred During the Pretreatment Of Cellulosic Fabrics And The Methods To Analyse Them”, MSc Dissertation, Ege University.
• 25. Iglesias, S.C., 2002, “Degradation and biodegradability enhancement of nitrobenzene and 2,4-dichlorophenol by means of advanced oxidation processes based on ozone”, PhD Thesis, Universitat De Barcelona.
• 26. Balousek, P.J.,1979, “The effects of ozone upon lignin-related model compounds containing a B-aryl ether linkage”, PhD Thesis, Lawrence University, Wisconsin.
• 27. Lyse, T.E., 1979, “A study on ozone modification of lignin in alkali fiberized wood”, PhD Thesis, The Institute of Paper Chemistry, Lawrence University, Wisconsin.
• 28. Adams, C.D., Gorg, S., 2002, “Effect of pH and gas-phase ozone concentration on the decolorization of common textile dyes”, J. Environ. Eng., 128, 293–