Research Article
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Performance Characteristics in Textile Application of Photochromic Dye Capsules

Year 2022, Volume: 32 Issue: 2, 155 - 161, 30.06.2022
https://doi.org/10.32710/tekstilvekonfeksiyon.942566

Abstract

Photochromic dyes which change their color with UV light, are water insoluble and sensitive to the environmental conditions. In order to be able to use these dyes in textile industry, the dyes are encapsulated with a polymer, and then the encapsulated photochromic dyes are applied onto the textile materials. The encapsulated photochromic dyes can show different properties according to the photochromic dye and polymer type, capsule size and the encapsulation method applied. In this study, the performance characteristics of different commercial photochromic dye capsules were investigated after the application onto cotton fabrics by pad-cure process. It was observed that the fabrics still provide UV protection at 50 + UPF level even after 10 washing cycles. The photochromic fabrics lost their color and UV protective properties at most 16% and 4%, respectively after 20 UV on-off cycles.

Supporting Institution

Ege University

Project Number

18-TKUAM-003

Thanks

The authors would like to gratefully acknowledge Ege University, scientific research projects through the project no. 18-TKUAM-003 for financial support to this research project.

References

  • Ferrara M., Bengisu M. 2013. Materials that Change Color: Smart Materials, Intelligent Design. London: Springer Briefs in Applied Sciences and Technology.
  • Akçakoca Kumbasar E. P. A., Morsunbul S., Alır, S. 2018. Photochromic Nanofibers. In T. Lin (Ed.), Novel Aspects of Nanofibers. London: IntechOpen, 69–85.
  • Akçakoca Kumbasar E. P., Morsunbul S. 2017. Photochromic Textiles. In B. Mahltig (Ed.), Textiles: Advances in Research and Applications. New York: Nova Science, 359–380.
  • Bouas-Laurent H., Dürr H. 2001. Organic photochromism. Pure Appl. Chem. 73, 639–665.
  • Nigel Corns S., Partington S. M., Towns A. D. 2009. Industrial organic photochromic dyes. Color. Technol. 125, 249–261.
  • Crano J. C., Gugliemetti R. J. 2002. Organic Photochromic and Thermochromic Compounds. Volume 1: Main Photochromic Families. New York: Kluwer Academic Publishers.
  • Parhizkar M., Zhao Y., Lin T. 2015. Photochromic Fibers and Fabrics. In X. Tao (Ed.), Handbook of Smart Textiles. Singapore: Springer, 155–182.
  • Chowdhury M. A., Joshi M., Butola B. S. 2014. Photochromic and thermochromic colorants in textile applications. J. Eng. Fiber. Fabr. 9, 107–123.
  • Abate M. T., Seipel S., Vikova M., Vik M., Ferri A., Jinping G., Chen G., Nierstrasz V.A. 2018. Comparison of the photochromic behaviour of dyes in solution and on polyester fabric applied by supercritical carbon dioxide. IOP Conf. Ser. Mater. Sci. Eng. 459, 1-8.
