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Effects of Mineral Additive Substitution on the Fresh State and Time-Dependent Hardened State Properties of Calcium Alumina Cement Mortars

Year 2023, Volume: 34 Issue: 3, 139 - 162, 01.05.2023

Faruk Eren Muhammer Keskinateş Burak Felekoğlu Kamile Tosun Felekoğlu

https://doi.org/10.18400/tjce.1288033
Cited By: 2

Abstract

Calcium aluminate cements (CAC) are a candidate alternative binder to provide the requirements of a repair material such as accelerated hardening, good adhesion, compatibility with existing concrete, dimensional stability and corrosion resistance. The absence of water-soluble hydrated lime among the hydration products can also be accepted as an important advantage. However, the transformation reactions that may occur in the phase structure of the CAC depending on the ambient conditions over time may cause a loss of strength in the concrete produced with this cement. In this study, it is aimed to provide solutions to the problems arising from the conversion reactions in the hydration process of CAC, to improve the fresh state properties and to stabilize the strength development in the long term. Consequently, the effects of using CAC blended with different mineral additives (SiO2 and CaSO4) on the mortar consistency, setting time and rheological properties were investigated. In the hardened state, abrasion resistance and time-dependent compressive and flexural strength developments were determined. As a result of the experimental studies, it was concluded that the CAC mortars containing 16% SiO2 and 50% CaSO4 additives can provide improved properties in their fresh state, and they also demonstrate an improvement in strength after 400 days by obtaining stable products during the hydration process without any time-related strength loss.

Keywords

Calcium aluminate cement mineral additive fresh state properties rheology mechanical strength

References

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Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri

Year 2023, Volume: 34 Issue: 3, 139 - 162, 01.05.2023

Faruk Eren Muhammer Keskinateş Burak Felekoğlu Kamile Tosun Felekoğlu

https://doi.org/10.18400/tjce.1288033
Cited By: 2

Abstract

Kalsiyum alüminat çimentoları (KAÇ) bir onarım malzemesinden beklenen; hızlı sertleşme, iyi yapışma, mevcut betonla uyumluluk, boyutsal kararlılık ve korozyon direnci gibi özellikleri sağlamaya aday bir alternatif bağlayıcıdır. Hidratasyon ürünleri arasında suda çözünür kireç olmaması da önemli bir avantaj olarak görülebilir. Ancak KAÇ’ın zaman içerisinde ortam koşullarına bağlı olarak faz yapısında meydana gelebilen dönüşüm reaksiyonları, bu çimento ile üretilen betonlarda dayanım kaybına neden olabilmektedir. Bu çalışmada KAÇ’ın hidratasyon sürecindeki dönüşüm reaksiyonlarından kaynaklanan problemlere çözüm sunmak, taze hal özelliklerini geliştirmek ve uzun dönemde dayanım gelişimini kararlı hale getirmek amaçlanmıştır. Buna bağlı olarak, farklı mineral katkı kaynaklarının (SiO2 ve CaSO4), KAÇ ile birlikte kullanımının harç kıvamı, priz süresi ve reolojik özelliklere etkileri incelenmiştir. Sertleşmiş halde aşınma dayanıklılığı ve zamana bağlı basınç ve eğilme dayanımı gelişimleri belirlenmiştir. Deneysel çalışmalar sonucunda, %16 SiO2 katkılı ve %50 CaSO4 katkılı KAÇ içeren harçların, taze hal özelliklerinde kullanım alanlarına uygun gelişmiş özellikler kazandırabildiği ve hidratasyon sürecinde kararlı ürünler elde ederek zamana bağlı bir mukavemet kaybına uğramadan, 400 günlük periyot sonunda dayanım gelişimi gösterdiği sonucuna ulaşılmıştır.

Keywords

Kalsiyum alüminat çimentosu mineral katkı taze hal özellikleri reoloji mekanik dayanım

