Research Article
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Year 2024, , 353 - 369, 30.04.2024
https://doi.org/10.31127/tuje.1363676

Abstract

References

  • Moreira, D. N., & Da Costa, M. P. (2020). The impact of the Covid-19 pandemic in the precipitation of intimate partner violence. International Journal of Law and Psychiatry, 71, 101606. https://doi.org/10.1016/j.ijlp.2020.101606
  • Ezegbogu, M. O., & Osadolor, H. B. (2019). Comparative forensic analysis of lipsticks using thin layer chromatography and gas chromatography. International Journal of Chemical and Molecular Engineering, 13(5), 236-240. https://doi.org/10.5281/zenodo.3298918
  • Kaur, K., Yadav, P. K., Bumbrah, G. S., & Sharma, R. M. (2020). Forensic classification of lipsticks using attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy. Vibrational Spectroscopy, 110, 103146. https://doi.org/10.1016/j.vibspec.2020.103146
  • Arora, T., Verma, R., Kumar, R., Chauhan, R., Kumar, B., & Sharma, V. (2021). Chemometrics based ATR-FTIR spectroscopy method for rapid and non-destructive discrimination between eyeliner and mascara traces. Microchemical Journal, 164, 106080. https://doi.org/10.1016/j.microc.2021.106080
  • AlSaeed, H., Amin, M. O., & Al-Hetlani, E. (2022). Forensic analysis of cosmetic smudges using surface-assisted laser desorption/ionization mass spectrometry: recovery and ageing study. Microchemical Journal, 180, 107609. https://doi.org/10.1016/j.microc.2022.107609
  • Chophi, R., Sharma, S., Sharma, S., & Singh, R. (2019). Trends in the forensic analysis of cosmetic evidence. Forensic Chemistry, 14, 100165. https://doi.org/10.1016/j.forc.2019.100165
  • Gardner, P., Bertino, M. F., Weimer, R., & Hazelrigg, E. (2013). Analysis of lipsticks using Raman spectroscopy. Forensic Science International, 232(1-3), 67-72. https://doi.org/10.1016/j.forsciint.2013.07.007
  • Gładysz, M., Król, M., & Kościelniak, P. (2021). Current analytical methodologies used for examination of lipsticks and its traces for forensic purposes. Microchemical Journal, 164, 106002. https://doi.org/10.1016/j.microc.2021.106002
  • Engasser, P. G. (2000). Lip cosmetics. Dermatologic Clinics, 18(4), 641-649. https://doi.org/10.1016/S0733-8635(05)70215-1
  • Seguı́, M. A., Feucht, M. M., Ponce, A. C., & Pascual, F. A. V. (2000). Persistent lipsticks and their lip prints: new hidden evidence at the crime scene. Forensic Science International, 112(1), 41-47. https://doi.org/10.1016/S0379-0738(00)00173-0
  • Angrish, A., Kumar, R., Chauhan, R., & Sharma, V. (2020). On the IR spectroscopy and chemometric based rapid and non-destructive method for the investigation of sunscreen stains: Application in forensic science. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 242, 118708. https://doi.org/10.1016/j.saa.2020.118708
  • Abidh, S., Cuvelier, G., de Clermont‐Gallerande, H., Navarro, S., & Delarue, J. (2019). The role of lipid composition in the sensory and physical properties of lipsticks. Journal of the American Oil Chemists' Society, 96(10), 1143-1152. https://doi.org/10.1002/aocs.12271
  • Epstein, H. (2016). Pre‐formulation design and considerations. Handbook of formulating dermal applications: A definitive practical guide, 1-27.
  • Beri, A., Norton, J. E., & Norton, I. T. (2013). Effect of emulsifier type and concentration, aqueous phase volume and wax ratio on physical, material and mechanical properties of water in oil lipsticks. International Journal of Cosmetic Science, 35(6), 613-621. https://doi.org/10.1111/ics.12085
  • Niederer, M., Stebler, T., & Grob, K. (2016). Mineral oil and synthetic hydrocarbons in cosmetic lip products. International Journal of Cosmetic Science, 38(2), 194-200. https://doi.org/10.1111/ics.12276
  • Jasuja, O. P., & Singh, R. (2005). Thin-layer chromatographic analysis of liquid lipsticks. Journal of Forensic Identification, 55(1), 28-35.
  • Wong, J. X., Sauzier, G., & Lewis, S. W. (2019). Forensic discrimination of lipsticks using visible and attenuated total reflectance infrared spectroscopy. Forensic Science International, 298, 88-96. https://doi.org/10.1016/j.forsciint.2019.02.044
  • Fernandes, A. R., Dario, M. F., Pinto, C. A. S. D. O., Kaneko, T. M., Baby, A. R., & Velasco, M. V. R. (2013). Stability evaluation of organic Lip Balm. Brazilian Journal of Pharmaceutical Sciences, 49, 293-299. https://doi.org/10.1590/S1984-82502013000200011
