Year 2025,
Volume: 9 Issue: 2, 49 - 57, 29.08.2025
Lütfi Erden
,
Hanife Erden
,
Ceren Aydın
Project Number
1919B012320029
References
-
BYrne, B., Liu, J., Bowman, K. W., Pascolini-Campbell, M., Chatterjee, A., Pandey, S., Miyazaki, K., van der Werf, G. R., Wunch, D., Wennberg, P. O., Roehl, C. M., & Sinha, S. (2024). Carbon emissions from the 2023 Canadian wildfires. Nature, 633, 835-839. https://doi.Org/l0.1038/s 41586-024-07878-z google scholar
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Cazetta, A. L., Vargas, A. M. M., Nogami, E. M., Kunita, M. H., Guilherme, M. R., Martins, A. C., Silva, T. L., Moraes, J. C. G., & Almeida, V. C. (2011). NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methYl-ene blue adsorption. Chemical Engineering Journal, 174(i), 117-125. https://doi.org/10.1016/j.cej.2011.08.058 google scholar
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Danish, M., Ahmad, T., Hashim, R., Said, N., Akhtar, M. N., Mohamad-Saleh, J., & Sulaiman, O. (2018). Comparison of surface properties of wood biomass activated carbons and their application against rhodamine B and methYlene blue dYe. Surfaces and Interfaces, 11, 1-13. https://doi.org/10.1016/j.surfin.2018.02.001 google scholar
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Ge, Q., Li, P., Liu, M., Xiao, G., Xiao, Z., Mao, J., & Gai, X. (2023). Removal of methYlene blue bY porous biochar obtained bY KOH activation from bamboo biochar. Bioresources and Bioprocessing, 10(1), 51. https://doi.org/l0.1186/s40643-023-00671-2 google scholar
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Ghaedi, M., Nasab, A. G., Khodadoust, S., Rajabi, M., & Azizian, S. (2014). Application of activated carbon as adsorbents for efficient removal of methYlene blue: Kinetics and equilibrium studY. Journal of Industrial and Engineering Chemistry, 20(4), 2317-2324. https://doi. org/10.1016/j.jiec.2013.10.007 google scholar
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Gomez Isaza, D. F., Cramp, R. L., & Franklin, C. E. (2022). Fire and rain: A sYstematic review of the impacts of wildfire and associated runoff on aquatic fauna. In Global Change Biology, 28(8), 2578-2595). https://doi.org/10.1111/gcb.16088 google scholar
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OladoYe, P. O., AjiboYe, T. O., Omotola, E. O., & OYewola, O. J. (2022). Meth-Ylene blue dYe: ToxicitY and potential elimination technologY from wastewater. Results in Engineering, 16, 100678. https://doi.org/10. 1016/j.rineng.2022.100678 google scholar
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Song, J., Zou, W., Bian, Y., Su, F., & Han, R. (2011). Adsorption character-istics of methYlene blue bY peanut husk in batch and column modes. Desalination, 265(1-3), 119-125. https://doi.org/10.1016/j. desal.2010.07.041 google scholar
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Suârez-Ruiz, I., & Crelling, J. C. (2008). Coal-Derived Carbon Materials. Applied Coal Petrology: The Role of Petrology in Coal Utilization, 193-225. https://doi.org/l0.1016/B978-0-08-045051-3.00008-7 google scholar
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SupanchaiYamat, N., Jetsrisuparb, K., Knijnenburg, J. T. N., Tsang, D. C. W., & Hunt, A. J. (2019). Lignin materials for adsorption: Current trend, perspectives and opportunities. Bioresource Technology, 570-581. https://doi.org/10.1016/j.biortech.2018.09.139 google scholar
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Tan, X., Liu, S., Liu, Y., Gu, Y., Zeng, G., Hu, X., Wang, X., Liu, S., & Jiang, L. (2017). Biochar as potential sustainable precursors for activated carbon production: Multiple Applications in environmental protec-tion and energY storage. Bioresource Technology, 227, 359-372. https://doi.org/10.1016/j.biortech.2016.12.083 google scholar
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TkaczYk, A., Mitrowska, K., & PosYniak, A. (2020). SYnthetic organic dYes as contaminants of the aquatic environment and their implications for ecosystems: A review. Science of the Total Environment, 717, 137222. https://doi.org/10.1016/j.scitotenv.2020.137222 google scholar
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Ying, Z., Chen, X., Li, H., Liu, X., Zhang, C., Zhang, J., & Yi, G. (2021). Efficient adsorption of methylene blue by porous biochar derived from soYbean dreg using a one-pot SYnthesis method. Molecules, 26 (3). https://doi.org/10.3390/molecules26030661 google scholar
A Novel Biochar Approach: Valorization of Wildfire Residual for The Removal of Cationic Dye from Textile Wastewater
Year 2025,
Volume: 9 Issue: 2, 49 - 57, 29.08.2025
Lütfi Erden
,
Hanife Erden
,
Ceren Aydın
Abstract
Objective: The main objective of this study was to reveal the cationic dye (methylene blue) removal performance of activated biochar materials produced from the pine tree (Pinus brutia) wildfire remnants from 2024 Çanakkale Wildfire area.