References

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  • A. Macias, A. Kindness, and F. P. Glasser, “Corrosion behaviour of steel in high alumina cement mortar cured at 5, 25 and 55°C: Chemical and physical factors,” J. Mater. Sci., vol. 31, no. 9, pp. 2279–2289, 1996, doi: 10.1007/BF01152936.
  • H. M. Son, S. Park, H. Y. Kim, J. H. Seo, and H. K. Lee, “Effect of CaSO4 on hydration and phase conversion of calcium aluminate cement,” Constr. Build. Mater., vol. 224, pp. 40–47, 2019, doi: 10.1016/j.conbuildmat.2019.07.004.
  • S. Moehmel, W. Gessner, T. A. Bier, and C. Parr, “The influence of microsilica on the course of hydration of monocalcium aluminate,” in In International conference on calcium aluminate cements, 2001, pp. 319–330.
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  • L. Scheinherrová and A. Trník, “Hydration of calcium aluminate cement determined by thermal analysis,” in AIP Conference Proceedings, 2017, doi: 10.1063/1.4994514.
  • M. D. M. Alonso, M. Palacios, and F. Puertas, “Effect of polycarboxylate-ether admixtures on calcium aluminate cement pastes. Part 2: Hydration studies,” Ind. Eng. Chem. Res., vol. 52, no. 49, pp. 17330–1734, 2013, doi: 10.1021/ie401616f.
  • Ş. Alpaslan and K. Tosun-Felekoğlu, “Polikarboksilat Bazlı Süperakışkanlaştırıcıların Kalsiyum Alüminat Çimentosunun Kıvam Koruma Performansı Üzerine Karşılaştırmalı Bir Çalışma,” Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilim. Derg., pp. 140–154, 2019.
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  • O. Akhlaghi, Y. Z. Menceloglu, and O. Akbulut, “Poly(carboxylate ether)-based superplasticizer achieves workability retention in calcium aluminate cement,” Sci. Rep., vol. 7, no. 1, pp. 1–7, 2017, doi: 10.1038/srep41743.
  • H. M. Son, S. M. Park, J. G. Jang, and H. K. Lee, “Effect of nano-silica on hydration and conversion of calcium aluminate cement,” Constr. Build. Mater., vol. 169, pp. 819–825, 2018, doi: 10.1016/j.conbuildmat.2018.03.011.
  • J. Ding, Y. Fu, and J. J. Beaudoin, “Strätlingite formation in high alumina cement - silica fume systems: Significance of sodium ions,” Cem. Concr. Res., vol. 25, no. 6, pp. 1311–1319, 1995, doi: 10.1016/0008-8846(95)00124-U.
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There are 71 citations in total.

Details

Primary Language Turkish
Subjects Civil Engineering
Journal Section Research Articles
Authors

Faruk Eren 0000-0003-4518-0669

Muhammer Keskinateş 0000-0001-8334-3073

Burak Felekoğlu 0000-0002-7426-1698

Kamile Tosun Felekoğlu 0000-0003-2191-7793

Early Pub Date May 3, 2023
Publication Date May 1, 2023
Submission Date July 5, 2022
Published in Issue Year 2023 Volume: 34 Issue: 3

Cite

APA Eren, F., Keskinateş, M., Felekoğlu, B., Tosun Felekoğlu, K. (2023). Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri. Turkish Journal of Civil Engineering, 34(3), 139-162. https://doi.org/10.18400/tjce.1288033
AMA Eren F, Keskinateş M, Felekoğlu B, Tosun Felekoğlu K. Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri. tjce. May 2023;34(3):139-162. doi:10.18400/tjce.1288033
Chicago Eren, Faruk, Muhammer Keskinateş, Burak Felekoğlu, and Kamile Tosun Felekoğlu. “Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal Ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri”. Turkish Journal of Civil Engineering 34, no. 3 (May 2023): 139-62. https://doi.org/10.18400/tjce.1288033.
EndNote Eren F, Keskinateş M, Felekoğlu B, Tosun Felekoğlu K (May 1, 2023) Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri. Turkish Journal of Civil Engineering 34 3 139–162.
IEEE F. Eren, M. Keskinateş, B. Felekoğlu, and K. Tosun Felekoğlu, “Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri”, tjce, vol. 34, no. 3, pp. 139–162, 2023, doi: 10.18400/tjce.1288033.
ISNAD Eren, Faruk et al. “Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal Ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri”. Turkish Journal of Civil Engineering 34/3 (May 2023), 139-162. https://doi.org/10.18400/tjce.1288033.
JAMA Eren F, Keskinateş M, Felekoğlu B, Tosun Felekoğlu K. Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri. tjce. 2023;34:139–162.
MLA Eren, Faruk et al. “Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal Ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri”. Turkish Journal of Civil Engineering, vol. 34, no. 3, 2023, pp. 139-62, doi:10.18400/tjce.1288033.
Vancouver Eren F, Keskinateş M, Felekoğlu B, Tosun Felekoğlu K. Mineral Katkı İkamesinin Kalsiyum Alümina Çimentolu Harçların Taze Hal ve Zamana Bağlı Sertleşmiş Hal Özelliklerine Etkileri. tjce. 2023;34(3):139-62.

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