Research Article
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Investigation of Anti-Pilling Properties of Different Fabrics Applied with Polyvinylcaprolactam

Year 2023, Volume: 33 Issue: 1, 77 - 87, 31.03.2023
https://doi.org/10.32710/tekstilvekonfeksiyon.1034833

Abstract

Pilling is one of the most important problems in the textile industry still not confidently solved. The problem is a kind of mechanically caused fabric defect consisting by a series of roughly spherical masses of entangled fibers called pills. Many studies have been carried out to define this problem in detail, determine the pilling intensity by different methods and improve the pilling grades of fabrics. One of the most beneficial methods to improve values is chemical finishing by applying specific polymers. In this study, a specific synthesized anti-pilling polymer was used for chemical finishing by padding method. A specific polymer based on polyvinylcaprolactam (PVCL) was synthesized and applied on the fabrics. The polymer has been characterized with FT-IR, NMR, DSC, elemental analysis devices also to optimize application-parameters. Especially pilling grades of blended fabrics of natural and synthetic staple fibres are often worser then other non blended fabrics, PVCL polymer was applied on a selection of different polyester cotton blends or polyester viscose blend, which have pilling values between 2-3. PVCL-Polymer applications were carried out by using these 7 different fabrics. As a result, approximately 1.5-2 pilling degree improvement was achieved. Anti-pilling polymers applied on the fabrics used to improve pilling values often decrease hydrophilicity values of the fabrics and worsen touch. However, the specific PVCL-polymer does not lead to a loss of smooth hand neighter to a loss of smooth fabric touch. On the contrary, it improves both hydrophilicity and smooth touch not causing fabric yellowing. PCVL is distinguished from other products used for pilling improvement in the textile industry.

Supporting Institution

TUBITAK TEYDEB

Project Number

3170840

Thanks

This work was supported by the [TUBITAK-TEYDEB] under Grant [number 3170840]. It was carried out in cooperation with Uludağ University-Rudolf Duraner. The authors would like to express their gratitude to the Rudolf-Duraner firm for providing the necessary textiles and supplies for the project, as well as a wide range of options and devices for textile applications of the synthesized polymers. This research has been the subject of a patent application. The study has successfully completed a pre-evaluation phase (with the patent number: PT2019-00086).