Materials and Methods: The pine tree (Pinus brutia) wildfire remnant samples were collected from the 2024 Çanakkale Wildfire area. Boric acid and Sodium Hydroxide were used as activation agents on the samples. Then, methylene blue adsorption equilibrium and kinetic studies were conducted to reveal the adsorption performance of the produced biochar adsorbent. The adsorption capacity, adsorption isotherms, and kinetic study experiments were conducted.
Results: The results showed that the Langmuir adsorption isotherm fitted very well with the Sodium Hydroxideactivated biochar samples for the methylene blue adsorption equilibrium experiments. The Methylene Blue Removal percentage of % 96 was reached. The kinetic studies revealed that the pseudo-second-order kinetic model fitted the experimental data well.
Conclusion: The adsorption capacity and percent methylene blue removal performances indicated that the produced activated carbons have competitive adsorption potentials in relation to the literature data.
Ethical Statement
The authors declare that no ethics committee approval is required for this study.
Supporting Institution
TÜBİTAK-2209-A
Project Number
1919B012320029
Thanks
The authors thank to TÜBİTAK for the financial support.
References
-
BYrne, B., Liu, J., Bowman, K. W., Pascolini-Campbell, M., Chatterjee, A., Pandey, S., Miyazaki, K., van der Werf, G. R., Wunch, D., Wennberg, P. O., Roehl, C. M., & Sinha, S. (2024). Carbon emissions from the 2023 Canadian wildfires. Nature, 633, 835-839. https://doi.Org/l0.1038/s 41586-024-07878-z google scholar
-
Cazetta, A. L., Vargas, A. M. M., Nogami, E. M., Kunita, M. H., Guilherme, M. R., Martins, A. C., Silva, T. L., Moraes, J. C. G., & Almeida, V. C. (2011). NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methYl-ene blue adsorption. Chemical Engineering Journal, 174(i), 117-125. https://doi.org/10.1016/j.cej.2011.08.058 google scholar
-
Danish, M., Ahmad, T., Hashim, R., Said, N., Akhtar, M. N., Mohamad-Saleh, J., & Sulaiman, O. (2018). Comparison of surface properties of wood biomass activated carbons and their application against rhodamine B and methYlene blue dYe. Surfaces and Interfaces, 11, 1-13. https://doi.org/10.1016/j.surfin.2018.02.001 google scholar
-
Ge, Q., Li, P., Liu, M., Xiao, G., Xiao, Z., Mao, J., & Gai, X. (2023). Removal of methYlene blue bY porous biochar obtained bY KOH activation from bamboo biochar. Bioresources and Bioprocessing, 10(1), 51. https://doi.org/l0.1186/s40643-023-00671-2 google scholar
-
Ghaedi, M., Nasab, A. G., Khodadoust, S., Rajabi, M., & Azizian, S. (2014). Application of activated carbon as adsorbents for efficient removal of methYlene blue: Kinetics and equilibrium studY. Journal of Industrial and Engineering Chemistry, 20(4), 2317-2324. https://doi. org/10.1016/j.jiec.2013.10.007 google scholar
-
Gomez Isaza, D. F., Cramp, R. L., & Franklin, C. E. (2022). Fire and rain: A sYstematic review of the impacts of wildfire and associated runoff on aquatic fauna. In Global Change Biology, 28(8), 2578-2595). https://doi.org/10.1111/gcb.16088 google scholar
