Research Article
BibTex RIS Cite

EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES

Year 2020, Volume: 6 Issue: 3, 204 - 213, 01.04.2020
https://doi.org/10.18186/thermal.711324

Abstract

During the last decades, the importance of structural parameters has been increased because the models which have been developed using structural parameter can define the gasification process effectively. In this study, structural parameters, rates of conversion and activation energies of Zonguldak coal and Beypazari lignite have obtained. The samples of Zonguldak coal and Beypazari lignite used in this study have different characteristics. Pore dimensions, distribution of pores and surface areas were used as structural parameters. Suitable kinetic parameters were determined by fitting the gasification model to experimental data. The random pore model was used to define these kinetic parameters. The data were taken from experiments of Balci and Durusoy and the results obtained from Zonguldak coal and Beypazarı lignite pyrolysed in a vertical tube heated from outside by an inert gas and gasified with steam at elevated temperatures (between 700 °C and 1000 °C) were used in the model.

References

  • [1] Gaye ÖÇ, Hayrettin Y, Gürüz AG. Physical and chemical properties of selected Turkish lignites and their pyrolysis and gasification rates determined by thermogravimetric analysis. J. Anal. Appl. Pyrolysis; 2007;80:262−268. https://doi.org/10.1016/j.jaap.2007.03.005
  • [2] Zhang Y, Ashizawa M, Kajitani S, Miura K. Proposal of a semi-empirical kinetic model to reconcile with gasification reactivity profiles of biomass chars. Fuel 2008;87:475-481.
  • [3] Watanabe H, Otaka M, Numerical simulation of coal gasification in entrained flow coal gasifier. Fuel 2006;85:1935-1943. https://doi.org/10.1016/j.fuel.2007.04.026
  • [4] Zou JH, Zhou ZJ, Wang FC, Zhang W, Dai ZH, Liu HF, Yu ZH. Modeling reaction kinetics of petroleum coke gasification with CO2. Chemical Eng. and Proc. 2007;46:630–636. https://doi.org/10.1016/j.cep.2006.08.008
  • [5] Xu S, Zhou Z, Gao X, Yu G, Gong X. The gasification reactivity of unburned carbon present in gasification slag from entrained-flow gasifier. Fuel 2009;90:1062-1070. https://doi.org/10.1016/j.fuproc.2009.04.006
  • [6] Fermoso J, Arias B, Pevida C, Plaza MG, Rubiera F, Pis JJ. Kinetic Models Comparison for Steam Gasification of Different Nature Fuel Chars. Journal of Thermal Analysis and Calorimetry, 2008;91:779–786. https://doi.org/10.1007/s10973-007-8623-5
  • [7] De Micco G, Nasjleti A, Bohé AE. Kinetics of the gasification of a Rio Turbio coal under different pyrolysis temperatures. Fuel 2012;95:537-543. https://doi.org/10.1016/j.fuel.2011.12.057
  • [8] Liu TF, Fang YT, Wang Y. An experimental investigation into the gasification reactivity of chars prepared at high temperatures. Fuel 2008;87:460–466. https://doi.org/10.1016/j.fuel.2007.06.019
  • [9] Liu H, Luo C, Kato S, Uemiya S, Kaneko M, Kojima T. Kinetics of CO2/Char gasification at elevated temperatures Part I: Experimental results. Fuel Processing Technology 2006;87:775–781.
  • [10] Matsumoto K, Takeno K, Ichinose T, Ogi T, Nakanishi M. Gasification reaction kinetics on biomass char obtained as by-product of gasification in an entrained-flow gasifier with steam and oxygen at 900–1000 °C. Fuel 2009;88:519-527. https://doi.org/10.1016/j.fuel.2008.09.022
  • [11] Everson RC, Neomagus HW, Kaitano R, Falcon R, Van Alphen C, Cann V. Properties of high ash coal-char particles derived from inertinite-rich coal: II. Gasification kinetics with carbon dioxide. Fuel 2008;87:3403–08. https://doi.org/10.1016/j.fuel.2008.05.019
  • [12] Kajitani S, Suzuki N, Ashizawa M, Hara S. CO2 gasification rate analysis of coal char in entrained flow coal gasifier. Fuel 2006;85:163-169. https://doi.org/10.1016/j.fuel.2005.07.024
