LiFePO4 Bataryalarda Güncel Çalışmalar

Year 2022, Volume: 1 Issue: 2, 108 - 119, 30.11.2022

Ezgi Tülek Serdar Altın

Abstract

Enerjinin depolanabilmesi; enerji üretimi, iletimi ve dağıtımı kadar önemlidir. Özellikle son yıllarda yapılan çalışmalar enerjinin depolanıp daha uzun süre kullanılabilmesi, her alanda temiz ve güvenilir enerji elde edilebilmesi adına yapılmaktadır. Bu sebeple enerji depolama sistemlerinin, büyük bir alanını kaplayan bataryalar ile ilgili yapılan araştırmalar da, büyük önem taşımaktadır. Son yıllarda batarya sistemlerinde lityum iyon bataryalar ön plana çıkmakta ve neredeyse her alanda kullanılmaktadır. Demir katkılı Lityum piller ise en çok araştırılan ve farklı tekniklerle üretilen batarya çeşitlerindendir. Kaynak ulaşımının kolay, daha az maliyetli olabileceği, yüksek sıcaklıklarda çalışabilme esnekliği ve uzun süreli kullanımı ile dikkat çeken LiFePO4 bataryalar ile ilgili her geçen gün yeni çalışmalar yapılmaktadır. Bu çalışmada, LiFePO4 katot malzemelerine odaklanıldı ve gelecekteki araştırmalar için yeni anlayışlar keşfetmek için son çalışmaların incelenmesi yapılmıştır.

Keywords

LiFePO4, enerji, lityum, batarya, Li-ion

Supporting Institution

İnönü Üniversitesi

Project Number

FYL-2021-2638

Thanks

Bu çalışma İnönü Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi tarafından FYL-2021-2638 nolu proje kapsamında gerçekleştirilmiştir

Current Studies on LiFePO4 Batteries

Abstract

Energy storage devices have important for energy generation, transmission and distribution studies. In the last years, studies about energy storage devices and their use for a long period have been focused on clean, trustful, and cheap ways. For this reason, batteries as energy storage systems have great importance. In the last decades, most battery systems consist of Li-ion cells for better performance. Lithium batteries containing iron are one of the most studied and used cathode materials which produced different techniques. New studies on LiFePO4 batteries have been carried out attention with their easy access to resources, less costly, flexibility which working at high temperatures, and long-term use. In this study, we focus on the LiFePO4 cathode materials and reviewed the recent studies the explore new insights for future research.

Keywords

LiFePO4, energy, lithium, batteries, Li-ion

Project Number

FYL-2021-2638

References

• [1] S. Sutison, K. Pengpat, U. Intatha, J. Fanı, W. Zhang, S. Eitssayeam, “Preparation of LFPbased cathode materials for lithium-ion battery applications,” Mater. Today: Proc.., vol. 65, no. 4, pp. 2347-2350, June 2022. doi.org/10.1016/j.matpr.2022.05.302.
• [2] J. P. Baboo, et. al. (2022). “Exploring Different Binders for a LiFePO4 Battery, Battery Testing, Modeling and Simulations,” Energies, vol. 15, no. 7, pp. 2332, March 2022.
• [3] M. P. Mercer, et al., “Transitions of lithium occupation in graphite: A physically informed model in the dilute lithium occupation limit supported by electrochemical and thermodynamic measurements,” Electrochim. Acta, vol. 324, November 2019.
• [4] E. M. Gavilán-Arriazu, et. al., “Effect of temperature on the kinetics of electrochemical insertion of Li-ions into a graphite electrode studied by kinetic Monte Carlo,” J. Electrochem. Soc., vol 167, no. 1, December 2019.
• [5] J. M. Reniers, G. Mulder, D. A. Howey, “ Review and performance comparison of mechanical-chemical degradation models for lithium-ion batteries,” J. Electrochem. Soc., vol. 166, no. 14, September 2019.
• [6] B. Özdoğru, H. Dykes, S. Padwal, S. Harimkar and Ö. Ö. Çapraz, “Electrochemical strain evolution in iron phosphate composite cathodes during lithium and sodium ion intercalation,” Electrochim. Acta, 353, September 2020.
• [7] W. G. Suci, Increasing Electric Bicycle Performance using Lithium Ferro Phosphate Batteries with a Battery Management System,” Esta Journal, vol. 2, no. 1, 2022.
• [8] J. Weng, L. Peng, L., Materials Chemistry and Physics, “Improving the electrochemical performance of LiFePO4 cathode with novel water-soluble binders,” Mater. Chem. Phys., vol. 290, October 2022.
• [9] Reuters Staff, (January 2020). Tesla wins China approval to build Model 3 vehicles with LFP batteries: Reuters. [Online] Available: https://www.reuters.com/article/us-teslachina-electric-batteries/tesla-wins-chinaapproval-to-build-model-3-vehicles-with-lfpbatteries-ministry-idUSKBN23I0VT.
• [10]C. Xu, et. al., “Future material demand for automotive lithium-based batteries,” Commun. Mater., vol. 1, no. 99, December 2020.
• [11]B. M. Spears, W. J. Brownlie, D. Cordell, L. Hermann, J. M. Mogollon, “Concerns about global phosphorus demand for lithium-ironphosphate batteries in the light electric vehicle sector,” Commun. Mater., vol. 3, no. 14, April 2022.
• [12]X. Sun, M. Ouyang, H. Hao, “Surging lithium price will not impede the electric vehicle boom,” Joule, vol. 6, no. 8, pp. 1738 – 1742, August 2022.
• [13]Mineral Commodity Summaries 2022, United States Geological Survey, USGS.
• [14]M. Wang, et. al., “Recycling of lithium iron phosphate batteries: Status, technologies, challenges, and prospects,” J. Renew. Sustain. Energ., volume 163, July 2022.
• [15]W. Wheleer, A. Sari, P. Venet, Y. Bultel, E. Riviere, “LFP battery aging behavior: diagnosis of cell materials for second life applications ”Hal Open Science,. 21st Int. Meet. Lithium Batteries (IMLB2022), Sydney, Australia, June 2022.
• [16]J. Quan, et. al., “Comparative life cycle assessment of LFP and NCM batteries including the secondary use and different recycling technologies,” Sci. Total Environ, vol. 819, May 2022.
• [17] F. Meng, X. Xiong, L. Tan, B. Yuan, R. Hu, “Strategies for improving electrochemical reaction kinetics of cathode materials for subzero-temperature Li-ion batteries: A review,” Energy Stor. Mater., vol. 44, pp. 390- 407, January 2022.
• [18] F. Wu, J. Maier, Y. Yu, “Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries,” Chem. Soc. Rev. vol. 49, no. 5, pp. 1569-1614, February 2020.
• [19] S. W. Oh, et. al., “Double Carbon Coating of LiFePO4 as High Rate Electrode for Rechargeable Lithium Batteries,” Adv. Mater., vol. 22, no. 43, pp. 4842-4845, November 2010.
• [20] C. Xu, et. al., “Reply to: Concerns about global phosphorus demand for lithium-ironphosphate batteries in the light electric vehicle sector,”, Commun. Mater., vol. 3, no. 1, December 2022.