  • Akçakoca Kumbasar E. P. A., Çay A., Morsunbul S., Voncina B. 2016. Color Build-Up and UV-protection Performance of Encapsulated Photochromic Dye-Treated Cotton Fabrics. AATCC J. Res. 3, 1–7.
  • Hoffmann K., Laperre J., Avermaete A., Altmeyer P., Gambichler T. 2001. Defined UV protection by apparel textiles. Arch. Dermatol. 137, 1089–1094.
  • Dubrovski P. D. 2010. Woven Fabrics and Ultraviolet Protection. In P. D. Dubrovski (Ed.), Woven Fabr. Eng. London: IntechOpen, 247–296.
  • Dubrovski, P. D., Golob D. 2009. Effects of Woven Fabric Construction and Color on Ultraviolet Protection. Text. Res. J. 79, 351–359.
  • Dubrovski P. D., Miran B. 2009. Prediction of the ultraviolet protection of cotton woven fabrics dyed with reactive dystuffs. Fibres Text. East. Eur. 17, 55–59.
  • Krzysztof K., Barbara L. S. 2014. Effect of selected metrological parameters of dyed polyester textiles on their UV-barrier properties. Fibers Polym. 15, 2077–2085.
  • Wong W., Lam J. K., Kan C., Postle R. 2016. Influence of reactive dyes on ultraviolet protection of cotton knitted fabrics with different fabric constructions. Text. Res. J. 86, 512–532.
  • Ibrahim N. A., E-Zairy W. R., Eid B. M. 2010. Novel approach for improving disperse dyeing and UV-protective function of cotton-containing fabrics using MCT-β-CD. Carbohydr. Polym. 79, 839–846.
  • Paluszkiewicz J., Czajkowski W., Kaźmierska M., Stolarski R. 2005. Reactive dyes for cellulose fibres including UV absorbers. Fibres Text. East. Eur. 13, 76–80.
  • Sarkar A. K. 2004. An evaluation of UV protection imparted by cotton fabrics dyed with natural colorants. BMC Dermatol. 4(15), 1-8.
  • Wang S. Q., Kopf A. W., Marx J., Bogdan A., Polsky D., Bart, R. S. 2001. Reduction of ultraviolet transmission through cotton T-shirt fabrics with low ultraviolet protection by various laundering methods and dyeing: Clinical implications. J. Am. Acad. Dermatol. 44, 767–774.
  • Wuxi City Greg Technology Co. 2021, April 21. China Photochromic Pigment for Yarn Making Ultraviolet UV Photosensitive Color Yarn. Retrieved from https://photoluminescent.en.made-in-china.com/product/LNKEOsqlSBVp/China-Photochromic-Pigment-for-Yarn-Making-Ultraviolet-UV-Photosensitive-Color-Yarn.html.
  • SolarActive. 2021, April 21. Recent Projects, Color Changing Products, Color Change, Buttons, Beads & Lace Change Color in the Sun. Retrieved from https://www.solaractive.com/recent-projects-solar-active-uv-color-change-products-ezp-4.html.
  • Talvenmaa, P. 2006. Introduction to chromic materials. In H. Mattila, Intelligent Textiles and Clothing. Woodhead Puhlishing in Textiles, 193–205.
  • DeFacto. 2021, April 21. Turuncu Erkek Çocuk - Genç Erkek Erkek Çocuk Şekil Değiştiren Baskılı Tişört. Retrieved from https://www.defacto.com.tr/erkek-cocuk-sekil-degistiren-baskili-kisa-kollu-tshirt-1224518.
  • Wang P. Y., Wu C. J. 1997. Photochromic behavior of some phenoxyanthraquinone dyes in solution and on polyester substrate. Dye. Pigment. 35, 279–288.
