A STUDY ON MODAL FABRIC TREATED WITH FORMIC ACID

Year 2017, Volume: 27 Issue: 2, 153 - 162, 30.06.2017

K Gnanapriya Jeyakodi Moses J

Abstract

Modal is a bio-based rather than natural made from the spun reconstituted cellulose polymer of beech trees. Modal is a second generation regenerated cellulosic fiber and a variation of rayon. They are wear resistant and strong while maintaining a soft, silky feel. Fabric made from modal drape well and do not pile like cotton. Modal fabrics resist fading, shrinking and the buildup of hard water mineral deposits even after repeated washing. In this study, modal fabrics (woven and knitted) are selected and conventionally pretreated and subjected with 98% formic acid which is a used for the bio process of cellulose polymeric materials, in different concentrations. The formic acid treated modal fabrics were then undergone different testing such as; physical properties, absorbency, wicking, K/S value, fastness properties, water vapour permeability, air permeability, and SEM analysis. These treatments on modal fabrics were correspondingly compared with those of cotton for its effectiveness.

Keywords

Modal fabrics, Formic acid, Wicking, Water vapour & Air Permeability, SEM

References

• 1. Kreze, T, & Malej, S, (2003), Structural Characteristics of New and Conventional Regenerated Cellulosic Fibers, Text Res J, 73(8), pp.675-684.
• 2. White, P, Hayhurst, M, Taylor, J, & Slater, A, (2005), In: Blackburn RS (ed) Biodegradable and Sustainable Fibers (Woodhead Publishing Limited, Cambridge).
• 3. Bui, HM, Lenninger, M, Manian, AP, Abu-Rous, M, Schimper, CB, Schuster KC, & Bechtold, T (2008), Treatment in Swelling So lutions Modifying Cellulose F iber Reactivity— Part 2 Accessibility Reactivity, Macromol Symp, 262, pp.50–64.
• 5. Schurz, J, (1999), Trends in polymer science. A bright future for cellulose, Progress in Polymer Science. 24(4), pp. 481–483.
• 6. Bredereck, K, & Hermanutz, F, (2005), Review of Progress in Coloration and Related Topics, Man-made cellulosics, 35, pp. 59–75.
• 7. Özgüney, AT, Körlü, AE, Bahtiyari, İ, & Bahar, M, (2006), Viskon Liflerinin Fiziksel Özellikleri ve Makromolekülerüstü Yapısı, Tekstil ve Konfeksiyon, 2, pp.100-104.
• 8. Bozdoğan, F, (2000), Lyocell Liflerinin Kristal Yapısına Bir Bakış, Tekstil ve Konfeksiyon.
• 9. Duran, K, Ayaz, ÖY, (1999), Sıvı Depolayan “Super Emici” Polimerler, Tekstil ve Konfeksiyon, 2, s: pp.120-127.
• 10. Chatterjee, PK, & Gupta, BS, (2002), Absorbent Technology, ISBN 044500006 (Elsevier Publishing).
• 11. Heinze, T, & Liebert, T, (2001), Unconventional methods in cellulose Functionalization, Progress in Polymer Science, 26(9), pp. 1689–1762.
• 12. Saalwachter, K, & Burchard, W, (2001), Cellulose in new metal-complexing solvents: Semidilute behavior in Cd-tren;, Macromolecules, 34(16), pp. 5587– 5598.
• 13. Simpson, V, (2011), India’s Textile and apparel industry: Growth potential and trade and investment opportunities (Staff Research Study, Office of Industries, U. S. International Trade Commission, Washington, USA).
• 14. Lewin, M, & Sello, (2000), Handbook of Fiber Science and Technology, Vol. II, Part B, (Dekker Series, New York, USA), pp. 120-125.
• 15. Lewin, M, (2007), Handbook of Fibre Chemistry;, 3 rd edition, (CRC Press, Baco Raton, USA), pp.331-382.
• 16. Teli, MD, & Kumar, GVNS, (2007), Functional textiles and apparels - Technical Textile; Journal of the Textile Association, pp. 21-30.
• 17. Stein, M, & Sauer, J, (1997), Formic acid tetramers: structure isomers in the gas phase: Chem Phys Lett, 267(1/2): pp.111–115.
• 18. Yong Sun, Lu Lin, Chunsheng Pang, Haibo Deng, Hong Peng, Jiazhe Li, Beihai He, and Shijie Liu, (2007), Hydrolysis of Cotton Fiber Cellulose in Formic Acid: Energy Fuels, 21 (4), pp. 2386–2389.
• 19. Kupiainen, L, (2012), Dilute acid catalysedhydrolysys if cellulose – Extension to formic acid (Ph.D, Dissertation, University of Oulu, Tampere, Finland).
• 20. Saville, BP, (2004), Physical Testing of Textiles (Wood Head Publishing Limited and CRC Press, Cambridge, England), pp.205-210.
• 21. Trotman, ER, (1984), Dyeing and Chemical Technology of Textile Fibers (Sixth edition, Edward Arnold, London), pp.187-217.