  • [13] Mandapati RN, Daggupati S, Mahajani SM, Aghalayam P, Sapru RK, Sharma RK, Ganesh A. Experiments and kinetic modeling for CO2 gasification of Indian coal chars in the context of underground coal gasification. Industrial & Engineering Chemistry Research 2012;51:15041-52. https://doi.org/10.1021/ie3022434
  • [14] Levenspiel O. Chemical Reaction Engineering, 3rd ed. Wiley: New York; 1998;41−42
  • [15] Levenspiel O. Chemical Reaction Engineering, 3rd ed. Wiley: New York; 1998;575−576.
  • [16] Gupta JS, Bhatia SK. A modified discrete random pore model allowing for different initial surface reactivity. Carbon 2000;38:47-58. https://doi.org/10.1016/S0008-6223(99)00095-0
  • [17] Feng B, Bhatia SK. On the validity of thermogravimetric determination of carbon gasification kinetics. Chemical Engineering Science 2002;57:2907-2920. https://doi.org/10.1016/S0009-2509(02)00189-6
  • [18] Feng B, Bhatia SK. Variation of the pore structure of coal chars during gasification. Carbon 2003;41:507-523. https://doi.org/10.1016/S0008-6223(02)00357-3
  • [19] Bhatia SK, Perlmutter DD. A random pore model for fluid solid reactions: part I. Isothermal, kinetic control. AIChE Journal 1980;26:379-86.
  • [20] Bhatia SK, Perlmutter DD. A random pore model for fluid solid reactions: part II. Diffusion and transport effects. AIChE J. 1981;27:247−254.
  • [21] Koyun A. Pyrolysis and gasification of low valence Turkish lignites. PhD Thesis, Turkey, 1992.
  • [22] Durusoy T. Turkey, Examination of the carbonization product of some Turkish lignite. PhD Thesis, 1989.
  • [23] Balcı S. Turkey, Kinetics of activated carbon production from almond shell, hazelnut shell and beech wood and characterization of products. PhD Thesis, 1985.
  • [24] Keller F, Küster F, Meyer B. Determination of coal gasification kinetics from integral drop tube furnace experiments with steam and CO2. Fuel 2018;218:425-438. https://doi.org/10.1016/j.fuel.2017.11.120
  • [25] Gao X., Zhang Y, Li B, Zhao Y, Jiang B. Determination of the intrinsic reactivity for carbon dioxide gasification of rice husk chars using random pore model. Bioresource technology 2016;218:1073-1081. https://doi.org/10.1016/j.biortech.2016.07.057
  • [26] Jayaraman K, Gökalp I, Jeyakumar S. Estimation of synergetic effects of CO2 in high ash coal-char steam gasification. Applied Thermal Eng. 2017;110,991-998. https://doi.org/10.1016/j.applthermaleng.2016.09.011
  • [27] Tanner J, Bhattacharya S. Kinetics of CO2 and steam gasification of Victorian brown coal chars. Chemical Engineering Journal 2016;285,331-340. https://doi.org/10.1016/j.cej.2015.09.106
  • [28] Samdani G, Ganesh A, Aghalayam P, Sapru, RK, Mahajani S. Kinetics of heterogeneous reactions with coal in context of underground coal gasification. Fuel 2017;199,102-114. https://doi.org/10.1016/j.fuel.2017.02.088
  • [29] Prabhakar A, Sadhukhan AK, Kamila, B, Gupta P. Modeling and Experimental Studies on CO2 Gasification of Coal Char Particle. Energy & Fuels 2017;31(3):2652-2662. https://doi.org/10.1021/acs.energyfuels.6b03241
  • [30] Coetzee GH, Sakurovs R, Neomagus HW, Everson RC, Mathews JP, Bunt JR. Particle size influence on the pore development of nanopores in coal gasification chars: From micron to millimeter particles. Carbon 2017;112: 37-46. https://doi.org/10.1016/j.carbon.2016.10.088
  • [31] Gouws SM, Neomagus HW, Roberts DG, Bunt JR, Everson RC. The effect of CO2 partial pressure on the gasification rate and pore development of Highveld coal chars at elevated pressures. Fuel Processing Technology 2018;179:1-9. https://doi.org/10.1016/j.fuproc.2018.05.027
Year 2020, Volume: 6 Issue: 3, 204 - 213, 01.04.2020
https://doi.org/10.18186/thermal.711324