  • Viková M., Vik, M. 2005. Colour shift photochromic pigments in colour space CIE L*a*b*. Mol. Cryst. Liq. Cryst. 431, 403–415.
  • Lee S. J., Son Y. A., Suh H. J., Lee D. N., Kim S. H. 2006. Preliminary exhaustion studies of spiroxazine dyes on polyamide fibers and their photochromic properties. Dye. Pigment. 69, 18–21.
  • Son Y. A., Park Y. M., Park S. Y., Shin C. J., Kim, S. H. 2007. Exhaustion studies of spiroxazine dye having reactive anchor on polyamide fibers and its photochromic properties. Dye. Pigment. 73, 76–80.
  • Billah S. M. R., Christie R. M., Shamey, R. 2008. Direct coloration of textiles with photochromic dyes. Part 1: Application of spiroindolinonaphthoxazines as disperse dyes to polyester, nylon and acrylic fabrics. Color. Technol. 124, 223–228.
  • Billah S. M. R., Christie R. M., Morgan, K. M., 2008. Direct coloration of textiles with photochromic dyes. Part 2: The effect of solvents on the colour change of photochromic textiles. Color. Technol. 124, 229–233.
  • Little A. F., Christie R. M. 2010. Textile applications of photochromic dyes. Part 1: Establishment of a methodology for evaluation of photochromic textiles using traditional colour measurement instrumentation. Color. Technol. 126, 157–163.
  • Little A. F., Christie R. M. 2010. Textile applications of photochromic dyes. Part 2: Factors affecting the photocoloration of textiles screen-printed with commercial photochromic dyes. Color. Technol. 126, 164–170.
  • Little A. F., Christie R. M. 2011. Textile applications of photochromic dyes. Part 3: Factors affecting the technical performance of textiles screen-printed with commercial photochromic dyes. Color. Technol. 127, 275–281.
  • Durasevic V., Parac D., Sutlovic A. 2011. From Murex Purpura to Sensory Photochromic Textiles. In P. Hauser (Ed.) Text. Dye. London: IntechOpen, 57-76.
  • Aldib M., Christie R. M. 2011. Textile applications of photochromic dyes. Part 4: application of commercial photochromic dyes as disperse dyes to polyester by exhaust dyeing. Color. Technol. 127, 282–287.
  • Billah S. M. R., Christie R. M., Shamey, R. Direct coloration of textiles with photochromic dyes. Part3: Dyeing of wool with photochromic acid dyes. Color. Technol. 128, 488–492.
  • Aldib M., Christie R. M. 2013. Textile applications of photochromic dyes. Part 5: Application of commercial photochromic dyes to polyester fabric by a solvent-based dyeing method. Color. Technol. 129, 131–143.
  • Benita, S. 2006. Microencapsulation: Methods and Industrial Applications. New York: Taylor & Francis.
  • Salaün, F. 2016. Microencapsulation technology for smart textile coatings. In J. Hu (Ed.) Active Coatings for Smart Textiles. Woodhead Publishing Series in Textiles, 179-220.
  • Cheng S. Y., Yuen C. W. M., Kan C. W., Cheuk K. K. L. 2008. Development of Cosmetic Textiles Using Microencapsulation Technology. RJTA 12(4), 41-51.
Year 2022, Volume: 32 Issue: 2, 155 - 161, 30.06.2022
https://doi.org/10.32710/tekstilvekonfeksiyon.942566