  • Abdullah, A., Fachrozan, R., & Hidayat, T. (2018, November). Characteristics of seaweed porridge Sargassum sp. and Eucheuma cottonii as raw materials for lip balm. In IOP Conference Series: Earth and Environmental Science, 196(1), 012018. https://doi.org/10.1088/1755-1315/196/1/012018
  • Sharma, S., Sahota, S. S., & Garg, R. K. (2016). Investigation on the aged lip-gloss stains by TLC and FT-IR. International Journal of Medical Toxicology & Legal Medicine, 19(1-2), 36-41.
  • Yadav, P.K., Sharma, R.M. (2022). Forensic analysis of cosmetic – exposition of significance, limitations and challenges. Indian Journal of Criminology. 49(2), 17-31.
  • Gładysz, M., Król, M., Karoly, A., Szalai, R., & Kościelniak, P. (2022). A multitechnique approach for discrimination and identification of lipsticks for forensic purposes. Journal of Forensic Sciences, 67(2), 494-504. https://doi.org/10.1111/1556-4029.14945
  • Bin Abdullaha, A. F. L., Marimuthua, Y., Hawa, C. K., Fatihah, N., Yaacoba, H., & Hooic, Y. C. (2011). Forensic discrimination of lipsticks by thin layer chromatography and gas chromatography-mass spectrometry. Malaysian Journal of Forensic Sciences, 2(1), 22-28.
  • López-López, M., Özbek, N., & García-Ruiz, C. (2014). Confocal Raman spectroscopy to trace lipstick with their smudges on different surfaces. Talanta, 123, 135-139. https://doi.org/10.1016/j.talanta.2014.02.025
  • Gładysz, M., Król, M., & Kościelniak, P. (2017). Differentiation of red lipsticks using the attenuated total reflection technique supported by two chemometric methods. Forensic Science International, 280, 130-138. https://doi.org/10.1016/j.forsciint.2017.09.019
  • Chophi, R., Sharma, S., & Singh, R. (2020). Forensic analysis of red lipsticks using ATR-FTIR spectroscopy and chemometrics. Forensic Chemistry, 17, 100209. https://doi.org/10.1016/j.forc.2019.100209
  • Gardner, P., Bertino, M. F., Weimer, R. (2015). Differentiation between lip cosmetics using raman spectroscopy. Journal of the American Society of Trace Evidence Examiners. 6(1), 42–57.
  • Salahioglu, F., Went, M. J., & Gibson, S. J. (2013). Application of Raman spectroscopy for the differentiation of lipstick traces. Analytical Methods, 5(20), 5392-5401. https://doi.org/10.1039/C3AY41274A
  • Kaur, S., Singh, J., & Garg, R. K. (2009). An Examination of Lip Glosses by Thin-Layer Chromatography. Journal of Forensic Identification, 59(5), 525-536.
  • Ka Khei, L., Verma, R., Tan, E. L. Y., Low, K. H., Ismail, D., & Mohamad Asri, M. N. (2023). Rapid and nondestructive analysis of lipstick on different substrates using ATR‐FTIR spectroscopy and chemometrics. Journal of Forensic Sciences, 68(3), 1001-1008. https://doi.org/10.1111/1556-4029.15223
  • Sharma, A., Chauhan, R., Kumar, R., Mankotia, P., Verma, R., & Sharma, V. (2021). A rapid and non-destructive ATR-FTIR spectroscopy method supported by chemometrics for discriminating between facial creams and the classification into herbal and non-herbal brands. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 258, 119803. https://doi.org/10.1016/j.saa.2021.119803
  • Gładysz, M., Król, M., Chudecka, A., & Kościelniak, P. (2020). Application of spectroscopic and separation techniques to the examination of the chemical composition stability of lipsticks exposed to various factors and storage conditions. Forensic Science International, 309, 110230. https://doi.org/10.1016/j.forsciint.2020.110230
  • Sapana, S., Vaibhav, S., Munish, M., AK, G. (2015). Forensic examination of lipstick by the various physio-chemical and instrumental method. International Journal of Social Relevance & Concern, 3(9), 1–7.
  • Sharma, V., Bharti, A., & Kumar, R. (2019). On the spectroscopic investigation of lipstick stains: Forensic trace evidence. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 215, 48-57. https://doi.org/10.1016/j.saa.2019.02.093
  • Singh, G. K., & Kaur, R. (2022). Forensic examination of vermilion (Sindoor) sample using ATR-FTIR spectroscopy. Materials Today: Proceedings, 68, 664-668. https://doi.org/10.1016/j.matpr.2022.05.357
  • Ossman, M. E., Mansour, M. S., Fattah, M. A., Taha, N., & Kiros, Y. (2014). Peanut shells and talc powder for removal of hexavalent chromium from aqueous solutions. Bulgarian Chemical Communications, 46(3), 629-639.