• 22. Shukla, SR, (2000), Advances in preparatory process in cotton;, NCUTE-Programme Series: Chemical Preparatory Process in Textiles (Indian Institute of Technology –Delhi; New Delhi), pp.85-92.
• 23. ASTM Test Method 1388-96, (2001), : Standard Test Method for Stiffness of Fabrics: Annual Book of ASTM Standards (West Conshohocken, PA, USA), Vol.07.01
• 24. AATCC Test Method 66-2003, (2003), Wrinkle recovery of woven fabrics recovery Angle: Technical Manual of the AATCC (Research Triangle Park, USA).
• 25. Connell, DL, (2005), The Control of Shrinkage in Textile Finishing (Editor Heywood, D, Woodhead Publication Ltd., Cambridge, England), pp. 60-62.
• 26. BSI, BS 5058:1973, (1990), British Standard Method for the Assessment of Drape of Fabrics (BS Handbook, London).
• 27. Collier, BJ, & Epps, HH, (1999), Textile Testing and analysis (6th edition, Prentice Hall Inc, New Jersey, USA), pp.30-35.
• 28. AATCC Technical Manual, (1991), American Association of Textile Chemists and Colorists ( Research Triangle Park, USA), pp.66.
• 29. Kissa, E, (1996), Wetting and wicking, Text Res J, 66(10), pp. 660-668.
• 30. Tyagi, GK, Krishna, G, Bhattacharya, S, & Kumar, P, (2009), Comfort aspects of finished polyester-cotton and polyester-viscose ring and MJS yarn fabrics, Indian Journal of Fiber & Textile Research, 34, pp.137-143.
• 31. Swarna Natarajan, & Jeyakodi Moses, J, (2012), Surface Modification of Polyester Fabric using Polyvinyl in Alkaline Medium, Indian Journal of Fiber & Textile Research, 37, pp. 287- 291.
• 32. Mohanty, BC, Chandramauli, KV, & Naik, HD, (1987), Natural Dyeing Process of India (Published by Calico Museum of Textiles, India).
• 33. Gulrajani, ML, & Gupta, D, (1992), Natural Dyes and their Application to Textiles (Indian Institute of Technology –Delhi, New Delhi).
• 34. AATCC Test Method 135-1985, (2003), Colour measurement of textiles: Instrumental Technical Manual of the AATCC (Research Triangle Path, USA).
• 35. AATCC test method 61, 2(A)- 2001 (2001), Colour Fastness to Laundering, Home and Commercial: Technical Manual of the AATCC (Research Triangle Park, U.S.A).
• 36. BIS Test Method IS:764-1979, Test 3 (1979), Indian Standard Method for Determination of Colour Fastness of Textile Materials to Washing (Bureau of Indian Standards).
• 37. AATCC Test Method 16-1998, (2003), Colour Fastness to Light: Technical Manual of the AATCC (Research Triangle Park, USA).
• 38. AATCC test method 8-2007, (2007), Colour Fastness to Crocking: Technical Manual of the AATCC (Research Triangle Park, USA).
• 39. AATCC Test Method 61-1996, (2003), Colour Fastness to Laundering: Home and Communication - Accelerated: Technical manual of the AATCC (Research. Triangle Park, U.S.A).
• 40. Özgüney, A, Kantar, C, & Saral, P, (2013), Investigation Of Fastness Properties And Antibacterial Effect Of Metallophthalocyanine ( M : Zn ) Containing Eugenol Printed On Cotton Fabric, Tekstil ve Konfeksiyon, 23(2), pp. 261 – 266.
• 41. ASTM – E96, (2000), Standard Test Methods for Water Vapor Transmission of Materials.
• 42. ASTM – D737, (2012), Standard Test Methods for Air Permeability of Textile Fabrics.
• 43. Keighley, J H, (1985), Breathable Fabrics and Comfort in Clothing: J. Coated Fabrics, 115, pp.89–104.
• 44. Gouda, M, & Hebeish, A, (2010), Preparation and Evaluation of CuO/Chitosan Nano-composite for Antibacterial Finishing Cotton Fabric: J of Industrial Text, 39(3), pp.203 – 213.
• 45. Hearle, JWS, (1972), Use of the Scanning Electron Microscope (Pergamon Press, Oxford, London).
• 46. Patnaik, A, Rengasamy, RS, Konthari, VK, and Ghosh, A, (2006), Wetting and wicking in fibrous materials: Textile Progress, 38, pp. 1–105.
• 47. Ramesh Babu, V, Ramakrishnan, G, Subramanian, VS, Lakshmi Kantha, (2012), Analysis of Fabrics Structure on the Character of Wicking: Journal of Engineered Fibers and Fabrics, 7(3), pp. 28 – 33.
• 48. Morent, R, Geyter, ND, Leys, C, Vansteenkiste, E, Bock, JD, and Philips, W, (2006), Measuring the wicking behavior of textiles by the combination of a horizontal wicking experiment and image processing: Rev. Sci. Instrum. 77: 093502.
• 49. Wang, SX, Li1, Y, Hiromi Tokura, Hu,JY, Han, YX, Kwok, YL, and Au, RW, (2007), Effect of Moisture Management on Functional Performance of Cold Protective Clothing: Textile Research Journal, 77(12), pp. 968–980.