Abstract

Project Number

18-TKUAM-003

References

  • Ferrara M., Bengisu M. 2013. Materials that Change Color: Smart Materials, Intelligent Design. London: Springer Briefs in Applied Sciences and Technology.
  • Akçakoca Kumbasar E. P. A., Morsunbul S., Alır, S. 2018. Photochromic Nanofibers. In T. Lin (Ed.), Novel Aspects of Nanofibers. London: IntechOpen, 69–85.
  • Akçakoca Kumbasar E. P., Morsunbul S. 2017. Photochromic Textiles. In B. Mahltig (Ed.), Textiles: Advances in Research and Applications. New York: Nova Science, 359–380.
  • Bouas-Laurent H., Dürr H. 2001. Organic photochromism. Pure Appl. Chem. 73, 639–665.
  • Nigel Corns S., Partington S. M., Towns A. D. 2009. Industrial organic photochromic dyes. Color. Technol. 125, 249–261.
  • Crano J. C., Gugliemetti R. J. 2002. Organic Photochromic and Thermochromic Compounds. Volume 1: Main Photochromic Families. New York: Kluwer Academic Publishers.
  • Parhizkar M., Zhao Y., Lin T. 2015. Photochromic Fibers and Fabrics. In X. Tao (Ed.), Handbook of Smart Textiles. Singapore: Springer, 155–182.
  • Chowdhury M. A., Joshi M., Butola B. S. 2014. Photochromic and thermochromic colorants in textile applications. J. Eng. Fiber. Fabr. 9, 107–123.
  • Abate M. T., Seipel S., Vikova M., Vik M., Ferri A., Jinping G., Chen G., Nierstrasz V.A. 2018. Comparison of the photochromic behaviour of dyes in solution and on polyester fabric applied by supercritical carbon dioxide. IOP Conf. Ser. Mater. Sci. Eng. 459, 1-8.
  • Akçakoca Kumbasar E. P. A., Çay A., Morsunbul S., Voncina B. 2016. Color Build-Up and UV-protection Performance of Encapsulated Photochromic Dye-Treated Cotton Fabrics. AATCC J. Res. 3, 1–7.
  • Hoffmann K., Laperre J., Avermaete A., Altmeyer P., Gambichler T. 2001. Defined UV protection by apparel textiles. Arch. Dermatol. 137, 1089–1094.
  • Dubrovski P. D. 2010. Woven Fabrics and Ultraviolet Protection. In P. D. Dubrovski (Ed.), Woven Fabr. Eng. London: IntechOpen, 247–296.
  • Dubrovski, P. D., Golob D. 2009. Effects of Woven Fabric Construction and Color on Ultraviolet Protection. Text. Res. J. 79, 351–359.
  • Dubrovski P. D., Miran B. 2009. Prediction of the ultraviolet protection of cotton woven fabrics dyed with reactive dystuffs. Fibres Text. East. Eur. 17, 55–59.
  • Krzysztof K., Barbara L. S. 2014. Effect of selected metrological parameters of dyed polyester textiles on their UV-barrier properties. Fibers Polym. 15, 2077–2085.
  • Wong W., Lam J. K., Kan C., Postle R. 2016. Influence of reactive dyes on ultraviolet protection of cotton knitted fabrics with different fabric constructions. Text. Res. J. 86, 512–532.
  • Ibrahim N. A., E-Zairy W. R., Eid B. M. 2010. Novel approach for improving disperse dyeing and UV-protective function of cotton-containing fabrics using MCT-β-CD. Carbohydr. Polym. 79, 839–846.
  • Paluszkiewicz J., Czajkowski W., Kaźmierska M., Stolarski R. 2005. Reactive dyes for cellulose fibres including UV absorbers. Fibres Text. East. Eur. 13, 76–80.
  • Sarkar A. K. 2004. An evaluation of UV protection imparted by cotton fabrics dyed with natural colorants. BMC Dermatol. 4(15), 1-8.
  • Wang S. Q., Kopf A. W., Marx J., Bogdan A., Polsky D., Bart, R. S. 2001. Reduction of ultraviolet transmission through cotton T-shirt fabrics with low ultraviolet protection by various laundering methods and dyeing: Clinical implications. J. Am. Acad. Dermatol. 44, 767–774.
  • Wuxi City Greg Technology Co. 2021, April 21. China Photochromic Pigment for Yarn Making Ultraviolet UV Photosensitive Color Yarn. Retrieved from https://photoluminescent.en.made-in-china.com/product/LNKEOsqlSBVp/China-Photochromic-Pigment-for-Yarn-Making-Ultraviolet-UV-Photosensitive-Color-Yarn.html.
  • SolarActive. 2021, April 21. Recent Projects, Color Changing Products, Color Change, Buttons, Beads & Lace Change Color in the Sun. Retrieved from https://www.solaractive.com/recent-projects-solar-active-uv-color-change-products-ezp-4.html.
  • Talvenmaa, P. 2006. Introduction to chromic materials. In H. Mattila, Intelligent Textiles and Clothing. Woodhead Puhlishing in Textiles, 193–205.