Forensic examination of lipsticks as trace evidence under different environmental conditions

Year 2024, , 353 - 369, 30.04.2024
https://doi.org/10.31127/tuje.1363676

Abstract

Trace evidence such as fingerprints, biological fluids, fibres, glass, hairs, soils, and cosmetics have been considered most of the important materials on the crime scene, which can be potentially transferred or exchanged between two surfaces when one makes contact to another. Cosmetic products are one of the valuable trace pieces of evidence on crime scene that are generally used for beautification, moisturize, reinforcement of the skin, nutritiveness, and improve the feeling or sensory aspects. In this study, different lip cosmetic products including wax lipstick, liquid lipstick, gloss and lip balm were investigated as forensic evidence. For this, 102 of lip cosmetic samples (20 of lipstick, 14 of lip gloss, 22 of lip balm and 46 of liquid lipstick) were analyzed by using Fourier-transform Infrared spectroscopy (FTIR). The differentiation between lip cosmetic products is detected. The effect of environmental conditions is studied. For this, lip cosmetic products are kept in various water medium such as simulated sea water, tap water, and distilled water in order to track the chemical stability by FTIR. Moreover, they are kept in different time of intervals from 1 day to 1 month to investigate the change over time. Staining of lip products to various substrates including fabric, glass and paper towel have been also explored. The effect of substrate type, lip cosmetic products, time and water sources have been systematically explored by FTIR and video spectral comparator (VSC). All the samples have been examined under different light sources such as visible light, UV-A (365 nm), infrared (695 nm) and spot (fluorescence) to observe the distinctive features of lip cosmetic samples on different substrates. The results have demonstrated that lip products including wax, liquids lipstick, gloss and lip balm have distinguishing character which is observed by FTIR and VSC8000. Moreover, the chemical stability of lip cosmetic products under different water sources could be characteristic tools for differentiating of lip cosmetic products. The outcomes show that cosmetic trace evidence found in water source could be critical evidence in crime scene investigation.

Thanks

The authors thank Research Asisstant Umut KENDÜZ for helping data analysis in this paper.

