New technology for production of leather for gloves and fancy goods

Year 2020, Volume: 30 Issue: 4, 270 - 275, 29.12.2020

Aigul Kudabayeva Bekzhan Abzalbekuly Urana Dandar Ersin Önem , Behzat Oral Bitlisli

https://doi.org/10.32710/tekstilvekonfeksiyon.650595

Cited By: 2

Abstract

The results of the development
of chromium saving method for obtaining of glove-haberdashery leather, allowing
to improve the quality of leather and to provide the ecological safety of
production, are presented in the paper. Leather tanning with ecologically
harmless tannages under proper parameters and consumption of chemical materials
has been carried out in semi-production conditions. The improvement of
glove-haberdashery leather quality had been achieved by partial replacement of
chromium by complex compounds, containing titanium and aluminum. Physical and
mechanical properties of glove-haberdashery ecologically harmless leathers corresponded
the standard norms and can be recommended for production of men’s and women’s
gloves.

Keywords

Tanning, eco-friendly technology, environmental safety, glove-haberdashery leather, titanium, aluminum

References

• 1. Madiev UK. 1984. Mineral'nye dubiteli na osnove geteropolijadernyh kompleksov soedinenij aljuminija, cirkonija i titana // Izv. Vuzov. Tehnologija Legkoj Promyshlennosti, 2, 158, 53-57.
• 2. Madiev UK. 1987. Mineral'noe dublenie v proizvodstve kozh. Moskva: Legprombytizdat, 120p.
• 3. Peng BY, Shi B, Ding KY, Fan HJ, Shelly DC. 2007. Novel titanium (IV) tanning for leathers with superior hydrothermal stability - III. Study of factors affecting titanium tanning and an eco-friendly titanium tanning method. Journal of the American Leather Chemists Association, 102, 297-305.
• 4. Gerasimova LG, Shchukina ES, Ohrimenko RF, Maslova MV. 2013. On the behavior of titanium(IV) sulfate in aqueous media used in leather tanning. Russian Journal of Applied Chemistry, 86, 453-457.
• 5. Mutlu MM, Crudu M, Maier SS, Deselnicu D, Albu L, Gulumser G, Bitlisli BO, Basaran B, Tosun CC, Zengin ACA. 2014. Eco-leather: Properties of chromium-free leathers produced with titanium tanning materials obtained from the wastes of the metal industry. Ekoloji, 23, 83-90.
• 6. Rosu L, Varganici CD, Crudu AM, Rosu D. 2018. Influence of different tanning agents on bovine leather thermal degradation. Journal of Thermal Analysis and Calorimetry, 134, 583-594.
• 7. Kozyreva NV, Bajandin VV, Klenovskaja NV. 1990. Fiziko-mehanicheskie svojstva kozh dlja verha obuvi titanhromovogo metoda dublenija. Kozhevenno-Obuvnaja Promyshlennost, 4, 58-60.
• 8. Crudu M, Deselnicu V, Deselnicu DC, Albu L. 2014. Valorization of titanium metal wastes as tanning agent used in leather industry. Waste Management, 34, 1806-1814.
• 9. Wang KJ, Chen YN, Dan NH, Li F, Dan WH. 2018. Chrome-less tanning - a non-pickling process based on Zr-Al-Ti complex tanning agent. Journal of the Society of Leather Technologists and Chemists, 102, 1-6.
• 10. Zissel A, Schmidt G, Magerkurth B. 1980. Der Erstz des Chroms durch aluminium und andere Gerbstoffe im Hinbiick uf Leder character Gerbsoffbindund. Leder, 2, 17-24.
• 11. Han W, Zhou CF, Zhang WH, Shi B. 2017. Molecular level understanding of the stability difference in collagen induced by chromium sulfate and aluminum sulfate. Journal of the Society of Leather Technologists and Chemists, 101, 273-279.
• 12. Wang L, Han WM, Yu Y, Zhou JF, Zhang WH, Shi B. 2017. Thermodynamic investigations on chrome and aluminum tanning. Journal of the American Leather Chemists Association, 112, 360-366.
• 13. Krawecki CZ. 1980. Methode non convetionnelle de tаnnаge chrome/аluminium. Technicuir, 4, 73-76.
• 14. Kudabaeva AK, Madiev UK, Evtjushkina M.I. 2007. Sposob dublenija perchatochno-galanterejnoj kozhi. Patent: AS-61182-2007/1761.1, Kazakhstan.
• 15. Tang HR, Covington AD, Hancock RA. 2003. Use of DSC to detect the heterogeneity of hydrothermal stability in the polyphenol-treated collagen matrix. Journal of Agricultural and Food Chemistry, 51, 6652-6656.
• 16. Hui C, Zhi-Hua S. 2008. Changes in hydrothermal stability of collagen with several catechin-metal compounds: A DSC study. Journal of the Society of Leather Technologists and Chemists, 92, 93-95.
• 17. Wang YJ, Guo J, Chen H, Shan ZH. 2010. Influence of containing moisture on hydrothermal stability of modified collagen thermal characteristics analysis by DSC. Journal of Thermal Analysis and Calorimetry, 99, 295-300.
• 18. Urudzhev RS, Demirova AM, Gadzhieva AM. 2005. O mehanizme vlijanija dublenija na termostojkost' kollagena. Kozhevenno-Obuvnaja Promyshlennost', 2, 47-48.
• 19. GOST 15092-80. 1982. Interstate Standards, Leather for gloves and mittens. Specifications, Moscow, 12p.
• 20. TS EN ISO 2589. 2016. Leather - Physical and mechanical tests - Determination of thickness. Turkish Standards Institution, Ankara, 11p.
• 21. TS EN ISO 3376. 2012. Leather - Physical and mechanical tests - Determination of tensile strength and percentage extension. Turkish Standards Institution, Ankara, 13p.
• 22. TS EN ISO 4045. 2018. Leather - Chemical tests - Determination of pH. Turkish Standards Institution, Ankara, 14p.
• 23. TS EN ISO 4684. 2006. Leather - Chemical tests - Determination of volatile matter. Turkish Standards Institution, Ankara, 14p.
• 24. TS EN ISO 5398-1. 2018. Leather - Chemical determination of chromic oxide content - Part 1: Quantification by titration. Turkish Standards Institution, Ankara, 18p.
• 25. TS EN ISO 4048. 2018. Leather - Chemical tests - Determination of matter soluble in dichloromethane and free fatty acid content. Turkish Standards Institution, Ankara, 22p.
• 26. Danilkovich AG, Chursin VI. 2002. Praktikum po himii i tehnologii kozhi meha. Uchebn. Posobie Dlja Vuzov, Moskva: CNIIKP, 413p.
• 27. Venkatachalam PS. 1962. Lecture Notes on Leather. Central Research Institute, Madras, India.
• 28. Kontou E, Farasoglou P. 1998. Determination of the true stress–strain behaviour of polypropylene. Journal of Materials Science, 33, 147-153.
• 29. Case J, Chilver A, Ross CTF. 1999. Strength of materials and structures. Butterworth-Heinemann, 720p.
• 30. Roylance D. 2001. Stress-strain curves. Massachusetts Institute of Technology, Cambridge University Press.
• 31. Kirakos'janc MH. 1978. Primenenie solej aljuminija pri dublenii. Moskva: Legkaja Industrija, 80p.