References

  • 1. Oğlakçıoğlu N, Marmaralı A. 2007. Thermal comfort properties of some knitted structures. Fibres&Textiles in Eastern Europe 15(5-6), 94-96.
  • 2. Türker E, Dönmez ET, Turan NY. Measurement of pilling occured on textile surfaces by image process. İleri Teknoloji Bilimleri Dergisi 6(1).
  • 3. Tomasino C. 1992. Chemistry-Technology of Fabric Preparation & Finishing. Department of Textile Engineering, Chemistry & Science College of Textiles, North Carolina State University.
  • 4. Telli A. 2019. An image processing research consistent with standard photographs to determine pilling grade of woven fabrics. Tekstil ve Konfeksiyon 29(1), 268-276.
  • 5. Ukponmwan JO, Mukhopadhyay A, Chatterjee KN. 1998. Pilling. Text. Prog. 28, 40.
  • 6. Man L, Raymand W. 2009. Mechanisms of pilling formation and reduction by attrition methods. The Hong Kong Polytechnic University Institute of Textiles & Clothing, Hong Kong.
  • 7. Başyiğit ZO. 2018. Effects of chemical and surface modification on mechanical and chemical properties of polyester fabrics. Düzce University Journal of Science & Technology 6, 1344-1353.
  • 8. Sivakumar VR, Pillay KPR. 1981. Study of pilling in polyester/cotton blended fabrics. Ind. J. Text. Res. 6, 22.
  • 9. Li L, Jia G, Zhou W. 2009. Effect of yarn properties on the pilling of cashmere treated fabric. Fibres &Textiles in Eastern Europe 17, 76- 79.
  • 10. Yahya C, Akaydın M. 2013. Effects on laundering process on pilling characteristic of cotton plain fabric. Pamukkale University Journal of Engineering Sciences 19, 4.
  • 11. Zhang J, Wang X. 2008. Objective pilling evaluation of wool fabrics. Textile Research Journal 77(12), 929–936. https://doi.org/10.1177/0040517507083522
  • 12. Wang XY, Gong RH, Dong Z, Porat I. 2007. Abrasion resistance of thermally bonded 3D nonwoven fabrics. Science Direct, Wear 262, 424–431.
  • 13. Dalbaşı ES, Kayseri GÖ. 2015. Research about the effect of the anti-pilling treatments on different structured cotton knitted fabrics. Tekstil ve Konfeksiyon 25, 54-60.
  • 14. Nihat C, Değirmenci Z, Kaynak HK. 2010. Effect of nano-silicone softener on abrasion and pilling resistance and color fastness of knitted fabrics. Tekstil ve Konfeksiyon 20(1), 41-47.
  • 15. Tusief MQ, Mahmood N, Saleem M. 2012. Effect of different anti-pilling agents to reduce pilling on polyester/cotton fabric. Journal Of The Chemical Society Of Pakistan 34(1), 53-57.
  • 16. Abril HC, Millan MS, Torres Y. 1998. Automatic Method Based on Image Analysis For Pilling Evaluation In Fabrics. Opt. Eng 37(11), 2937–2947.
  • 17. Kowalczyk D, Brzezinski S, Kaminska I. 2015. Multifunctional bioactive and improving the performance durability nanocoatings for finishing PET/CO woven fabrics by the solgel method. Journal of Alloys and Compounds 649, 387-393.
  • 18. Hashemikia S, Montazer M. 2012. Sodium hypophosphite and nano TiO2 inorganic catalysts along with citric acid on textile producing multi-functional properties. Applied Catalysis A: General 417-418, 200-208.
  • 19. Kulyk I, Scapinello M, Stefan M. 2012. Generation of nano roughness on fibrous materials by atmospheric plasma, 12th High-Tech Plasma Processes Conference (HTPP-12), Journal of Physics. https://doi.org/:10.1088/1742-6596/406/1/012015 20. Tusief MQ, Mahmood N, Amin N. 2012. Fabric tensile strength as affected by different anti-pilling agents at various concentration and ph levels. Journal of The Chemical Society of Pakistan 34(1), 53-57.
  • 21. Montazer M, Mazaheri F, Khosravian SH, Azimi M, Bameni M, Sadeghi AH. 2011. Application of resins and crosslinking agents on fiber blend fabric to reduce pilling performance. Optimized by Response Surface Methodology. Society of Plastics Engineers, Journal of Vınyl&Additive Technology. https://doi.org/:10.1002/vnl.20274
  • 22. Mavruz S, Oğulata R. 2009. Biyoparlatma uygulanmış örme kumaşlara tekrarlı (çoklu) yıkamaların etkisinin incelenmesi. Tekstil ve Konfeksiyon 3, 224-230. 23. Bahtiyari MI, Duran K, Körlü AE. 2010. Usage of commercial cellulases in biopolishing of viscose fabrics. Tekstil ve Konfeksiyon 20(1), 57-54.
  • 24. Körlü AE., Duran K, Bahtiyari Mİ, Perinçek S. 2008. The Effects Of Cellulase Enzymes On Cellulosic Fabrics. Tekstil ve Konfeksiyon 18(1), 35-41.
  • 25. Ming Yu M, Wang Z, Lv M, Hao R, Zhao R, Qi L, Liu S, Yu C, Zhang B, Fan C, Li J. 2016. Antisuperbug Cotton Fabric with Excellent Laundering Durability. ACS Appl. Mater. Interfaces 8, 19866-19871.
  • 26. Bui HM, Enhrhardt A, Bechtold T. 2008. Pilling in cellulosic fabrics, part 2: A study on kinetics of pilling in alkali-treated lyocell fabrics. Journal of Applied Polymer Science 109, 3696-3703. 27. Kertmen M, Marmaralı A. 2019. Örme Kumaşlarda Sürdürebilirlik için Boncuklanma ve Patlama Mukavemet Özelliklerinin Değerlendirilmesi. 17th International The Recent Progress Symposium On Textile Technology And Chemistry, Bursa.
  • 28. Usanmaz A, Özdemir T, Polat O. 2009. Solid state polymerization of N-vinylcaprolactam via gamma irradiation and characterization. Journal of Macromolecular Science, Part A 46(6), 597-606.
  • 29. Kozanoğlu S, Özdemir T, Usanmaz A. 2011. Polymerization of N-Vinylcaprolactam and Characterization of Poly(N-Vinylcaprolactam). Journal of Macromolecular Science, Part A, Pure and Applied Chemistry 48, 467–477.
Year 2023, Volume: 33 Issue: 1, 77 - 87, 31.03.2023
https://doi.org/10.32710/tekstilvekonfeksiyon.1034833