References

  • Moreira, D. N., & Da Costa, M. P. (2020). The impact of the Covid-19 pandemic in the precipitation of intimate partner violence. International Journal of Law and Psychiatry, 71, 101606. https://doi.org/10.1016/j.ijlp.2020.101606
  • Ezegbogu, M. O., & Osadolor, H. B. (2019). Comparative forensic analysis of lipsticks using thin layer chromatography and gas chromatography. International Journal of Chemical and Molecular Engineering, 13(5), 236-240. https://doi.org/10.5281/zenodo.3298918
  • Kaur, K., Yadav, P. K., Bumbrah, G. S., & Sharma, R. M. (2020). Forensic classification of lipsticks using attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy. Vibrational Spectroscopy, 110, 103146. https://doi.org/10.1016/j.vibspec.2020.103146
  • Arora, T., Verma, R., Kumar, R., Chauhan, R., Kumar, B., & Sharma, V. (2021). Chemometrics based ATR-FTIR spectroscopy method for rapid and non-destructive discrimination between eyeliner and mascara traces. Microchemical Journal, 164, 106080. https://doi.org/10.1016/j.microc.2021.106080
  • AlSaeed, H., Amin, M. O., & Al-Hetlani, E. (2022). Forensic analysis of cosmetic smudges using surface-assisted laser desorption/ionization mass spectrometry: recovery and ageing study. Microchemical Journal, 180, 107609. https://doi.org/10.1016/j.microc.2022.107609
  • Chophi, R., Sharma, S., Sharma, S., & Singh, R. (2019). Trends in the forensic analysis of cosmetic evidence. Forensic Chemistry, 14, 100165. https://doi.org/10.1016/j.forc.2019.100165
  • Gardner, P., Bertino, M. F., Weimer, R., & Hazelrigg, E. (2013). Analysis of lipsticks using Raman spectroscopy. Forensic Science International, 232(1-3), 67-72. https://doi.org/10.1016/j.forsciint.2013.07.007
  • Gładysz, M., Król, M., & Kościelniak, P. (2021). Current analytical methodologies used for examination of lipsticks and its traces for forensic purposes. Microchemical Journal, 164, 106002. https://doi.org/10.1016/j.microc.2021.106002
  • Engasser, P. G. (2000). Lip cosmetics. Dermatologic Clinics, 18(4), 641-649. https://doi.org/10.1016/S0733-8635(05)70215-1
  • Seguı́, M. A., Feucht, M. M., Ponce, A. C., & Pascual, F. A. V. (2000). Persistent lipsticks and their lip prints: new hidden evidence at the crime scene. Forensic Science International, 112(1), 41-47. https://doi.org/10.1016/S0379-0738(00)00173-0
  • Angrish, A., Kumar, R., Chauhan, R., & Sharma, V. (2020). On the IR spectroscopy and chemometric based rapid and non-destructive method for the investigation of sunscreen stains: Application in forensic science. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 242, 118708. https://doi.org/10.1016/j.saa.2020.118708
  • Abidh, S., Cuvelier, G., de Clermont‐Gallerande, H., Navarro, S., & Delarue, J. (2019). The role of lipid composition in the sensory and physical properties of lipsticks. Journal of the American Oil Chemists' Society, 96(10), 1143-1152. https://doi.org/10.1002/aocs.12271
  • Epstein, H. (2016). Pre‐formulation design and considerations. Handbook of formulating dermal applications: A definitive practical guide, 1-27.
  • Beri, A., Norton, J. E., & Norton, I. T. (2013). Effect of emulsifier type and concentration, aqueous phase volume and wax ratio on physical, material and mechanical properties of water in oil lipsticks. International Journal of Cosmetic Science, 35(6), 613-621. https://doi.org/10.1111/ics.12085
  • Niederer, M., Stebler, T., & Grob, K. (2016). Mineral oil and synthetic hydrocarbons in cosmetic lip products. International Journal of Cosmetic Science, 38(2), 194-200. https://doi.org/10.1111/ics.12276
  • Jasuja, O. P., & Singh, R. (2005). Thin-layer chromatographic analysis of liquid lipsticks. Journal of Forensic Identification, 55(1), 28-35.
  • Wong, J. X., Sauzier, G., & Lewis, S. W. (2019). Forensic discrimination of lipsticks using visible and attenuated total reflectance infrared spectroscopy. Forensic Science International, 298, 88-96. https://doi.org/10.1016/j.forsciint.2019.02.044
  • Fernandes, A. R., Dario, M. F., Pinto, C. A. S. D. O., Kaneko, T. M., Baby, A. R., & Velasco, M. V. R. (2013). Stability evaluation of organic Lip Balm. Brazilian Journal of Pharmaceutical Sciences, 49, 293-299. https://doi.org/10.1590/S1984-82502013000200011
