THE CATALYST FROM THE GROUND: MONTMORILLONITE

Year 2013, Volume: 14 Issue: 1, 43 - 59, 21.11.2016

Hakan Kolancılar

Abstract

Due to excessive contamination of the environment the environmentally friendly catalysts have gained importance. Montmorillonite that is abundant and cheap is an important candidate as catalyst. It can be used as catalyst and catalyst support because of their swelling and ion exchanging properties. The various modified methods like pillaring and ion exchanging increases its catalytic characteristics. Montmorillonite clay is one of the widely studied solid acid catalysts for many organic reactions.

Keywords

Montmorillonite clay, Pillaring, Ion exchanging, Solid acid catalyst

TOPRAKTAN GELEN KATALİZÖR: MONTMORİLLONİT

Abstract

Çevrenin aşırı kirlenmesinden dolayı çevre dostu katalizörler önem kazanmıştır. Bol ve ucuz olan Montmorillonit kili buna önemli bir adaydır. Montmorillonit kili şişebilme ve katyon değiştirme özelliğinden dolayı katalizör ve katalizör destekleyicisi olarak kullanılabilir. Metal yükleme, sütunlama gibi değişik modifiye işlemleri onun katalizör özelliğini arttırır. Montmorillonit kili, birçok organik reaksiyonlar için yaygın olarak kullanılan katı asid katalizörlerinden biridir.