Abstract

Project Number

3170840

References

  • 1. Oğlakçıoğlu N, Marmaralı A. 2007. Thermal comfort properties of some knitted structures. Fibres&Textiles in Eastern Europe 15(5-6), 94-96.
  • 2. Türker E, Dönmez ET, Turan NY. Measurement of pilling occured on textile surfaces by image process. İleri Teknoloji Bilimleri Dergisi 6(1).
  • 3. Tomasino C. 1992. Chemistry-Technology of Fabric Preparation & Finishing. Department of Textile Engineering, Chemistry & Science College of Textiles, North Carolina State University.
  • 4. Telli A. 2019. An image processing research consistent with standard photographs to determine pilling grade of woven fabrics. Tekstil ve Konfeksiyon 29(1), 268-276.
  • 5. Ukponmwan JO, Mukhopadhyay A, Chatterjee KN. 1998. Pilling. Text. Prog. 28, 40.
  • 6. Man L, Raymand W. 2009. Mechanisms of pilling formation and reduction by attrition methods. The Hong Kong Polytechnic University Institute of Textiles & Clothing, Hong Kong.
  • 7. Başyiğit ZO. 2018. Effects of chemical and surface modification on mechanical and chemical properties of polyester fabrics. Düzce University Journal of Science & Technology 6, 1344-1353.
  • 8. Sivakumar VR, Pillay KPR. 1981. Study of pilling in polyester/cotton blended fabrics. Ind. J. Text. Res. 6, 22.
  • 9. Li L, Jia G, Zhou W. 2009. Effect of yarn properties on the pilling of cashmere treated fabric. Fibres &Textiles in Eastern Europe 17, 76- 79.
  • 10. Yahya C, Akaydın M. 2013. Effects on laundering process on pilling characteristic of cotton plain fabric. Pamukkale University Journal of Engineering Sciences 19, 4.
  • 11. Zhang J, Wang X. 2008. Objective pilling evaluation of wool fabrics. Textile Research Journal 77(12), 929–936. https://doi.org/10.1177/0040517507083522
  • 12. Wang XY, Gong RH, Dong Z, Porat I. 2007. Abrasion resistance of thermally bonded 3D nonwoven fabrics. Science Direct, Wear 262, 424–431.
  • 13. Dalbaşı ES, Kayseri GÖ. 2015. Research about the effect of the anti-pilling treatments on different structured cotton knitted fabrics. Tekstil ve Konfeksiyon 25, 54-60.
  • 14. Nihat C, Değirmenci Z, Kaynak HK. 2010. Effect of nano-silicone softener on abrasion and pilling resistance and color fastness of knitted fabrics. Tekstil ve Konfeksiyon 20(1), 41-47.
  • 15. Tusief MQ, Mahmood N, Saleem M. 2012. Effect of different anti-pilling agents to reduce pilling on polyester/cotton fabric. Journal Of The Chemical Society Of Pakistan 34(1), 53-57.
  • 16. Abril HC, Millan MS, Torres Y. 1998. Automatic Method Based on Image Analysis For Pilling Evaluation In Fabrics. Opt. Eng 37(11), 2937–2947.
  • 17. Kowalczyk D, Brzezinski S, Kaminska I. 2015. Multifunctional bioactive and improving the performance durability nanocoatings for finishing PET/CO woven fabrics by the solgel method. Journal of Alloys and Compounds 649, 387-393.
  • 18. Hashemikia S, Montazer M. 2012. Sodium hypophosphite and nano TiO2 inorganic catalysts along with citric acid on textile producing multi-functional properties. Applied Catalysis A: General 417-418, 200-208.