Abstract

References

  • [1] Gaye ÖÇ, Hayrettin Y, Gürüz AG. Physical and chemical properties of selected Turkish lignites and their pyrolysis and gasification rates determined by thermogravimetric analysis. J. Anal. Appl. Pyrolysis; 2007;80:262−268. https://doi.org/10.1016/j.jaap.2007.03.005
  • [2] Zhang Y, Ashizawa M, Kajitani S, Miura K. Proposal of a semi-empirical kinetic model to reconcile with gasification reactivity profiles of biomass chars. Fuel 2008;87:475-481.
  • [3] Watanabe H, Otaka M, Numerical simulation of coal gasification in entrained flow coal gasifier. Fuel 2006;85:1935-1943. https://doi.org/10.1016/j.fuel.2007.04.026
  • [4] Zou JH, Zhou ZJ, Wang FC, Zhang W, Dai ZH, Liu HF, Yu ZH. Modeling reaction kinetics of petroleum coke gasification with CO2. Chemical Eng. and Proc. 2007;46:630–636. https://doi.org/10.1016/j.cep.2006.08.008
  • [5] Xu S, Zhou Z, Gao X, Yu G, Gong X. The gasification reactivity of unburned carbon present in gasification slag from entrained-flow gasifier. Fuel 2009;90:1062-1070. https://doi.org/10.1016/j.fuproc.2009.04.006
  • [6] Fermoso J, Arias B, Pevida C, Plaza MG, Rubiera F, Pis JJ. Kinetic Models Comparison for Steam Gasification of Different Nature Fuel Chars. Journal of Thermal Analysis and Calorimetry, 2008;91:779–786. https://doi.org/10.1007/s10973-007-8623-5
  • [7] De Micco G, Nasjleti A, Bohé AE. Kinetics of the gasification of a Rio Turbio coal under different pyrolysis temperatures. Fuel 2012;95:537-543. https://doi.org/10.1016/j.fuel.2011.12.057
  • [8] Liu TF, Fang YT, Wang Y. An experimental investigation into the gasification reactivity of chars prepared at high temperatures. Fuel 2008;87:460–466. https://doi.org/10.1016/j.fuel.2007.06.019
  • [9] Liu H, Luo C, Kato S, Uemiya S, Kaneko M, Kojima T. Kinetics of CO2/Char gasification at elevated temperatures Part I: Experimental results. Fuel Processing Technology 2006;87:775–781.
  • [10] Matsumoto K, Takeno K, Ichinose T, Ogi T, Nakanishi M. Gasification reaction kinetics on biomass char obtained as by-product of gasification in an entrained-flow gasifier with steam and oxygen at 900–1000 °C. Fuel 2009;88:519-527. https://doi.org/10.1016/j.fuel.2008.09.022
  • [11] Everson RC, Neomagus HW, Kaitano R, Falcon R, Van Alphen C, Cann V. Properties of high ash coal-char particles derived from inertinite-rich coal: II. Gasification kinetics with carbon dioxide. Fuel 2008;87:3403–08. https://doi.org/10.1016/j.fuel.2008.05.019
  • [12] Kajitani S, Suzuki N, Ashizawa M, Hara S. CO2 gasification rate analysis of coal char in entrained flow coal gasifier. Fuel 2006;85:163-169. https://doi.org/10.1016/j.fuel.2005.07.024
  • [13] Mandapati RN, Daggupati S, Mahajani SM, Aghalayam P, Sapru RK, Sharma RK, Ganesh A. Experiments and kinetic modeling for CO2 gasification of Indian coal chars in the context of underground coal gasification. Industrial & Engineering Chemistry Research 2012;51:15041-52. https://doi.org/10.1021/ie3022434
  • [14] Levenspiel O. Chemical Reaction Engineering, 3rd ed. Wiley: New York; 1998;41−42
  • [15] Levenspiel O. Chemical Reaction Engineering, 3rd ed. Wiley: New York; 1998;575−576.
  • [16] Gupta JS, Bhatia SK. A modified discrete random pore model allowing for different initial surface reactivity. Carbon 2000;38:47-58. https://doi.org/10.1016/S0008-6223(99)00095-0
  • [17] Feng B, Bhatia SK. On the validity of thermogravimetric determination of carbon gasification kinetics. Chemical Engineering Science 2002;57:2907-2920. https://doi.org/10.1016/S0009-2509(02)00189-6
  • [18] Feng B, Bhatia SK. Variation of the pore structure of coal chars during gasification. Carbon 2003;41:507-523. https://doi.org/10.1016/S0008-6223(02)00357-3
  • [19] Bhatia SK, Perlmutter DD. A random pore model for fluid solid reactions: part I. Isothermal, kinetic control. AIChE Journal 1980;26:379-86.
  • [20] Bhatia SK, Perlmutter DD. A random pore model for fluid solid reactions: part II. Diffusion and transport effects. AIChE J. 1981;27:247−254.
  • [21] Koyun A. Pyrolysis and gasification of low valence Turkish lignites. PhD Thesis, Turkey, 1992.
  • [22] Durusoy T. Turkey, Examination of the carbonization product of some Turkish lignite. PhD Thesis, 1989.
  • [23] Balcı S. Turkey, Kinetics of activated carbon production from almond shell, hazelnut shell and beech wood and characterization of products. PhD Thesis, 1985.
  • [24] Keller F, Küster F, Meyer B. Determination of coal gasification kinetics from integral drop tube furnace experiments with steam and CO2. Fuel 2018;218:425-438. https://doi.org/10.1016/j.fuel.2017.11.120
  • [25] Gao X., Zhang Y, Li B, Zhao Y, Jiang B. Determination of the intrinsic reactivity for carbon dioxide gasification of rice husk chars using random pore model. Bioresource technology 2016;218:1073-1081. https://doi.org/10.1016/j.biortech.2016.07.057
  • [26] Jayaraman K, Gökalp I, Jeyakumar S. Estimation of synergetic effects of CO2 in high ash coal-char steam gasification. Applied Thermal Eng. 2017;110,991-998. https://doi.org/10.1016/j.applthermaleng.2016.09.011
  • [27] Tanner J, Bhattacharya S. Kinetics of CO2 and steam gasification of Victorian brown coal chars. Chemical Engineering Journal 2016;285,331-340. https://doi.org/10.1016/j.cej.2015.09.106
  • [28] Samdani G, Ganesh A, Aghalayam P, Sapru, RK, Mahajani S. Kinetics of heterogeneous reactions with coal in context of underground coal gasification. Fuel 2017;199,102-114. https://doi.org/10.1016/j.fuel.2017.02.088
  • [29] Prabhakar A, Sadhukhan AK, Kamila, B, Gupta P. Modeling and Experimental Studies on CO2 Gasification of Coal Char Particle. Energy & Fuels 2017;31(3):2652-2662. https://doi.org/10.1021/acs.energyfuels.6b03241
  • [30] Coetzee GH, Sakurovs R, Neomagus HW, Everson RC, Mathews JP, Bunt JR. Particle size influence on the pore development of nanopores in coal gasification chars: From micron to millimeter particles. Carbon 2017;112: 37-46. https://doi.org/10.1016/j.carbon.2016.10.088
  • [31] Gouws SM, Neomagus HW, Roberts DG, Bunt JR, Everson RC. The effect of CO2 partial pressure on the gasification rate and pore development of Highveld coal chars at elevated pressures. Fuel Processing Technology 2018;179:1-9. https://doi.org/10.1016/j.fuproc.2018.05.027
There are 31 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Ömer Faruk Güney This is me 0000-0003-3107-9199