  • DeFacto. 2021, April 21. Turuncu Erkek Çocuk - Genç Erkek Erkek Çocuk Şekil Değiştiren Baskılı Tişört. Retrieved from https://www.defacto.com.tr/erkek-cocuk-sekil-degistiren-baskili-kisa-kollu-tshirt-1224518.
  • Wang P. Y., Wu C. J. 1997. Photochromic behavior of some phenoxyanthraquinone dyes in solution and on polyester substrate. Dye. Pigment. 35, 279–288.
  • Viková M., Vik, M. 2005. Colour shift photochromic pigments in colour space CIE L*a*b*. Mol. Cryst. Liq. Cryst. 431, 403–415.
  • Lee S. J., Son Y. A., Suh H. J., Lee D. N., Kim S. H. 2006. Preliminary exhaustion studies of spiroxazine dyes on polyamide fibers and their photochromic properties. Dye. Pigment. 69, 18–21.
  • Son Y. A., Park Y. M., Park S. Y., Shin C. J., Kim, S. H. 2007. Exhaustion studies of spiroxazine dye having reactive anchor on polyamide fibers and its photochromic properties. Dye. Pigment. 73, 76–80.
  • Billah S. M. R., Christie R. M., Shamey, R. 2008. Direct coloration of textiles with photochromic dyes. Part 1: Application of spiroindolinonaphthoxazines as disperse dyes to polyester, nylon and acrylic fabrics. Color. Technol. 124, 223–228.
  • Billah S. M. R., Christie R. M., Morgan, K. M., 2008. Direct coloration of textiles with photochromic dyes. Part 2: The effect of solvents on the colour change of photochromic textiles. Color. Technol. 124, 229–233.
  • Little A. F., Christie R. M. 2010. Textile applications of photochromic dyes. Part 1: Establishment of a methodology for evaluation of photochromic textiles using traditional colour measurement instrumentation. Color. Technol. 126, 157–163.
  • Little A. F., Christie R. M. 2010. Textile applications of photochromic dyes. Part 2: Factors affecting the photocoloration of textiles screen-printed with commercial photochromic dyes. Color. Technol. 126, 164–170.
  • Little A. F., Christie R. M. 2011. Textile applications of photochromic dyes. Part 3: Factors affecting the technical performance of textiles screen-printed with commercial photochromic dyes. Color. Technol. 127, 275–281.
  • Durasevic V., Parac D., Sutlovic A. 2011. From Murex Purpura to Sensory Photochromic Textiles. In P. Hauser (Ed.) Text. Dye. London: IntechOpen, 57-76.
  • Aldib M., Christie R. M. 2011. Textile applications of photochromic dyes. Part 4: application of commercial photochromic dyes as disperse dyes to polyester by exhaust dyeing. Color. Technol. 127, 282–287.
  • Billah S. M. R., Christie R. M., Shamey, R. Direct coloration of textiles with photochromic dyes. Part3: Dyeing of wool with photochromic acid dyes. Color. Technol. 128, 488–492.
  • Aldib M., Christie R. M. 2013. Textile applications of photochromic dyes. Part 5: Application of commercial photochromic dyes to polyester fabric by a solvent-based dyeing method. Color. Technol. 129, 131–143.
  • Benita, S. 2006. Microencapsulation: Methods and Industrial Applications. New York: Taylor & Francis.
  • Salaün, F. 2016. Microencapsulation technology for smart textile coatings. In J. Hu (Ed.) Active Coatings for Smart Textiles. Woodhead Publishing Series in Textiles, 179-220.
  • Cheng S. Y., Yuen C. W. M., Kan C. W., Cheuk K. K. L. 2008. Development of Cosmetic Textiles Using Microencapsulation Technology. RJTA 12(4), 41-51.
There are 40 citations in total.

Details

Primary Language English
Subjects Wearable Materials
Journal Section Articles
Authors

Seniha Morsümbül 0000-0002-4929-0681

Emriye Perrin Akçakoca Kumbasar

Project Number 18-TKUAM-003
Publication Date June 30, 2022
Submission Date May 25, 2021
Acceptance Date May 23, 2022
Published in Issue Year 2022 Volume: 32 Issue: 2

Cite

APA Morsümbül, S., & Akçakoca Kumbasar, E. P. (2022). Performance Characteristics in Textile Application of Photochromic Dye Capsules. Textile and Apparel, 32(2), 155-161. https://doi.org/10.32710/tekstilvekonfeksiyon.942566

No part of this journal may be reproduced, stored, transmitted or disseminated in any forms or by any means without prior written permission of the Editorial Board. The views and opinions expressed here in the articles are those of the authors and are not the views of Tekstil ve Konfeksiyon and Textile and Apparel Research-Application Center.