  • Abdullah, A., Fachrozan, R., & Hidayat, T. (2018, November). Characteristics of seaweed porridge Sargassum sp. and Eucheuma cottonii as raw materials for lip balm. In IOP Conference Series: Earth and Environmental Science, 196(1), 012018. https://doi.org/10.1088/1755-1315/196/1/012018
  • Sharma, S., Sahota, S. S., & Garg, R. K. (2016). Investigation on the aged lip-gloss stains by TLC and FT-IR. International Journal of Medical Toxicology & Legal Medicine, 19(1-2), 36-41.
  • Yadav, P.K., Sharma, R.M. (2022). Forensic analysis of cosmetic – exposition of significance, limitations and challenges. Indian Journal of Criminology. 49(2), 17-31.
  • Gładysz, M., Król, M., Karoly, A., Szalai, R., & Kościelniak, P. (2022). A multitechnique approach for discrimination and identification of lipsticks for forensic purposes. Journal of Forensic Sciences, 67(2), 494-504. https://doi.org/10.1111/1556-4029.14945
  • Bin Abdullaha, A. F. L., Marimuthua, Y., Hawa, C. K., Fatihah, N., Yaacoba, H., & Hooic, Y. C. (2011). Forensic discrimination of lipsticks by thin layer chromatography and gas chromatography-mass spectrometry. Malaysian Journal of Forensic Sciences, 2(1), 22-28.
  • López-López, M., Özbek, N., & García-Ruiz, C. (2014). Confocal Raman spectroscopy to trace lipstick with their smudges on different surfaces. Talanta, 123, 135-139. https://doi.org/10.1016/j.talanta.2014.02.025
  • Gładysz, M., Król, M., & Kościelniak, P. (2017). Differentiation of red lipsticks using the attenuated total reflection technique supported by two chemometric methods. Forensic Science International, 280, 130-138. https://doi.org/10.1016/j.forsciint.2017.09.019
  • Chophi, R., Sharma, S., & Singh, R. (2020). Forensic analysis of red lipsticks using ATR-FTIR spectroscopy and chemometrics. Forensic Chemistry, 17, 100209. https://doi.org/10.1016/j.forc.2019.100209
  • Gardner, P., Bertino, M. F., Weimer, R. (2015). Differentiation between lip cosmetics using raman spectroscopy. Journal of the American Society of Trace Evidence Examiners. 6(1), 42–57.
  • Salahioglu, F., Went, M. J., & Gibson, S. J. (2013). Application of Raman spectroscopy for the differentiation of lipstick traces. Analytical Methods, 5(20), 5392-5401. https://doi.org/10.1039/C3AY41274A
  • Kaur, S., Singh, J., & Garg, R. K. (2009). An Examination of Lip Glosses by Thin-Layer Chromatography. Journal of Forensic Identification, 59(5), 525-536.
  • Ka Khei, L., Verma, R., Tan, E. L. Y., Low, K. H., Ismail, D., & Mohamad Asri, M. N. (2023). Rapid and nondestructive analysis of lipstick on different substrates using ATR‐FTIR spectroscopy and chemometrics. Journal of Forensic Sciences, 68(3), 1001-1008. https://doi.org/10.1111/1556-4029.15223
  • Sharma, A., Chauhan, R., Kumar, R., Mankotia, P., Verma, R., & Sharma, V. (2021). A rapid and non-destructive ATR-FTIR spectroscopy method supported by chemometrics for discriminating between facial creams and the classification into herbal and non-herbal brands. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 258, 119803. https://doi.org/10.1016/j.saa.2021.119803
  • Gładysz, M., Król, M., Chudecka, A., & Kościelniak, P. (2020). Application of spectroscopic and separation techniques to the examination of the chemical composition stability of lipsticks exposed to various factors and storage conditions. Forensic Science International, 309, 110230. https://doi.org/10.1016/j.forsciint.2020.110230
  • Sapana, S., Vaibhav, S., Munish, M., AK, G. (2015). Forensic examination of lipstick by the various physio-chemical and instrumental method. International Journal of Social Relevance & Concern, 3(9), 1–7.
  • Sharma, V., Bharti, A., & Kumar, R. (2019). On the spectroscopic investigation of lipstick stains: Forensic trace evidence. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 215, 48-57. https://doi.org/10.1016/j.saa.2019.02.093
  • Singh, G. K., & Kaur, R. (2022). Forensic examination of vermilion (Sindoor) sample using ATR-FTIR spectroscopy. Materials Today: Proceedings, 68, 664-668. https://doi.org/10.1016/j.matpr.2022.05.357
  • Ossman, M. E., Mansour, M. S., Fattah, M. A., Taha, N., & Kiros, Y. (2014). Peanut shells and talc powder for removal of hexavalent chromium from aqueous solutions. Bulgarian Chemical Communications, 46(3), 629-639.
There are 36 citations in total.