-
Khan, I., Saeed, K., Zekker, I., Zhang, B., Hendi, A. H., Ahmad, A., Ahmad, S., Zada, N., Ahmad, H., Shah, L. A., Shah, T., & Khan, I. (2022). Review on methYlene blue: Its properties, uses, toxicitY and photodegra-dation. Water, 14(2), 242. https://doi.org/10.3390/w14020242 google scholar
-
Munoz, Y., Arriagada, R., Soto-Garrido, G., & Garcîa, R. (2003). Phosphoric and boric acid activation of pine sawdust. Journal of Chemical Technology and Biotechnology, 78(12), 1252-1258. https://doi.org/ 10.1002/jctb.923 google scholar
-
OladoYe, P. O., AjiboYe, T. O., Omotola, E. O., & OYewola, O. J. (2022). Meth-Ylene blue dYe: ToxicitY and potential elimination technologY from wastewater. Results in Engineering, 16, 100678. https://doi.org/10. 1016/j.rineng.2022.100678 google scholar
-
Orman Mühendisleri Odası Yönetim Kurulu. (2024). https://www,ormuh, org,tr/haberler/orman-yanginlari-ile-ilgili-basin-aciklamasi-417. google scholar
-
Raposo, F., De La Rubia, M. A., & Borja, R. (2009). MethYlene blue number as useful indicator to evaluate the adsorptive capacitY of granular activated carbon in batch mode: Influence of adsorbate/adsorbent mass ratio and particle size. Journal of Hazardous Materials, 165(1-3), 291-299. https://doi.org/10.1016/j.jhazmat.2008.09.106 google scholar
-
Searles Valley Minerals. (2020). Boric Acid Technical Information. google scholar
-
Song, J., Zou, W., Bian, Y., Su, F., & Han, R. (2011). Adsorption character-istics of methYlene blue bY peanut husk in batch and column modes. Desalination, 265(1-3), 119-125. https://doi.org/10.1016/j. desal.2010.07.041 google scholar
-
Suârez-Ruiz, I., & Crelling, J. C. (2008). Coal-Derived Carbon Materials. Applied Coal Petrology: The Role of Petrology in Coal Utilization, 193-225. https://doi.org/l0.1016/B978-0-08-045051-3.00008-7 google scholar
-
SupanchaiYamat, N., Jetsrisuparb, K., Knijnenburg, J. T. N., Tsang, D. C. W., & Hunt, A. J. (2019). Lignin materials for adsorption: Current trend, perspectives and opportunities. Bioresource Technology, 570-581. https://doi.org/10.1016/j.biortech.2018.09.139 google scholar
-
Tan, X., Liu, S., Liu, Y., Gu, Y., Zeng, G., Hu, X., Wang, X., Liu, S., & Jiang, L. (2017). Biochar as potential sustainable precursors for activated carbon production: Multiple Applications in environmental protec-tion and energY storage. Bioresource Technology, 227, 359-372. https://doi.org/10.1016/j.biortech.2016.12.083 google scholar
-
TkaczYk, A., Mitrowska, K., & PosYniak, A. (2020). SYnthetic organic dYes as contaminants of the aquatic environment and their implications for ecosystems: A review. Science of the Total Environment, 717, 137222. https://doi.org/10.1016/j.scitotenv.2020.137222 google scholar
-
Ying, Z., Chen, X., Li, H., Liu, X., Zhang, C., Zhang, J., & Yi, G. (2021). Efficient adsorption of methylene blue by porous biochar derived from soYbean dreg using a one-pot SYnthesis method. Molecules, 26 (3). https://doi.org/10.3390/molecules26030661 google scholar