Ahmet Koyun This is me 0000-0002-5527-4151

Publication Date April 1, 2020
Submission Date May 29, 2018
Published in Issue Year 2020 Volume: 6 Issue: 3

Cite

APA Güney, Ö. F., & Koyun, A. (2020). EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES. Journal of Thermal Engineering, 6(3), 204-213. https://doi.org/10.18186/thermal.711324
AMA Güney ÖF, Koyun A. EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES. Journal of Thermal Engineering. April 2020;6(3):204-213. doi:10.18186/thermal.711324
Chicago Güney, Ömer Faruk, and Ahmet Koyun. “EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES”. Journal of Thermal Engineering 6, no. 3 (April 2020): 204-13. https://doi.org/10.18186/thermal.711324.
EndNote Güney ÖF, Koyun A (April 1, 2020) EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES. Journal of Thermal Engineering 6 3 204–213.
IEEE Ö. F. Güney and A. Koyun, “EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES”, Journal of Thermal Engineering, vol. 6, no. 3, pp. 204–213, 2020, doi: 10.18186/thermal.711324.
ISNAD Güney, Ömer Faruk - Koyun, Ahmet. “EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES”. Journal of Thermal Engineering 6/3 (April 2020), 204-213. https://doi.org/10.18186/thermal.711324.
JAMA Güney ÖF, Koyun A. EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES. Journal of Thermal Engineering. 2020;6:204–213.
MLA Güney, Ömer Faruk and Ahmet Koyun. “EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES”. Journal of Thermal Engineering, vol. 6, no. 3, 2020, pp. 204-13, doi:10.18186/thermal.711324.
Vancouver Güney ÖF, Koyun A. EXPERIMENTAL ANALYSIS AND KINETIC MODELLING FOR STEAM GASIFICATION OF THE TURKISH LIGNITES. Journal of Thermal Engineering. 2020;6(3):204-13.

IMPORTANT NOTE: JOURNAL SUBMISSION LINK http://eds.yildiz.edu.tr/journal-of-thermal-engineering