Details

Primary Language English
Subjects Environmental Engineering (Other)
Journal Section Articles
Authors

Seyda Turkay 0000-0001-5575-4406

Soner Kizil 0000-0003-3405-1212

Early Pub Date April 17, 2024
Publication Date April 30, 2024
Published in Issue Year 2024

Cite

APA Turkay, S., & Kizil, S. (2024). Forensic examination of lipsticks as trace evidence under different environmental conditions. Turkish Journal of Engineering, 8(2), 353-369. https://doi.org/10.31127/tuje.1363676
AMA Turkay S, Kizil S. Forensic examination of lipsticks as trace evidence under different environmental conditions. TUJE. April 2024;8(2):353-369. doi:10.31127/tuje.1363676
Chicago Turkay, Seyda, and Soner Kizil. “Forensic Examination of Lipsticks As Trace Evidence under Different Environmental Conditions”. Turkish Journal of Engineering 8, no. 2 (April 2024): 353-69. https://doi.org/10.31127/tuje.1363676.
EndNote Turkay S, Kizil S (April 1, 2024) Forensic examination of lipsticks as trace evidence under different environmental conditions. Turkish Journal of Engineering 8 2 353–369.
IEEE S. Turkay and S. Kizil, “Forensic examination of lipsticks as trace evidence under different environmental conditions”, TUJE, vol. 8, no. 2, pp. 353–369, 2024, doi: 10.31127/tuje.1363676.
ISNAD Turkay, Seyda - Kizil, Soner. “Forensic Examination of Lipsticks As Trace Evidence under Different Environmental Conditions”. Turkish Journal of Engineering 8/2 (April 2024), 353-369. https://doi.org/10.31127/tuje.1363676.
JAMA Turkay S, Kizil S. Forensic examination of lipsticks as trace evidence under different environmental conditions. TUJE. 2024;8:353–369.
MLA Turkay, Seyda and Soner Kizil. “Forensic Examination of Lipsticks As Trace Evidence under Different Environmental Conditions”. Turkish Journal of Engineering, vol. 8, no. 2, 2024, pp. 353-69, doi:10.31127/tuje.1363676.
Vancouver Turkay S, Kizil S. Forensic examination of lipsticks as trace evidence under different environmental conditions. TUJE. 2024;8(2):353-69.
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