Keywords

Montmorillonit kili, Sütunlama, İyon değiştirme, Katı asid katalizörü

References

• AHMED O. S., DUTTA D.K. Friedel-Crafts benzylation of benzene using Zn and Cd ions exchanged clay composites. Journal of Molecular Catalysis A: Chemical 229: 227–231, 2005.
• BALEK V., BENES M., MALEK Z., MATUSCHEK G., KETTRUP A., YARIV S. Emanatıon thermal analysıs study of Na-Montmorıllonıte and Montmorıllonıte saturated wıth varıous catıons. Journal of Thermal Analysis and Calorimetry. 83:3, 617–623, 2006.
• BINEESH K.V., KIM M.-IL., PARK M.-S., LEE K.-Y., PARK D.-W. Selective catalytic oxidation of H2S over V2O5-supported Fe-pillared montmorillonite clay Catalysis Today 175: 183–188, 2011.
• BORAH M., GANGULI J.N., DUTTA D.K. Intersalation Reactions of Trisdiimine Metal Complexeswith Montmorillonite Clay: A New Approach Journal of Colloid and Interface Science. 233: 171–179, 2001.
• BROWN D.R., RHODES C.N. Bronsted and Lewis acid catalysis with ion-exchanged clays. Catalysis Letters. 45: 35-40, 1997.
• DAS P., KUZNIARSKA-BIERNACKA I., SILVA A.R., CARVALHO A.P., PIRES J., FREIRE C. Encapsulation of chiral Mn(III) salen complexes into aluminium pillared clays: Application as heterogeneous catalysts in the epoxidation of styrene Journal of Molecular Catalysis A: Chemical. 248: 135–143, 2006.
• DESTREE A., LONG G.J., VATOVEZ B., GRANDJEAN F., FONSECA A.,NAGY J.B., FRANSOLET A.-M. Synthesis and characterization of carbon nanotubes grown on montmorillonite clay catalysts. J Mater Sci. 42: 8671–8689, 2007.
• FLESSNER U., JONES D.J., ROZIERE J., ZAJAC J., STORARO L., LENARDA M., PAVAN M., JIMENEZ-LOPEZ A., RODRIGUEZ-CASTELLON E., TROMBETTA M., BUSCA G. A study of the surface acidity of acid-treated montmorillonite clay catalysts, Journal of Molecular Catalysis A: Chemical 168: 247–256, 2001.
• GIL A., VICENTE M.A., LAMBERT J.-F., GANDIA L.M. Platinum catalysts supported on Al-pillared clays Application to the catalytic combustion of acetone and methyl-ethylketone Catalysis Today. 68: 41–51, 2001.
• HART M.P., BROWN D.R. Surface acidities and catalytic activities of acid-activated clays Journal of Molecular Catalysis A: Chemica.l 212: 315–321, 2004.
• ISSAADI R., GARIN F., CHITOUR E., MAIRE G. Catalytic behaviour of combined palladium-acid catalysts: use of Al and Zr-pillared montmorillonite as supports Part I. Reactivity of linear, branched and cyclic hexane hydrocarbons. Applied Catalysis A: General. 207: 323–332, 2001.
• JAGTAP N., RAMASWAMY V. Oxidation of aniline over titania pillared
• montmorillonite clays Applied Clay Science 33: 89–98, 2006.
• JANKOVIC L. AND KOMADEL P. Metal cation-exchanged montmorillonite catalyzed protection of aromatic aldehydes with Ac2O Journal of Catalysis 218: 227–233, 2003.
• JOSEPH T., SHANBHAG G.V., SAWANT D.P., HALLIGUDI S.B. Chemoselective anti-Markovnikov hydroamination of α,β-ethylenic compounds with amines using montmorillonite clay Journal of Molecular Catalysis A: Chemical 250: 210–217, 2006.
• KAR P., SAMANTARAY S., MISHRA B.G. Catalytic application of chromia-pillared montmorillonite towards environmentally benign synthesis of octahydroxanthenes Reac Kinet Mech Cat 108:241–251, 2013.
• KLOPROGGE J.T., MAHMUTAGIC E., FROST R.L. Mid-infrared and infrared emission spectroscopy of Cu-exchanged montmorillonite. Journal of Colloid and Interface Science. 296: 640–646, 2006.
• KOSTER R.M., BOGERT M., LEEUW B., POELS E.K., BLIEK A. Active sites in the clay catalysed dimerisation of oleic acid Journal of Molecular Catalysis A: Chemical. 134: 159–169, 1998.
• MOLINA M.F., MOLINA R., MORENO S. Hydroconversion of heptane over a Colombian montmorillonite modified with mixed pillars of Al–Zr and Al–Si Catalysis Today 107–108: 426–430, 2005.
• NARAYANAN S., DESHPANDE K., Alumina pillared montmorillonite:
• characterization and catalysis of toluene benzylation and aniline ethylation, Applied Catalysis A: General. 193: 17–27, 2000.
• NGUYEN-THANH D., BLOCK K., BANDOSZ T.J. Adsorption of hydrogen sulfide on montmorillonites modified with iron. Chemosphere. 59: 343–353, 2005.
• PAI S.G., BAJPAI A.R., DESHPANDE A.B., SAMANT S.D. Benzylation of arenes in the presence of Montmorillonite K10 modified using aqueous and acetonitrile solutions of FeCl3 Journal of Molecular Catalysis A: Chemical. 156: 233–243, 2000.
• PHUKAN A., GANGULI J.N., DUTTA D.K. ZnCl2-Zn2+-Montmorillonite composite: efficient solid acid catalyst for benzylation of benzene Journal of Molecular Catalysis A: Chemical. 202: 279–287, 2003.
• SALERNO P., ASENJO M.B., MENDIOROZ S. Influence of preparation method on thermal stability and acidity of Al-PILCs. Thermochimica Acta. 379: 101-109, 2001.
• SINGH V., SAPEHIYIA V., LAL KAD G. Ultrasound and microwave activated preparation of ZrO2-pillared clay composite: catalytic activity for selective, solventless acylation of 1,n-diols Journal of Molecular Catalysis A: Chemical. 210: 119–124,2004.
• TIMOFEEVA M.N., KHANKHASAEVA S.Ts., BADMAEVA S.V., CHUVILIN A.L., BURGINA E.B., AYUPOV A.B., PANCHENKO V.N., KULIKOVA A.V. Synthesis, characterization and catalytic application for wet oxidation of phenol of iron-containing clays. Applied Catalysis B: Environmental. 59: 243–248, 2005.
• TYAGI B., CHUDASAMA C.D., JASRA R.V. Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy. Spectrochimica Acta Part A. 64: 273–278, 2006.
• YADAV G.D. Synergism of clay and heteropoly acids as nano-catalysts for the development of green processes with potential industrial applications Catalysis Surveys from Asia. 9: 2, 117-137, 2005.
• ZENG Z., JIANG J.Q. Effects of the type and structure of modified clays on adsorption performance International Journal of Environmental Studies. 62:4, 403–414, 2005.