  • 19. Kulyk I, Scapinello M, Stefan M. 2012. Generation of nano roughness on fibrous materials by atmospheric plasma, 12th High-Tech Plasma Processes Conference (HTPP-12), Journal of Physics. https://doi.org/:10.1088/1742-6596/406/1/012015 20. Tusief MQ, Mahmood N, Amin N. 2012. Fabric tensile strength as affected by different anti-pilling agents at various concentration and ph levels. Journal of The Chemical Society of Pakistan 34(1), 53-57.
  • 21. Montazer M, Mazaheri F, Khosravian SH, Azimi M, Bameni M, Sadeghi AH. 2011. Application of resins and crosslinking agents on fiber blend fabric to reduce pilling performance. Optimized by Response Surface Methodology. Society of Plastics Engineers, Journal of Vınyl&Additive Technology. https://doi.org/:10.1002/vnl.20274
  • 22. Mavruz S, Oğulata R. 2009. Biyoparlatma uygulanmış örme kumaşlara tekrarlı (çoklu) yıkamaların etkisinin incelenmesi. Tekstil ve Konfeksiyon 3, 224-230. 23. Bahtiyari MI, Duran K, Körlü AE. 2010. Usage of commercial cellulases in biopolishing of viscose fabrics. Tekstil ve Konfeksiyon 20(1), 57-54.
  • 24. Körlü AE., Duran K, Bahtiyari Mİ, Perinçek S. 2008. The Effects Of Cellulase Enzymes On Cellulosic Fabrics. Tekstil ve Konfeksiyon 18(1), 35-41.
  • 25. Ming Yu M, Wang Z, Lv M, Hao R, Zhao R, Qi L, Liu S, Yu C, Zhang B, Fan C, Li J. 2016. Antisuperbug Cotton Fabric with Excellent Laundering Durability. ACS Appl. Mater. Interfaces 8, 19866-19871.
  • 26. Bui HM, Enhrhardt A, Bechtold T. 2008. Pilling in cellulosic fabrics, part 2: A study on kinetics of pilling in alkali-treated lyocell fabrics. Journal of Applied Polymer Science 109, 3696-3703. 27. Kertmen M, Marmaralı A. 2019. Örme Kumaşlarda Sürdürebilirlik için Boncuklanma ve Patlama Mukavemet Özelliklerinin Değerlendirilmesi. 17th International The Recent Progress Symposium On Textile Technology And Chemistry, Bursa.
  • 28. Usanmaz A, Özdemir T, Polat O. 2009. Solid state polymerization of N-vinylcaprolactam via gamma irradiation and characterization. Journal of Macromolecular Science, Part A 46(6), 597-606.
  • 29. Kozanoğlu S, Özdemir T, Usanmaz A. 2011. Polymerization of N-Vinylcaprolactam and Characterization of Poly(N-Vinylcaprolactam). Journal of Macromolecular Science, Part A, Pure and Applied Chemistry 48, 467–477.
There are 26 citations in total.

Details

Primary Language English
Subjects Wearable Materials
Journal Section Articles
Authors

Ali Kara 0000-0003-2457-6314

Burcu Büyükkoru

Project Number 3170840
Early Pub Date March 28, 2023
Publication Date March 31, 2023
Submission Date December 9, 2021
Acceptance Date November 23, 2022
Published in Issue Year 2023 Volume: 33 Issue: 1

Cite

APA Kara, A., & Büyükkoru, B. (2023). Investigation of Anti-Pilling Properties of Different Fabrics Applied with Polyvinylcaprolactam. Textile and Apparel, 33(1), 77-87. https://doi.org/10.32710/tekstilvekonfeksiyon.1034833

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